Process for producing high resilience polyurethane foam
    2.
    发明授权
    Process for producing high resilience polyurethane foam 失效
    生产高强度聚氨酯泡沫的方法

    公开(公告)号:US5104907A

    公开(公告)日:1992-04-14

    申请号:US559348

    申请日:1990-07-30

    IPC分类号: C08G18/20

    CPC分类号: C08G18/2027 C08G2101/0008

    摘要: A process for producing a high resilience polyurethane foam by reacting a polyol with a polyisocyanate in the presence of a catalyst, a blowing agent, and a foam stabilizer; said polyisocyanate containing at least diphenylmethane diisocyanate and/or a mixture of diphenylmethane diisocyanate with a derivative thereof, the blowing agent being water, or water and a halogenated hydrocarbon in amounts of not less than 2 parts by weight of water and not more than 20 parts by weight of the halogenated hydrocarbon based on 100 parts by weight of the polyol, and the catalyst being at least one selected from the compounds represented by the formula (I) below: ##STR1## where R.sup.1 is alkyl having 1 to 4 carbons, dimethylaminopropyl, benzyl, vinyl, or hydroxyalkyl having 1 to 3 carbons; R.sup.2 is hydrogen, alkyl having 1 to 4 carbons, alkyl, benzyl or phenyl; and R.sup.3 and R.sup.4 are independently hydrogen, alkyl having 1 to 4 carbons, or hydroxymethyl.

    Process for producing flexible polyurethane foam having high air flow
property
    3.
    发明授权
    Process for producing flexible polyurethane foam having high air flow property 失效
    具有高空气流动性的柔性聚氨酯泡沫塑料的制造方法

    公开(公告)号:US5306738A

    公开(公告)日:1994-04-26

    申请号:US17437

    申请日:1993-02-12

    摘要: Process for producing a flexible polyurethane foam through reaction of a polyol with a polyisocyanate in the presence of an amine catalyst, a blowing agent, and a foam stabilizer, the amine catalyst comprising at least one of the imidazoles represented by the general formula below: ##STR1## wherein R.sup.1 is alkyl of 1 to 4 carbons, dimethylaminopropyl, benzyl, vinyl, or hydroxyalkyl of 1 to 3 carbons; R.sup.2 is hydrogen, alkyl of 1 to 4 carbons, allyl, benzyl, or phenyl; and R.sup.3 and R.sup.4 are respectively hydrogen, alkyl of 1 to 4 carbons, or hydroxymethyl.

    摘要翻译: 在胺催化剂,发泡剂和泡沫稳定剂的存在下通过多元醇与多异氰酸酯的反应制备软质聚氨酯泡沫的方法,所述胺催化剂包含由以下通式表示的至少一种咪唑:( *化学结构*)其中R 1为1至4个碳的烷基,二甲基氨基丙基,苄基,乙烯基或1至3个碳的羟烷基; R2是氢,1至4个碳的烷基,烯丙基,苄基或苯基; R3和R4分别为氢,1〜4个碳的烷基或羟甲基。

    Catalyst for polyurethane having delay property
    4.
    发明授权
    Catalyst for polyurethane having delay property 失效
    具有延迟性能的聚氨酯催化剂

    公开(公告)号:US4617286A

    公开(公告)日:1986-10-14

    申请号:US647399

    申请日:1984-09-05

    CPC分类号: C08G18/1875 C08G18/2027

    摘要: The disclosed catalyst for polyurethane comprises an organic carboxylic acid salt of a tertiary amine compound and 1-methyl-4-(2-dimethylaminoethyl)piperazine. The tertiary amine compound is selected from the group of triethylenediamine, bis(2-dimethylaminoethyl)ether and N,N,N',N",N"-pentamethyldiethylenetriamine and the organic carboxylic acid is selected from the organic carboxylic acids having 1-20 carbon atoms.

    摘要翻译: 所公开的聚氨酯催化剂包括叔胺化合物和1-甲基-4-(2-二甲基氨基乙基)哌嗪的有机羧酸盐。 叔胺化合物选自三亚乙基二胺,双(2-二甲基氨基乙基)醚和N,N,N',N“,N” - 五甲基二亚乙基三胺,有机羧酸选自具有1 -20个碳原子。

    Preparation of fine-cell rigid polyurethane foam using amine catalyst
    5.
    发明授权
    Preparation of fine-cell rigid polyurethane foam using amine catalyst 失效
    使用胺催化剂制备细胞硬质聚氨酯泡沫

    公开(公告)号:US4910230A

    公开(公告)日:1990-03-20

    申请号:US288238

    申请日:1988-12-22

    IPC分类号: C08G18/18

    摘要: A fine-cell rigid polyurethane foam is prepared by reacting a polyol having a blowing agent such as water incorporated therein with a polyisocyanate in the presence of an amine catalyst having a retarding effect. The amine catalyst is comprised of (a) 30 to 50 parts by weight of triethylene diamine, (b) 30 to 50 parts by weight of bis(dimethylaminoethyl)ether and/or N,N',N",N"-pentamethyldiethylene triamine, (c) up to 40 parts by weight of tetramethylhexamethylene diamine and/or trimethylaminoethylpiperazine, and (d) formic acid in an amount of 0.2 to 1.5 moles per mole of triethylene diamine.

    Amine catalyst for forming fine-cell rigid polyurethane foam
    6.
    发明授权
    Amine catalyst for forming fine-cell rigid polyurethane foam 失效
    用于形成细胞硬质聚氨酯泡沫的胺催化剂

    公开(公告)号:US5006501A

    公开(公告)日:1991-04-09

    申请号:US458504

    申请日:1989-12-28

    IPC分类号: C08G18/18

    摘要: A fine-cell rigid polyurethane foam is prepared by reacting a polyol having a blowing agent such as water incorporated therein with a polyisocyanate in the presence of an amine catalyst having a retarding effect. The amine catalyst is comprised of (a) 30 to 50 parts by weight of triethylene diamine, (b) 30 to 50 parts by weight of bis(dimethylaminoethyl)ether and/or N,N',N",N"-pentamethyldiethylene triamine, (c) up to 40 parts by weight of tetramethylhexamethylene diamine and/or trimethylaminoethylpiperazine, and (d) formic acid in an amount of 0.2 to 1.5 moles per mole of triethylene diamine.

    Fluorine-containing polymerisable monomer and polymer prepared by using same
    8.
    发明申请
    Fluorine-containing polymerisable monomer and polymer prepared by using same 有权
    含氟可聚合单体和使用它制备的聚合物

    公开(公告)号:US20060252897A1

    公开(公告)日:2006-11-09

    申请号:US11485422

    申请日:2006-07-13

    IPC分类号: C08F220/22

    摘要: The present invention relates to a polymerizable monomer represented by the general formula (1), wherein R1 is a hydrogen atom, a halogen atom, a hydrocarbon group or a fluorine-containing alkyl group; R2 is a straight-chain or branched alkyl group, a cyclic alkyl group, an aromatic group, or a substituent having at least two of these groups, the R2 being optionally partially fluorinated; R3 is a hydrogen atom, a hydrocarbon group that is optionally branched, a fluorine-containing alkyl group, or a cyclic group having an aromatic or alicyclic structure, the R3 optionally containing a bond of an oxygen atom or carbonyl group; and n is an integer of 1-2.

    摘要翻译: 本发明涉及由通式(1)表示的可聚合单体,其中R 1是氢原子,卤素原子,烃基或含氟烷基; R 2是直链或支链烷基,环状烷基,芳族基团或具有这些基团中的至少两个的取代基,R 2是 任选部分氟化; R 3是氢原子,任选支链的烃基,含氟烷基或具有芳族或脂环结构的环状基团,R 3, 任选地含有氧原子或羰基的键; n为1-2的整数。

    Process for producing alcohols
    10.
    发明授权
    Process for producing alcohols 失效
    醇的制备方法

    公开(公告)号:US4263449A

    公开(公告)日:1981-04-21

    申请号:US133438

    申请日:1980-03-24

    摘要: An alcohol is produced from a compound having an alkenyl group by a hydroformylation of said compound having an alkenyl group in a substantially water immiscible solvent in the presence of a hydroformylation catalyst which is soluble in said solvent and a hydrogenation of the reaction mixture in the presence of a hydrogenation catalyst.Water is added at a ratio of 0.5 to 30 times by weight base on an aldehyde produced by said hydroformylation before said hydrogenation, and an organic phase containing the hydroformylation catalyst component is separated from a water phase containing the alcohol produced by said hydrogenation and said organic phase is recycled into said hydroformylation.The compound having an alkenyl group is an aliphatic olefin, a hydroxyolefin, and olefin ether or an olefin ester and the corresponding saturated alcohol having one more carbon atom is produced.

    摘要翻译: 在可溶于所述溶剂的加氢甲酰化催化剂存在下,通过在基本上与水不混溶的溶剂中具有链烯基的所述化合物的羰基化从具有烯基的化合物制备醇,并且在存在下氢化反应混合物 的氢化催化剂。 加水的比例为0.5-30重量%,基于在所述氢化之前通过所述加氢甲酰化产生的醛,并且含有加氢甲酰化催化剂组分的有机相与含有由所述氢化产生的醇的水相和所述有机物 相循环进入所述加氢甲酰化反应。 具有烯基的化合物是脂族烯烃,羟基烯烃和烯烃醚或烯烃酯,并且产生具有一个以上碳原子的相应的饱和醇。