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    PROCESS FOR REDUCING THE TOTAL ACID NUMBER OF A HYDROCARBON FEED
    1.
    发明申请
    PROCESS FOR REDUCING THE TOTAL ACID NUMBER OF A HYDROCARBON FEED 有权
    减少油料进料总酸值的方法

    公开(公告)号：US20120074042A1

    公开(公告)日：2012-03-29

    申请号：US12889715

    申请日：2010-09-24

    申请人： Shabbir Husain ,  Lin Li ,  Zhen Zhou ,  Alexander E. Kuperman ,  Zunqing He ,  Huping Luo

    发明人： Shabbir Husain ,  Lin Li ,  Zhen Zhou ,  Alexander E. Kuperman ,  Zunqing He ,  Huping Luo

    IPC分类号： C10G29/04

    CPC分类号： C10G29/00 ,  C10G29/04 ,  C10G29/06 ,  C10G2300/1011 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/203 ,  C10G2300/4018 ,  Y02P30/20

    摘要： Disclosed are embodiments relating to a process for reducing the total acid number of a hydrocarbon feed by contacting the feed with a metal titanate catalyst having an MTiO3 structure wherein M is a metal having a valence of 2+, resulting in a hydrocarbon product having a final total acid number lower than the initial total acid number of the feed. The process is useful for pretreating high acid crudes prior to further processing thus avoiding corrosion of equipment used in refining operations. The process can be integrated into conventional refining operations in order to treat various refinery streams. In one embodiment, a process is provided for refining a low acid crude oil and a high acid crude oil by separately introducing a relatively low acid crude oil feed and a relatively high acid crude oil feed to an atmospheric distillation column, wherein the relatively high acid crude oil feed is contacted with a metal titanate catalyst prior to introduction to the atmospheric distillation column.

    摘要翻译： 公开了通过使进料与具有MTiO 3结构的金属钛酸酯催化剂接触来降低烃进料的总酸值的方法的实施方案，其中M是具有2+价数的金属，导致烃产物具有最终的 总酸值低于进料的初始总酸值。 该方法可用于在进一步加工之前预处理高酸性原油，从而避免在精炼操作中使用的设备的腐蚀。 该方法可以集成到常规的精炼操作中，以便处理各种炼油流。 在一个实施方案中，提供了通过将相对低的酸性原油进料和相对高的酸性原油进料单独引入常压蒸馏塔来提炼低酸原油和高酸性原油的方法，其中相对高的酸 原油进料在引入常压蒸馏塔之前与钛酸金属催化剂接触。

    Process for reducing the total acid number of a hydrocarbon feed
    4.
    发明授权
    Process for reducing the total acid number of a hydrocarbon feed 有权
    降低烃进料总酸值的方法

    公开(公告)号：US08815085B2

    公开(公告)日：2014-08-26

    申请号：US12889715

    申请日：2010-09-24

    申请人： Shabbir Husain ,  Lin Li ,  Zhen Zhou ,  Alexander E. Kuperman ,  Zunqing He ,  Huping Luo

    发明人： Shabbir Husain ,  Lin Li ,  Zhen Zhou ,  Alexander E. Kuperman ,  Zunqing He ,  Huping Luo

    IPC分类号： C10G29/16 ,  C10G29/04

    CPC分类号： C10G29/00 ,  C10G29/04 ,  C10G29/06 ,  C10G2300/1011 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/203 ,  C10G2300/4018 ,  Y02P30/20

    摘要： Disclosed are embodiments relating to a process for reducing the total acid number of a hydrocarbon feed by contacting the feed with a metal titanate catalyst having an MTiO3 structure wherein M is a metal having a valence of 2+, resulting in a hydrocarbon product having a final total acid number lower than the initial total acid number of the feed. The process is useful for pretreating high acid crudes prior to further processing thus avoiding corrosion of equipment used in refining operations. The process can be integrated into conventional refining operations in order to treat various refinery streams. In one embodiment, a process is provided for refining a low acid crude oil and a high acid crude oil by separately introducing a relatively low acid crude oil feed and a relatively high acid crude oil feed to an atmospheric distillation column, wherein the relatively high acid crude oil feed is contacted with a metal titanate catalyst prior to introduction to the atmospheric distillation column.

    摘要翻译： 公开了通过使进料与具有MTiO 3结构的金属钛酸酯催化剂接触来降低烃进料的总酸值的方法的实施方案，其中M是具有2+价数的金属，导致烃产物具有最终的 总酸值低于进料的初始总酸值。 该方法可用于在进一步加工之前预处理高酸性原油，从而避免在精炼操作中使用的设备的腐蚀。 该方法可以集成到常规的精炼操作中，以便处理各种炼油流。 在一个实施方案中，提供了通过将相对低的酸性原油进料和相对高的酸性原油进料单独引入常压蒸馏塔来提炼低酸原油和高酸性原油的方法，其中相对高的酸 原油进料在引入常压蒸馏塔之前与钛酸金属催化剂接触。

    System, process and reactor for conducting a synthesis gas conversion reaction
    7.
    发明授权
    System, process and reactor for conducting a synthesis gas conversion reaction 有权
    用于进行合成气转化反应的系统，工艺和反应器

    公开(公告)号：US09023901B2

    公开(公告)日：2015-05-05

    申请号：US13955897

    申请日：2013-07-31

    申请人： Lixin You ,  Shabbir Husain ,  Christopher M. Chen

    发明人： Lixin You ,  Shabbir Husain ,  Christopher M. Chen

    IPC分类号： C07C27/06 ,  C07C1/04 ,  C10G2/00

    CPC分类号： C07C1/0485 ,  C07C1/041 ,  C07C2523/75 ,  C10G2/32 ,  C10G2/332 ,  C10G2/341 ,  C07C11/02

    摘要： A synthesis gas conversion process and system are disclosed. Fresh syngas from a methane reformer is used as a sweep zone gas feed which is caused to flow across a water permselective membrane in a membrane reactor. The water permselective membrane is adjacent a synthesis gas conversion reaction zone in which synthesis gas is contacted with a catalyst and converted to effluent including water. Water is removed from the reaction zone through the membrane and passes out of the reactor with the sweep zone gas. The water is then removed from the sweep zone gas forming a modified gas feed which is fed to the reaction zone. The modified gas feed has a preferred H2/CO ratio to feed into the reaction zone.

    摘要翻译： 公开了一种合成气转化方法和系统。 使用来自甲烷重整器的新鲜合成气作为吹扫区气体进料，其被流过膜反应器中的水选择性膜。 水选择性膜与合成气转化反应区相邻，其中合成气与催化剂接触并转化成包含水的流出物。 通过膜从反应区域除去水，并用扫气区气体从反应器中排出。 然后将水从吹扫区气体中除去，形成进料到反应区的改性气体进料。 改性气体进料具有优选的进料到反应区中的H 2 / CO比。

    SYSTEM, PROCESS AND REACTOR FOR CONDUCTING A SYNTHESIS GAS CONVERSION REACTION
    9.
    发明申请
    SYSTEM, PROCESS AND REACTOR FOR CONDUCTING A SYNTHESIS GAS CONVERSION REACTION 有权
    用于导致合成气转化反应的系统，过程和反应器

    公开(公告)号：US20150038598A1

    公开(公告)日：2015-02-05

    申请号：US13955897

    申请日：2013-07-31

    申请人： Lixin You ,  Shabbir Husain ,  Christopher M. Chen

    发明人： Lixin You ,  Shabbir Husain ,  Christopher M. Chen

    IPC分类号： C07C1/04

    CPC分类号： C07C1/0485 ,  C07C1/041 ,  C07C2523/75 ,  C10G2/32 ,  C10G2/332 ,  C10G2/341 ,  C07C11/02

    摘要： A synthesis gas conversion process and system are disclosed. Fresh syngas from a methane reformer is used as a sweep zone gas feed which is caused to flow across a water permselective membrane in a membrane reactor. The water permselective membrane is adjacent a synthesis gas conversion reaction zone in which synthesis gas is contacted with a catalyst and converted to effluent including water. Water is removed from the reaction zone through the membrane and passes out of the reactor with the sweep zone gas. The water is then removed from the sweep zone gas forming a modified gas feed which is fed to the reaction zone. The modified gas feed has a preferred H2/CO ratio to feed into the reaction zone.

    摘要翻译： 公开了一种合成气转化方法和系统。 使用来自甲烷重整器的新鲜合成气作为吹扫区气体进料，其被流过膜反应器中的水选择性膜。 水选择性膜与合成气转化反应区相邻，其中合成气与催化剂接触并转化成包含水的流出物。 通过膜从反应区域除去水，并用扫气区气体从反应器中排出。 然后将水从吹扫区气体中除去，形成进料到反应区的改性气体进料。 改性气体进料具有优选的进料到反应区中的H 2 / CO比。

    PROCESS AND SYSTEM FOR PRODUCING SYNTHETIC CRUDE OIL FROM OFFSHORE PRODUCED FLUIDS CONTAINING HIGH CO2 CONTENT
    10.
    发明申请
    PROCESS AND SYSTEM FOR PRODUCING SYNTHETIC CRUDE OIL FROM OFFSHORE PRODUCED FLUIDS CONTAINING HIGH CO2 CONTENT 有权
    从海洋生产含有高二氧化碳含量的流体生产合成原油的方法和系统

    公开(公告)号：US20140100295A1

    公开(公告)日：2014-04-10

    申请号：US13644328

    申请日：2012-10-04

    申请人： Daniel Chinn ,  Gordon R. Deppe ,  Anne M. Helgeson ,  Shabbir Husain

    发明人： Daniel Chinn ,  Gordon R. Deppe ,  Anne M. Helgeson ,  Shabbir Husain

    IPC分类号： B01J12/00 ,  C07C27/00

    CPC分类号： B01J12/00 ,  C10G2/32 ,  C10G2/50

    摘要： A system and process for producing synthetic crude oil from produced fluids of an oil well is disclosed. The system comprises a separation plant for producing an associated gas stream from produced fluids a membrane unit comprising a plurality of polymer membranes to provide a CO2 enriched permeate stream and a CO2 depleted product gas stream, a gas conversion plant for converting the CO2 depleted product gas stream into a synthetic crude oil and a heat exchanger adding heat to the associated gas stream so that the membrane unit operates at a temperature of at least 80° C. during separation of the associated gas stream using the membrane unit. A process using the aforementioned components, including separation of the associated gas stream using the membrane unit at a temperature >80° C., into a CO2 enriched stream and a CO2 depleted product stream, is also described.

    摘要翻译： 公开了一种从油井的生产流体生产合成原油的系统和方法。 该系统包括用于从产生的流体产生相关气流的分离装置，包括多个聚合物膜的膜单元，以提供富含CO 2的渗透物流和CO 2贫化产物气流，用于转化CO 2贫化产物气体的气体转化装置 流入合成原油和向相关气流加热的热交换器，使得膜单元在使用膜单元分离相关气流期间在至少80℃的温度下操作。 还描述了使用上述组分的方法，包括将温度> 80℃下使用膜单元的相关气流分离成富CO 2流和二氧化碳贫化产物流。