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    PROCESS FOR REDUCING THE TOTAL ACID NUMBER OF A HYDROCARBON FEED
    1.
    发明申请
    PROCESS FOR REDUCING THE TOTAL ACID NUMBER OF A HYDROCARBON FEED 有权
    减少油料进料总酸值的方法

    公开(公告)号：US20120074042A1

    公开(公告)日：2012-03-29

    申请号：US12889715

    申请日：2010-09-24

    申请人： Shabbir Husain ,  Lin Li ,  Zhen Zhou ,  Alexander E. Kuperman ,  Zunqing He ,  Huping Luo

    发明人： Shabbir Husain ,  Lin Li ,  Zhen Zhou ,  Alexander E. Kuperman ,  Zunqing He ,  Huping Luo

    IPC分类号： C10G29/04

    CPC分类号： C10G29/00 ,  C10G29/04 ,  C10G29/06 ,  C10G2300/1011 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/203 ,  C10G2300/4018 ,  Y02P30/20

    摘要： Disclosed are embodiments relating to a process for reducing the total acid number of a hydrocarbon feed by contacting the feed with a metal titanate catalyst having an MTiO3 structure wherein M is a metal having a valence of 2+, resulting in a hydrocarbon product having a final total acid number lower than the initial total acid number of the feed. The process is useful for pretreating high acid crudes prior to further processing thus avoiding corrosion of equipment used in refining operations. The process can be integrated into conventional refining operations in order to treat various refinery streams. In one embodiment, a process is provided for refining a low acid crude oil and a high acid crude oil by separately introducing a relatively low acid crude oil feed and a relatively high acid crude oil feed to an atmospheric distillation column, wherein the relatively high acid crude oil feed is contacted with a metal titanate catalyst prior to introduction to the atmospheric distillation column.

    摘要翻译： 公开了通过使进料与具有MTiO 3结构的金属钛酸酯催化剂接触来降低烃进料的总酸值的方法的实施方案，其中M是具有2+价数的金属，导致烃产物具有最终的 总酸值低于进料的初始总酸值。 该方法可用于在进一步加工之前预处理高酸性原油，从而避免在精炼操作中使用的设备的腐蚀。 该方法可以集成到常规的精炼操作中，以便处理各种炼油流。 在一个实施方案中，提供了通过将相对低的酸性原油进料和相对高的酸性原油进料单独引入常压蒸馏塔来提炼低酸原油和高酸性原油的方法，其中相对高的酸 原油进料在引入常压蒸馏塔之前与钛酸金属催化剂接触。

    Process for reducing the total acid number of a hydrocarbon feed
    4.
    发明授权
    Process for reducing the total acid number of a hydrocarbon feed 有权
    降低烃进料总酸值的方法

    公开(公告)号：US08815085B2

    公开(公告)日：2014-08-26

    申请号：US12889715

    申请日：2010-09-24

    申请人： Shabbir Husain ,  Lin Li ,  Zhen Zhou ,  Alexander E. Kuperman ,  Zunqing He ,  Huping Luo

    发明人： Shabbir Husain ,  Lin Li ,  Zhen Zhou ,  Alexander E. Kuperman ,  Zunqing He ,  Huping Luo

    IPC分类号： C10G29/16 ,  C10G29/04

    CPC分类号： C10G29/00 ,  C10G29/04 ,  C10G29/06 ,  C10G2300/1011 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/203 ,  C10G2300/4018 ,  Y02P30/20

    摘要： Disclosed are embodiments relating to a process for reducing the total acid number of a hydrocarbon feed by contacting the feed with a metal titanate catalyst having an MTiO3 structure wherein M is a metal having a valence of 2+, resulting in a hydrocarbon product having a final total acid number lower than the initial total acid number of the feed. The process is useful for pretreating high acid crudes prior to further processing thus avoiding corrosion of equipment used in refining operations. The process can be integrated into conventional refining operations in order to treat various refinery streams. In one embodiment, a process is provided for refining a low acid crude oil and a high acid crude oil by separately introducing a relatively low acid crude oil feed and a relatively high acid crude oil feed to an atmospheric distillation column, wherein the relatively high acid crude oil feed is contacted with a metal titanate catalyst prior to introduction to the atmospheric distillation column.

    摘要翻译： 公开了通过使进料与具有MTiO 3结构的金属钛酸酯催化剂接触来降低烃进料的总酸值的方法的实施方案，其中M是具有2+价数的金属，导致烃产物具有最终的 总酸值低于进料的初始总酸值。 该方法可用于在进一步加工之前预处理高酸性原油，从而避免在精炼操作中使用的设备的腐蚀。 该方法可以集成到常规的精炼操作中，以便处理各种炼油流。 在一个实施方案中，提供了通过将相对低的酸性原油进料和相对高的酸性原油进料单独引入常压蒸馏塔来提炼低酸原油和高酸性原油的方法，其中相对高的酸 原油进料在引入常压蒸馏塔之前与钛酸金属催化剂接触。

    METHOD FOR REDUCING MERCAPTANS IN HYDROCARBONS
    6.
    发明申请
    METHOD FOR REDUCING MERCAPTANS IN HYDROCARBONS 有权
    减少碳氢化合物的方法

    公开(公告)号：US20120103872A1

    公开(公告)日：2012-05-03

    申请号：US13281114

    申请日：2011-10-25

    申请人： Lin Li ,  Zunqing He ,  Zhen Zhou ,  King T. Ng ,  Paul E. Hajdu

    发明人： Lin Li ,  Zunqing He ,  Zhen Zhou ,  King T. Ng ,  Paul E. Hajdu

    IPC分类号： C10G27/02

    CPC分类号： C10G17/07 ,  C10G19/02 ,  C10G53/10 ,  C10G53/12 ,  C10G2300/1033 ,  C10G2300/202

    摘要： A method for reducing mercaptan concentration in a crude oil is disclosed. The method comprises contacting the crude with a treating solution comprising a hypochlorite solution, whereby the mercaptan sulfur is oxidized and converted to at least one sulfur oxoacid or salt thereof, yielding a treated crude oil having less than 50 ppm mercaptan sulfur and residual organic chloride. The treated crude oil containing residual organic chloride is brought in contact with a caustic solution at a molar ratio of caustic to chloride of 0.1:1 to 50:1, generating an upgraded crude oil with less than 10 ppm organic chloride. In one embodiment, the spent treating solution is recycled to form a regenerated hypochlorite stream for use in the treatment solution.

    摘要翻译： 公开了一种降低原油中硫醇浓度的方法。 该方法包括使粗品与包含次氯酸盐溶液的处理溶液接触，由此硫醇硫被氧化并转化成至少一种含硫的含硫酸或其盐，产生具有小于50ppm硫醇硫和残余的有机氯化物的经处理的原油。 含有残余有机氯化物的处理过的原油与苛性碱溶液以0.1:1至50:1的苛性碱与氯化物的摩尔比接触，产生具有小于10ppm有机氯化物的升级原油。 在一个实施方案中，废处理溶液被再循环以形成用于处理溶液的再生次氯酸盐流。

    Method for reducing mercaptans in hydrocarbons
    7.
    发明授权
    Method for reducing mercaptans in hydrocarbons 有权
    降低碳氢化合物中硫醇的方法

    公开(公告)号：US09296956B2

    公开(公告)日：2016-03-29

    申请号：US13281114

    申请日：2011-10-25

    申请人： Lin Li ,  Zunqing He ,  Zhen Zhou ,  King T. Ng ,  Paul E. Hajdu

    发明人： Lin Li ,  Zunqing He ,  Zhen Zhou ,  King T. Ng ,  Paul E. Hajdu

    IPC分类号： C10G27/02 ,  C10G17/07 ,  C10G19/02 ,  C10G53/10 ,  C10G53/12

    CPC分类号： C10G17/07 ,  C10G19/02 ,  C10G53/10 ,  C10G53/12 ,  C10G2300/1033 ,  C10G2300/202

    摘要： A method for reducing mercaptan concentration in a crude oil is disclosed. The method comprises contacting the crude with a treating solution comprising a hypochlorite solution, whereby the mercaptan sulfur is oxidized and converted to at least one sulfur oxoacid or salt thereof, yielding a treated crude oil having less than 50 ppm mercaptan sulfur and residual organic chloride. The treated crude oil containing residual organic chloride is brought in contact with a caustic solution at a molar ratio of caustic to chloride of 0.1:1 to 50:1, generating an upgraded crude oil with less than 10 ppm organic chloride. In one embodiment, the spent treating solution is recycled to form a regenerated hypochlorite stream for use in the treatment solution.

    摘要翻译： 公开了一种降低原油中硫醇浓度的方法。 该方法包括使粗品与包含次氯酸盐溶液的处理溶液接触，由此硫醇硫被氧化并转化成至少一种含硫的含硫酸或其盐，产生具有小于50ppm硫醇硫和残余的有机氯化物的经处理的原油。 含有残余有机氯化物的处理过的原油与苛性碱溶液以0.1:1至50:1的苛性碱与氯化物的摩尔比接触，产生具有小于10ppm有机氯化物的升级原油。 在一个实施方案中，废处理溶液被再循环以形成用于处理溶液的再生次氯酸盐流。

    Method for Reducing Mercaptans in Hydrocarbons
    8.
    发明申请
    Method for Reducing Mercaptans in Hydrocarbons 审中-公开
    减少碳氢化合物中硫醇的方法

    公开(公告)号：US20120103871A1

    公开(公告)日：2012-05-03

    申请号：US12914275

    申请日：2010-10-28

    申请人： Zunqing He ,  Zhen Zhou ,  Lin Li

    发明人： Zunqing He ,  Zhen Zhou ,  Lin Li

    IPC分类号： C10G27/02 ,  C10G19/00 ,  C10G27/00

    CPC分类号： C10G27/02 ,  C10G27/06 ,  C10G33/00 ,  C10G2300/1033 ,  C10G2300/202 ,  C10G2400/08

    摘要： A method for reducing mercaptan concentration in a liquid hydrocarbon, comprising: contacting a mercaptan-rich liquid hydrocarbon having a first concentration of mercaptan sulfur with a composition comprising an oxidizing agent and water wherein the molar ratio of the oxidizing agent to mercaptan sulfur in the mercaptan-rich liquid hydrocarbon is from 3:1 to 10:1; and separating the water from the liquid hydrocarbon to yield a mercaptan-depleted liquid hydrocarbon having a second concentration of mercaptan sulfur, the second concentration being less than the first concentration; wherein a major amount of mercaptan compounds in the mercaptan-rich liquid hydrocarbon are converted to at least one sulfur oxoacid or salt thereof, having the formula: [RSOx]nY wherein R is a hydrocarbyl group; x is an integer from 1 to 3; n is 1 or 2; and Y is hydrogen, an alkaline metal, or alkaline earth metal.

    摘要翻译： 一种用于降低液体烃中硫醇浓度的方法，包括：使具有第一浓度的硫醇硫的富硫醇液体烃与包含氧化剂和水的组合物接触，其中硫醇中的氧化剂与硫醇的摩尔比 富液体烃为3：1至10：1; 并从液态烃中分离出水，得到具有第二浓度的硫醇硫的硫醇贫化液态烃，第二浓度小于第一浓度; 其中所述富硫醇溶液中的主要量的硫醇化合物被转化成至少一种具有下式的硫代酸或其盐：其中R是烃基的[RSO x] n Y; x是1至3的整数; n为1或2; Y是氢，碱金属或碱土金属。