公开(公告)号：US20110144248A1

公开(公告)日：2011-06-16

申请号：US12798832

申请日：2010-04-13

申请人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz ,  Herve Adam

发明人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz ,  Herve Adam

IPC分类号： C08K5/1515

CPC分类号： C08K5/0008 ,  C08K5/06 ,  C09D5/024 ,  C09D7/63 ,  C08L21/02

摘要： Disclosed are low Tg latex polymers and low VOC aqueous coating compositions having an improved open time profile, as well as drying time, stain resistance, wet edge time, low temperature film formation, block resistance, adhesion, water sensitivity and low-VOC content. The latex polymers and aqueous coating compositions include at least one latex polymer derived from at least one monomer copolymerized or alkoxylated compounds or blended with an alkoxylated compound, for example an alkoxylated tristyrylphenol or an alkoxylated tributylphenol. Also provided is an aqueous coating or adhesive composition including at least one latex polymer, water and one or a blend of two or more open time additives or drying time additives. The blend can comprise nonionic and anionic open time additives. Typically, the open time and/or drying time additive is present in an amount greater than about 1.3% by weight of the polymer or composition, typically in an amount greater than about 2% by weight of the polymer or composition, in an amount greater than about 4% by weight of the polymer or composition, in an amount greater than about 7.5% by weight of the polymer or composition, in an amount greater than about 10% by weight of the polymer or composition or in an amount greater than about 20% by weight of the polymer or composition.

摘要翻译： 公开了低Tg胶乳聚合物和低VOC水性涂料组合物，其具有改进的开放时间曲线，以及干燥时间，耐污染性，湿边缘时间，低温成膜，阻块性，粘附性，水敏感性和低VOC含量。 胶乳聚合物和水性涂料组合物包括至少一种衍生自至少一种单体共聚或烷氧基化化合物的胶乳聚合物或与烷氧基化化合物，例如烷氧基化三苯乙烯基苯酚或烷氧基化三丁基苯酚共混。 还提供了包含至少一种胶乳聚合物，水和两种或更多种开放时间添加剂或干燥时间添加剂的一种或共混物的水性涂料或粘合剂组合物。 共混物可以包含非离子和阴离子开放时间添加剂。 通常，开放时间和/或干燥时间添加剂以大于聚合物或组合物的约1.3重量％的量存在，其量通常大于聚合物或组合物的约2重量％，其量更大 大于约4重量％的聚合物或组合物，其量大于聚合物或组合物的约7.5重量％，其量大于聚合物或组合物的约10重量％或大于约 20重量％的聚合物或组合物。

公开(公告)号：US08304479B2

公开(公告)日：2012-11-06

申请号：US12798832

申请日：2010-04-13

申请人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz ,  Herve Adam

发明人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz ,  Herve Adam

IPC分类号： C08K5/06

CPC分类号： C08K5/0008 ,  C08K5/06 ,  C09D5/024 ,  C09D7/63 ,  C08L21/02

摘要： Disclosed are low Tg latex polymers and low VOC aqueous coating compositions having an improved open time profile, as well as drying time, stain resistance, wet edge time, low temperature film formation, block resistance, adhesion, water sensitivity and low-VOC content. The latex polymers and aqueous coating compositions include at least one latex polymer derived from at least one monomer copolymerized or alkoxylated compounds or blended with an alkoxylated compound, for example an alkoxylated tristyrylphenol or an alkoxylated tributylphenol. Also provided is an aqueous coating or adhesive composition including at least one latex polymer, water and one or a blend of two or more open time additives or drying time additives. The blend can comprise nonionic and anionic open time additives. Typically, the open time and/or drying time additive is present in an amount greater than about 1.3% by weight of the polymer or composition, typically in an amount greater than about 2% by weight of the polymer or composition, in an amount greater than about 4% by weight of the polymer or composition, in an amount greater than about 7.5% by weight of the polymer or composition, in an amount greater than about 10% by weight of the polymer or composition or in an amount greater than about 20% by weight of the polymer or composition.

摘要翻译： 公开了低Tg胶乳聚合物和低VOC水性涂料组合物，其具有改进的开放时间曲线，以及干燥时间，耐污染性，湿边缘时间，低温成膜，阻块性，粘附性，水敏感性和低VOC含量。 胶乳聚合物和水性涂料组合物包括至少一种衍生自至少一种单体共聚或烷氧基化化合物的胶乳聚合物或与烷氧基化化合物，例如烷氧基化三苯乙烯基苯酚或烷氧基化三丁基苯酚共混。 还提供了包含至少一种胶乳聚合物，水和两种或更多种开放时间添加剂或干燥时间添加剂的一种或共混物的水性涂料或粘合剂组合物。 共混物可以包含非离子和阴离子开放时间添加剂。 通常，开放时间和/或干燥时间添加剂以大于聚合物或组合物的约1.3重量％的量存在，其量通常大于聚合物或组合物的约2重量％，其量更大 大于约4重量％的聚合物或组合物，其量大于聚合物或组合物的约7.5重量％，其量大于聚合物或组合物的约10重量％或大于约 20重量％的聚合物或组合物。

公开(公告)号：US20110086961A1

公开(公告)日：2011-04-14

申请号：US12973316

申请日：2010-12-20

申请人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz

发明人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz

IPC分类号： C08K5/06

CPC分类号： C09D133/02 ,  C08F2/24 ,  C08K5/0008 ,  C09D133/08 ,  C08F2220/1825 ,  C08F220/14 ,  C08F220/06

摘要： Disclosed are latex polymers and an aqueous coating compositions having excellent freeze-thaw stability, open time, stain resistance, low temperature film formation, foam resistance, block resistance, adhesion, water sensitivity and a low-VOC content. The latex polymers and aqueous coating compositions include at least one latex polymer derived from at least one monomer copolymerized or blended with an alkoxylated compound, for example an alkoxylated tristyrylphenol or an alkoxylated tributylphenol. Also provided is an aqueous coating composition including at least one latex polymer, at least one pigment, water and at least one freeze-thaw additive. Typically, the freeze-thaw additive in an amount greater than about 1.3% by weight of the polymer, typically in an amount greater than about 2% by weight of the polymer, in an amount greater than about 4% by weight of the polymer, in an amount greater than about 7.5% by weight of the polymer, in an amount greater than about 10% by weight of the polymer or in an amount greater than about 20% by weight of the polymer.

摘要翻译： 公开了胶乳聚合物和具有优异的冻融稳定性，开放时间，耐污染性，低温成膜，耐泡沫性，抗粘连性，粘附性，水敏感性和低VOC含量的水性涂料组合物。 胶乳聚合物和水性涂料组合物包括至少一种衍生自至少一种与烷氧基化化合物共聚或共混的单体的胶乳聚合物，例如烷氧基化三苯乙烯基苯酚或烷氧基化三丁基苯酚。 还提供了包含至少一种胶乳聚合物，至少一种颜料，水和至少一种冻融添加剂的水性涂料组合物。 通常，大于约1.3重量％的聚合物的冻融添加剂，其量通常大于聚合物的约2重量％，其量大于聚合物的约4重量％ 其量大于聚合物的约7.5重量％，其量大于聚合物的约10重量％，或大于聚合物重量的约20重量％。

公开(公告)号：US07906577B2

公开(公告)日：2011-03-15

申请号：US12321214

申请日：2009-01-16

申请人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz

发明人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz

IPC分类号： C08K3/22 ,  C08K5/13

CPC分类号： C09D133/02 ,  C08F2/24 ,  C08K5/0008 ,  C09D133/08 ,  C08F2220/1825 ,  C08F220/14 ,  C08F220/06

摘要： Disclosed are latex polymers and an aqueous coating compositions having excellent freeze-thaw stability, open time, stain resistance, low temperature film formation, foam resistance, block resistance, adhesion, water sensitivity and a low-VOC content. The latex polymers and aqueous coating compositions include at least one latex polymer derived from at least one monomer copolymerized or blended with an alkoxylated compound, for example an alkoxylated tristyrylphenol or an alkoxylated tributylphenol. Also provided is an aqueous coating composition including at least one latex polymer, at least one pigment, water and at least one freeze-thaw additive. Typically, the freeze-thaw additive in an amount greater than about 1.3% by weight of the polymer, typically in an amount greater than about 2% by weight of the polymer, in an amount greater than about 4% by weight of the polymer, in an amount greater than about 7.5% by weight of the polymer, in an amount greater than about 10% by weight of the polymer or in an amount greater than about 20% by weight of the polymer.

摘要翻译： 公开了胶乳聚合物和具有优异的冻融稳定性，开放时间，耐污染性，低温成膜，耐泡沫性，抗粘连性，粘附性，水敏感性和低VOC含量的水性涂料组合物。 胶乳聚合物和水性涂料组合物包括至少一种衍生自至少一种与烷氧基化化合物共聚或共混的单体的胶乳聚合物，例如烷氧基化三苯乙烯基苯酚或烷氧基化三丁基苯酚。 还提供了包含至少一种胶乳聚合物，至少一种颜料，水和至少一种冻融添加剂的水性涂料组合物。 通常，大于约1.3重量％的聚合物的冻融添加剂，其量通常大于聚合物的约2重量％，其量大于聚合物的约4重量％ 其量大于聚合物的约7.5重量％，其量大于聚合物的约10重量％，或大于聚合物重量的约20重量％。

公开(公告)号：US20100016485A1

公开(公告)日：2010-01-21

申请号：US12586486

申请日：2009-09-23

申请人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz

发明人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz

IPC分类号： C08K5/06 ,  C07C213/00 ,  C08K5/524 ,  C08K5/53 ,  C08K5/42 ,  C07C305/12 ,  C07C303/22 ,  C07F9/09 ,  C07C255/32 ,  C07F9/32 ,  C07C59/00 ,  C07C41/00

CPC分类号： C09D133/02 ,  C08F2/24 ,  C08K5/0008 ,  C09D133/08 ,  C08F2220/1825 ,  C08F220/14 ,  C08F220/06

摘要： Disclosed are latex polymers and an aqueous coating compositions having excellent freeze-thaw stability, open time, stain resistance, low temperature film formation, foam resistance, block resistance, adhesion, water sensitivity and a low-VOC content. The latex polymers and aqueous coating compositions include at least one latex polymer derived from at least one monomer copolymerized or blended with an alkoxylated compound, for example an alkoxylated tristyrylphenol or an alkoxylated tributylphenol. Also provided is an aqueous coating composition including at least one latex polymer, at least one pigment, water and at least one freeze-thaw additive. Typically, the freeze-thaw additive in an amount greater than about 1.3% by weight of the polymer, typically in an amount greater than about 2% by weight of the polymer, in an amount greater than about 4% by weight of the polymer, in an amount greater than about 7.5% by weight of the polymer, in an amount greater than about 10% by weight of the polymer or in an amount greater than about 20% by weight of the polymer.

摘要翻译： 公开了胶乳聚合物和具有优异的冻融稳定性，开放时间，耐污染性，低温成膜，耐泡沫性，抗粘连性，粘附性，水敏感性和低VOC含量的水性涂料组合物。 胶乳聚合物和水性涂料组合物包括至少一种衍生自至少一种与烷氧基化化合物共聚或共混的单体的胶乳聚合物，例如烷氧基化三苯乙烯基苯酚或烷氧基化三丁基苯酚。 还提供了包含至少一种胶乳聚合物，至少一种颜料，水和至少一种冻融添加剂的水性涂料组合物。 通常，大于约1.3重量％的聚合物的冻融添加剂，其量通常大于聚合物的约2重量％，其量大于聚合物的约4重量％ 其量大于聚合物的约7.5重量％，其量大于聚合物的约10重量％，或大于聚合物重量的约20重量％。

公开(公告)号：US09388323B2

公开(公告)日：2016-07-12

申请号：US12321256

申请日：2009-01-16

申请人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz

发明人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz

IPC分类号： C08F12/04 ,  C08F16/22 ,  C08F20/36 ,  C09D133/02 ,  C07C43/23 ,  C08F2/24 ,  C09D133/08 ,  C08K5/00

CPC分类号： C09D133/02 ,  C07C43/23 ,  C08F2/24 ,  C08K5/0008 ,  C09D133/08 ,  Y10T428/2982 ,  C08F2220/1825 ,  C08F220/14 ,  C08F220/06

摘要： Disclosed are latex polymers and an aqueous coating compositions having excellent freeze-thaw stability, open time, stain resistance, low temperature film formation, foam resistance, block resistance, adhesion, water sensitivity and a low-VOC content. The latex polymers and aqueous coating compositions include at least one latex polymer derived from at least one monomer copolymerized or blended with an alkoxylated compound, for example an alkoxylated tristyrylphenol or an alkoxylated tributylphenol. Also provided is an aqueous coating composition including at least one latex polymer, at least one pigment, water and at least one freeze-thaw additive. Typically, the freeze-thaw additive in an amount greater than about 1.3% by weight of the polymer, typically in an amount greater than about 2% by weight of the polymer, in an amount greater than about 4% by weight of the polymer, in an amount greater than about 7.5% by weight of the polymer, in an amount greater than about 10% by weight of the polymer or in an amount greater than about 20% by weight of the polymer.

公开(公告)号：US20090186972A1

公开(公告)日：2009-07-23

申请号：US12321214

申请日：2009-01-16

申请人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz

发明人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz

IPC分类号： C08K5/06

CPC分类号： C09D133/02 ,  C08F2/24 ,  C08K5/0008 ,  C09D133/08 ,  C08F2220/1825 ,  C08F220/14 ,  C08F220/06

摘要： Disclosed are latex polymers and an aqueous coating compositions having excellent freeze-thaw stability, open time, stain resistance, low temperature film formation, foam resistance, block resistance, adhesion, water sensitivity and a low-VOC content. The latex polymers and aqueous coating compositions include at least one latex polymer derived from at least one monomer copolymerized or blended with an alkoxylated compound, for example an alkoxylated tristyrylphenol or an alkoxylated tributylphenol. Also provided is an aqueous coating composition including at least one latex polymer, at least one pigment, water and at least one freeze-thaw additive. Typically, the freeze-thaw additive in an amount greater than about 1.3% by weight of the polymer, typically in an amount greater than about 2% by weight of the polymer, in an amount greater than about 4% by weight of the polymer, in an amount greater than about 7.5% by weight of the polymer, in an amount greater than about 10% by weight of the polymer or in an amount greater than about 20% by weight of the polymer.

摘要翻译： 公开了胶乳聚合物和具有优异的冻融稳定性，开放时间，耐污染性，低温成膜，耐泡沫性，抗粘连性，粘附性，水敏感性和低VOC含量的水性涂料组合物。 胶乳聚合物和水性涂料组合物包括至少一种衍生自至少一种与烷氧基化化合物共聚或共混的单体的胶乳聚合物，例如烷氧基化三苯乙烯基苯酚或烷氧基化三丁基苯酚。 还提供了包含至少一种胶乳聚合物，至少一种颜料，水和至少一种冻融添加剂的水性涂料组合物。 通常，大于约1.3重量％的聚合物的冻融添加剂，其量通常大于聚合物的约2重量％，其量大于聚合物的约4重量％ 其量大于聚合物的约7.5重量％，其量大于聚合物的约10重量％，或大于聚合物重量的约20重量％。

公开(公告)号：US08889774B2

公开(公告)日：2014-11-18

申请号：US12586486

申请日：2009-09-23

申请人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz

发明人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz

IPC分类号： C08K5/00 ,  C08K5/526 ,  C08K5/51 ,  C08K5/19 ,  C08K5/41 ,  C08K5/42 ,  C08K5/09 ,  C08K5/06 ,  C09D133/02

CPC分类号： C09D133/02 ,  C08F2/24 ,  C08K5/0008 ,  C09D133/08 ,  C08F2220/1825 ,  C08F220/14 ,  C08F220/06

摘要： Disclosed are latex polymers and an aqueous coating compositions having excellent freeze-thaw stability, open time, stain resistance, low temperature film formation, foam resistance, block resistance, adhesion, water sensitivity and a low-VOC content. The latex polymers and aqueous coating compositions include at least one latex polymer derived from at least one monomer copolymerized or blended with an alkoxylated compound, for example an alkoxylated tristyrylphenol or an alkoxylated tributylphenol. Also provided is an aqueous coating composition including at least one latex polymer, at least one pigment, water and at least one freeze-thaw additive. Typically, the freeze-thaw additive in an amount greater than about 1.3% by weight of the polymer, typically in an amount greater than about 2% by weight of the polymer, in an amount greater than about 4% by weight of the polymer, in an amount greater than about 7.5% by weight of the polymer, in an amount greater than about 10% by weight of the polymer or in an amount greater than about 20% by weight of the polymer.

摘要翻译： 公开了胶乳聚合物和具有优异的冻融稳定性，开放时间，耐污染性，低温成膜，耐泡沫性，抗粘连性，粘附性，水敏感性和低VOC含量的水性涂料组合物。 胶乳聚合物和水性涂料组合物包括至少一种衍生自至少一种与烷氧基化化合物共聚或共混的单体的胶乳聚合物，例如烷氧基化三苯乙烯基苯酚或烷氧基化三丁基苯酚。 还提供了包含至少一种胶乳聚合物，至少一种颜料，水和至少一种冻融添加剂的水性涂料组合物。 通常，大于约1.3重量％的聚合物的冻融添加剂，其量通常大于聚合物的约2重量％，其量大于聚合物的约4重量％ 其量大于聚合物的约7.5重量％，其量大于聚合物的约10重量％，或大于聚合物重量的约20重量％。

公开(公告)号：US08580883B2

公开(公告)日：2013-11-12

申请号：US12973316

申请日：2010-12-20

申请人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz

发明人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz

IPC分类号： C08K3/22 ,  C08K5/06

CPC分类号： C09D133/02 ,  C08F2/24 ,  C08K5/0008 ,  C09D133/08 ,  C08F2220/1825 ,  C08F220/14 ,  C08F220/06

摘要： Disclosed are latex polymers and an aqueous coating compositions having excellent freeze-thaw stability, open time, stain resistance, low temperature film formation, foam resistance, block resistance, adhesion, water sensitivity and a low-VOC content. The latex polymers and aqueous coating compositions include at least one latex polymer derived from at least one monomer copolymerized or blended with an alkoxylated compound, for example an alkoxylated tristyrylphenol or an alkoxylated tributylphenol. Also provided is an aqueous coating composition including at least one latex polymer, at least one pigment, water and at least one freeze-thaw additive.

摘要翻译： 公开了胶乳聚合物和具有优异的冻融稳定性，开放时间，耐污染性，低温成膜，耐泡沫性，抗粘连性，粘附性，水敏感性和低VOC含量的水性涂料组合物。 胶乳聚合物和水性涂料组合物包括至少一种衍生自至少一种与烷氧基化化合物共聚或共混的单体的胶乳聚合物，例如烷氧基化三苯乙烯基苯酚或烷氧基化三丁基苯酚。 还提供了包含至少一种胶乳聚合物，至少一种颜料，水和至少一种冻融添加剂的水性涂料组合物。

公开(公告)号：US20090186968A1

公开(公告)日：2009-07-23

申请号：US12321256

申请日：2009-01-16

申请人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz

发明人： Zhengang Zong ,  Yi-Zhong Li ,  Jose Ruiz

IPC分类号： C08K5/5333 ,  C08F12/24 ,  C08L33/08 ,  C08K5/06 ,  C08K5/521 ,  C08K5/41 ,  B32B5/02

CPC分类号： C09D133/02 ,  C07C43/23 ,  C08F2/24 ,  C08K5/0008 ,  C09D133/08 ,  Y10T428/2982 ,  C08F2220/1825 ,  C08F220/14 ,  C08F220/06

摘要： Disclosed are latex polymers and an aqueous coating compositions having excellent freeze-thaw stability, open time, stain resistance, low temperature film formation, foam resistance, block resistance, adhesion, water sensitivity and a low-VOC content. The latex polymers and aqueous coating compositions include at least one latex polymer derived from at least one monomer copolymerized or blended with an alkoxylated compound, for example an alkoxylated tristyrylphenol or an alkoxylated tributylphenol. Also provided is an aqueous coating composition including at least one latex polymer, at least one pigment, water and at least one freeze-thaw additive. Typically, the freeze-thaw additive in an amount greater than about 1.3% by weight of the polymer, typically in an amount greater than about 2% by weight of the polymer, in an amount greater than about 4% by weight of the polymer, in an amount greater than about 7.5% by weight of the polymer, in an amount greater than about 10% by weight of the polymer or in an amount greater than about 20% by weight of the polymer.

摘要翻译： 公开了胶乳聚合物和具有优异的冻融稳定性，开放时间，耐污染性，低温成膜，耐泡沫性，抗粘连性，粘附性，水敏感性和低VOC含量的水性涂料组合物。 胶乳聚合物和水性涂料组合物包括至少一种衍生自至少一种与烷氧基化化合物共聚或共混的单体的胶乳聚合物，例如烷氧基化三苯乙烯基苯酚或烷氧基化三丁基苯酚。 还提供了包含至少一种胶乳聚合物，至少一种颜料，水和至少一种冻融添加剂的水性涂料组合物。 通常，大于约1.3重量％的聚合物的冻融添加剂，其量通常大于聚合物的约2重量％，其量大于聚合物的约4重量％ 其量大于聚合物的约7.5重量％，其量大于聚合物的约10重量％，或大于聚合物重量的约20重量％。