摘要:
A polyisocyanate production method that can allow effective use of hydrogen chloride produced secondarily in a polyisocyanate production process, while allowing reduction of environmental burdens, and a polyisocyanate production system for performing the polyisocyanate production method. After chlorine is allowed to react with carbon monoxide to produce carbonyl chloride in a carbonyl chloride producing reactor, the carbonyl chloride produced in the carbonyl chloride producing reactor is allowed to react with polyamine in an isocyanate producing reactor to produce polyisocyanate. Then, after hydrochloric gas produced secondarily in the isocyanate producing reactor is purified in a hydrogen chloride purifying column, the purified hydrochloric gas is oxidized in a hydrogen chloride oxidizing reactor to produce chlorine. Thereafter, the chlorine thus produced is supplied to the carbonyl chloride producing reactor from a chlorine resupply line, so that it is allowed to react with carbon monoxide to produce carbonyl chloride.
摘要:
A terminal isocyanate group-containing polyamide resin can be produced by reacting a terminal carboxyl group-containing oligomer and a polyisocyanate compound at such a ratio that the amount of an isocyanate group exceeds that of a carboxyl group. An alkoxysilane-modified polyamide resin can be produced by reacting the terminal isocyanate group-containing polyamide resin with an alkoxysilane compound containing a secondary amine.
摘要:
A concentrating method and a concentrating system for concentrating polyisocyanate residues that that can effectively concentrate polyisocyanate residues from crude polyisocyanate comprising polyisocyanate and polyisocyanate residues in a short time and can also suppress increase in viscosity to provide stable transport of the residues and prevent blockage of the transport line, and a treating method and a treating system for decomposing the concentrated components to polyamine.The polyisocyanate residues are first heated on the boil by the distiller to be concentrated to a midterm concentrating rate, and then, the polyisocyanate residues are concentrated to the final concentrating rate by evaporation using a evaporator. This can allow the polyisocyanate residues to be decomposed to polyamine to be recovered by setting a Cl content of a high boiling point distillate fraction concentrated to be not more than 2 weight % and then putting the high boiling point distillate fraction into contact with high temperature and high pressure water to be hydrolyzed by the decomposing apparatus.
摘要:
A polyisocyanate production method that can allow effective use of hydrogen chloride produced secondarily in a polyisocyanate production process, while allowing reduction of environmental burdens, and a polyisocyanate production system for performing the polyisocyanate production method. After chlorine is allowed to react with carbon monoxide to produce carbonyl chloride in a carbonyl chloride producing reactor, the carbonyl chloride produced in the carbonyl chloride producing reactor is allowed to react with polyamine in an isocyanate producing reactor to produce polyisocyanate. Then, after hydrochloric gas produced secondarily in the isocyanate producing reactor is purified in a hydrogen chloride purifying column, the purified hydrochloric gas is oxidized in a hydrogen chloride oxidizing reactor to produce chlorine. Thereafter, the chlorine thus produced is supplied to the carbonyl chloride producing reactor from a chlorine resupply line, so that it is allowed to react with carbon monoxide to produce carbonyl chloride.
摘要:
A flexible polyurethane foam produced by contacting the polyol composition (A) comprising a polyether polyol (an amine value: 400 to 600 mg KOH/g, a hydroxyl value: 350 to 700 mg KOH/g), which is the adduct of an alkylene oxide to a compound selected from following formulas (1) and (2), with an organic polyisocyanate in the presence of water wherein R1 and R2 represent H or (CH)n—NH2 (n: 1-3), R3-R6 and R7 represent H or an alkyl group or alkenyl group having 1 to 4 carbon atoms, and k and m represent 1 to 6. The flexible polyurethane foam exhibits sufficient physical properties and reduced volatile amine components. The flexible polyurethane foam can be used to provide excellent seat pads and sound absorbing materials for automobiles.
摘要:
A gas treatment apparatus for treating a gas by bringing the gas into contact with a treatment liquid. The gas treatment apparatus includes a gas-liquid contact chamber for a gas-liquid contact of the gas with the treatment liquid, a storage chamber, located over the gas-liquid contact chamber, for storing the treatment liquid, and a treatment liquid supplying unit for supplying the treatment liquid stored in the storage chamber to an inside of the gas-liquid contact chamber with a gravity-drop.
摘要:
The polyurethane foam composition of the present invention comprises at least water, a catalyst, a surfactant, a polyisocyanate, and a polyol and/or a polymer-dispersed polyol in which polymer fine particles obtained by polymerizing a compound having an unsaturated bond are dispersed in a polyol, wherein the polyol comprises at least (A) a plant-derived polyol produced by using a raw material obtained from plants and (B) a low-monol polyol having an overall degree of unsaturation of 0.050 meq/g or less. The polyurethane foam relating to the present invention is obtained by foaming this polyurethane foam composition. The polyurethane foam contributes to reducing environmental burdens and attains hardness and ball rebound suitable for a cushioning material and excellent durability in a balanced manner.
摘要:
Polyurethane resin compositions include a urethane prepolymer with an active hydrogen group and a polyisocyanate, or a urethane prepolymer with an isocyanate group and an active hydrogen compound. The urethane prepolymers having an active hydrogen group or an isocyanate group are obtained by reacting an allophanate group-containing polyisocyanate with a side-chain hydrocarbon group of 5 or more carbon atoms and a bifunctional or polyfunctional active hydrogen compound. Particularly preferably, the allophanate group-containing polyisocyanate is obtained by reacting a C5 or higher carbon number compound having an alcoholic hydroxyl group and an organic diisocyanate, in the presence of an organic bismuth carboxylate and an organic phosphite triester. The polyurethane resin compositions are suited for use as adhesives for bonding low-polarity resin bases such as polyolefin films.
摘要:
A laminating adhesive includes a polyol; an acid-modified polyol obtained by reaction of a hydrophobic polyol containing a hydrocarbon moiety having 12 to 80 carbon atoms in its molecule in an amount of 30 to 95% by weight or a derivative thereof with an aromatic polycarboxylic acid anhydride and having a carboxyl group at a molecular terminal thereof; an organic polyisocyanate compound; and a silane coupling agent.A laminating adhesive film is excellent even after high-temperature sterilization treatment in adhesion performance between a metal foil or a barrier film and a plastic film serving as an inner layer, and also in adhesion performance between a metal foil or a barrier film and a plastic film serving as an outer layer.
摘要:
The present invention relates to a method for decomposing and recovering an isocyanate compound, which comprises: continuously mixing and dispersing into water at high pressure and high temperature an isocyanate compound having at least one isocyanate group or group derived from an isocyanate group in a molten state or solution state, supplying a liquid mixture containing the isocyanate compound and the water at high pressure and high temperature continuously to a reactor, followed by subjecting the isocyanate compound to a decomposition reaction in the reactor, and recovering a raw material for the isocyanate compound or a derivative thereof; and an apparatus for decomposing and recovering an isocyanate compound, which comprises: a reactor which brings water at high pressure and high temperature into contact with an isocyanate compound having at least one isocyanate group or group derived from an isocyanate group to cause a decomposition reaction, a water supply line which continuously supplies the water at high pressure and high temperature to a reactor, a compound supply line which continuously supplies the isocyanate compound in a molten state or solution state to the water supply line, an on-off valve which communicates the compound supply line with a vicinity of a communication portion of the water supply line to the reactor, a dehydrating device which conducts a dehydration of a decomposition reaction product discharged from the reactor, and a purification device which purifies the decomposition reaction product after the dehydration.