公开(公告)号：US5605631A

公开(公告)日：1997-02-25

申请号：US467181

申请日：1995-06-06

申请人： Sami A. I. Barri ,  Graham J. Bratton ,  Timothy d. Naylor

发明人： Sami A. I. Barri ,  Graham J. Bratton ,  Timothy d. Naylor

IPC分类号： B01D71/02 ,  B01J29/04 ,  B01J29/06 ,  B01J29/80 ,  B01J35/06 ,  C01B39/38 ,  B01D61/14

CPC分类号： B01D67/0051 ,  B01D67/0048 ,  B01D69/10 ,  B01D71/028 ,  B01J29/04 ,  B01D2323/46 ,  B01J2229/64 ,  B01J2229/66 ,  B01J35/06 ,  Y10S95/902

摘要： Novel membranes comprise crystals of a zeo-type material carried by a porous support. The crystal growth of the zeo-type material is essentially continuous over the pores of the support and the zeo-type material is crystallized directly from and bonds directly to the support. Membranes may be prepared by immersing the support in a synthesis gel, crystallizing the gel, removing the support, and repeating these steps at least once.

摘要翻译： 新型膜包含由多孔载体承载的锌型材料的晶体。 锌型材料的晶体生长在支撑体的孔隙上基本上是连续的，并且锌型材料直接从载体结晶并直接结合到载体上。 可以通过将载体浸入合成凝胶中，结晶凝胶，除去载体并重复这些步骤至少一次来制备膜。

公开(公告)号：US5344976A

公开(公告)日：1994-09-06

申请号：US72365

申请日：1993-06-03

申请人： Michael D. Jones ,  Derrick J. Watson ,  Bruce L. Williams

发明人： Michael D. Jones ,  Derrick J. Watson ,  Bruce L. Williams

IPC分类号： B01J39/04 ,  C07B63/00 ,  C07C51/12 ,  C07C51/47 ,  C07C51/573 ,  C07C53/08 ,  C07C53/12 ,  C07C53/122 ,  C07C53/124 ,  C07C53/126

CPC分类号： C07C51/573 ,  C07C51/47

摘要： In a process for removing iodide compounds from a liquid composition comprising carboxylic acids having 2 to 6 carbon atoms or anhydrides thereof, by passing the liquid composition through a silver, mercury, palladium and/or rhodium-exchanged strong acid cation exchange resin, prior to contacting with the metal-exchanged resin the composition is contacted with a cation exchanger in the acid form to remove at least a portion of the metal ion contaminants in the liquid composition which have been found to displace the silver, mercury, palladium and/or rhodium from the metal-exchanged resin.

摘要翻译： 在通过使液体组合物通过银，汞，钯和/或铑交换的强酸阳离子交换树脂从包含具有2至6个碳原子的羧酸或其酸酐的液体组合物中除去碘化合物的方法中， 与金属交换的树脂接触，使组合物与酸形式的阳离子交换剂接触以除去液态组合物中已发现取代银，汞，钯和/或铑的至少一部分金属离子污染物 从金属交换树脂。

公开(公告)号：US5336826A

公开(公告)日：1994-08-09

申请号：US944939

申请日：1986-12-22

申请人： John H. Brophy ,  Steven R. Wade

发明人： John H. Brophy ,  Steven R. Wade

IPC分类号： C07B61/00 ,  B01J23/00 ,  B01J23/04 ,  C07C1/00 ,  C07C2/84 ,  C07C9/06 ,  C07C11/04 ,  C07C67/00 ,  C07C2/00

CPC分类号： B01J23/04 ,  C07C2/84 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/10 ,  C07C2523/12 ,  C07C2523/20 ,  Y10S585/943

摘要： Higher hydrocarbons are produced from methane by reacting the methane at elevated temperature, suitably in the range from 600.degree. to 800.degree. C., with an oxygen-containing gas having a ratio of methane to oxygen of greater than the stoichiometric ratio for complete combustion in the presence as catalyst of a lithium-doped material which under the reaction conditions is a physically base-stable, non-melting, oxygen-stable compound of an element of Groups III to VIII of the Periodic Table of the Elements including the rare earth elements.

摘要翻译： 通过使甲烷在适宜的温度范围为600-800℃的甲烷与甲烷与氧的比例大于完全燃烧的化学计量比使甲烷与甲烷反应生成高级烃。 作为催化剂的锂掺杂材料的存在，其在反应条件下是元素周期表第III至VIII族元素的物理基础稳定的，非熔融的，氧稳定的化合物，包括稀土元素 。

公开(公告)号：US5233064A

公开(公告)日：1993-08-03

申请号：US866645

申请日：1992-04-09

申请人： Neil A. Cooley

发明人： Neil A. Cooley

IPC分类号： B01J31/22 ,  C07F15/00 ,  C08G67/02

CPC分类号： C08G67/02 ,  C07F15/0066

摘要： Palladium complexes having the general formula Pd(R'CO.sub.2).sub.2 X where R' is C.sub.1 to C.sub.10 alkyl or C.sub.6 to C.sub.10 aryl and X is a chelating ligand of formula (R.sup.2).sub.2 PYP(R.sup.2).sub.2 where the R.sup.2 groups are independently selected from C.sub.1 to C.sub.4 alkyl, phenyl or alkoxy substituted phenyl, and Y is --(CH.sub.2).sub.n -- where n=2 to 4 are provided. The complexes may be prepared by reacting the compounds Pd(R'CO.sub.2).sub.2 and (R.sup.2).sub.2 PYP(R.sup.2).sub.2 together in an aromatic solvent at a temperature of less than 60.degree. C. in amounts such that the molar ratio of the two compounds is in the range 1.2:1 to 1:1.2.

公开(公告)号：US5210210A

公开(公告)日：1993-05-11

申请号：US694567

申请日：1991-05-02

申请人： Stephen G. Davies

发明人： Stephen G. Davies

IPC分类号： C07B53/00 ,  C07D233/32 ,  C07D233/38 ,  C07D233/42 ,  C07D235/02 ,  C07D235/26 ,  C07D235/28

CPC分类号： C07D235/02 ,  C07D233/32 ,  C07D233/38 ,  C07D233/42 ,  C07D235/26 ,  C07D235/28

摘要： Chiral imidazolidones and imidazolidinethiones having the general formula: ##STR1## where (a) Z is either oxygen or sulphur(b) the R groups are independently selected from hydrogen or R.sup.2 CO where R.sup.2 is C.sub.1 to C.sub.10 alkyl, C.sub.2 to C.sub.10 alkenyl or benzyl and(c) the two R.sup.1 groups are either (1) identical groups selected from C.sub.1 to C.sub.10 alkyl, phenyl or C.sub.1 to C.sub.6 alkyl or alkoxy substituted phenyl or (2) such that together they form an alkylene group of formula --(CH.sub.2).sub.n -- where n=3 to 8.Most preferred are those compounds where both R groups are R.sup.2 CO and there is a C.sub.2 axis of symmetry running along the CZ double bond. Compounds of formula (I) where at least one R group is R.sup.2 CO are efficient chiral auxiliaries for a range of asymmetric electrophilic substitution reactions when used in homochiral form. As such they are important tools for synthesising a range of chiral pharmaceuticals, agrochemicals and the like.

公开(公告)号：US5178837A

公开(公告)日：1993-01-12

申请号：US590045

申请日：1990-09-27

申请人： Russell I. Crisp

发明人： Russell I. Crisp

IPC分类号： G01N31/12 ,  G01N33/24

CPC分类号： G01N33/241 ,  G01N31/12

摘要： A rock analyser includes a chamber containing a heater (2) and the sensor (6) of a hydrocarbon detector (7), the heater (2) being connectable to a source of power (5) and the sensor (6) being connected to the remainder of the hydrocarbon detector (7). The analyser determines the amount of hydrocarbon material present in the rock. It is portable and is useful for field screening tests to reduce the number of samples sent for laboratory analysis.

摘要翻译： 岩石分析仪包括容纳加热器（2）和烃探测器（7）的传感器（6）的腔室，所述加热器（2）可连接到动力源（5），所述传感器（6）连接到 烃检测器（7）的其余部分。 分析仪确定岩石中存在的烃类物质的量。 它是便携式的，并且可用于现场筛选测试以减少发送用于实验室分析的样品数量。

公开(公告)号：US5145612A

公开(公告)日：1992-09-08

申请号：US704903

申请日：1991-05-21

申请人： Derek W. Reay ,  Stuart Fraser ,  Richard G. Heddle

发明人： Derek W. Reay ,  Stuart Fraser ,  Richard G. Heddle

IPC分类号： B01D3/00 ,  B01D3/20

CPC分类号： B01D3/008 ,  B01D3/20

摘要： The efficiency of mixing vapor in a countercurrent column (1) is improved by use of one or more vapor risers (6) each incorporating a mixing device (7). The method is suitable for use in countercurrent columns operating at high pressures or under vacuum. For high pressure operation a single riser is preferred positioned in the center of the distributor tray (5).

摘要翻译： 通过使用一个或多个各自包含混合装置（7）的蒸汽提升管（6）来提高在逆流柱（1）中混合蒸汽的效率。 该方法适用于在高压或真空下运行的逆流柱。 对于高压操作，单个提升管优选地定位在分配器托盘（5）的中心。

公开(公告)号：US5143109A

公开(公告)日：1992-09-01

申请号：US570052

申请日：1990-08-20

申请人： Spencer E. Taylor

发明人： Spencer E. Taylor

IPC分类号： B01D17/04 ,  C10G33/00

CPC分类号： B01D17/042 ,  C10G33/00 ,  Y10T137/0391

摘要： A method for recovering the surfactant from a dispersion or emulsion of oil and water containing a temperature sensitive surfactant which method comprises the steps of heating the dispersion or emulsion to a temperature above the cloud point of the surfactant under conditions of temperature and aqueous phase salinity such that the dispersion or emulsion breaks and separates into an oil layer, an aqueous layer and a surfactant layer, and recovering the surfactant layer.The recovered surfactant may be recycled for use in preparing further quantities of dispersion or emulsion, thus rendering the operation more economic.

公开(公告)号：US5118891A

公开(公告)日：1992-06-02

申请号：US739777

申请日：1991-07-30

申请人： Graham Butler ,  Malcolm P. Heyward

发明人： Graham Butler ,  Malcolm P. Heyward

IPC分类号： B01J23/58 ,  C07C1/04

CPC分类号： C07C1/0445 ,  B01J23/58 ,  C07C2523/04 ,  C07C2523/10 ,  C07C2523/46 ,  C07C2523/63

摘要： A composition for use after reductive activation as a catalyst in the conversion of synthesis gas to hydrocarbons, the composition having formula: Ru.sub.z A.sub.b CeO.sub.x, wherein A is an alkali metal, x is a number such that the valence requirements of the other elements for oxygen is satisfied, a is greater than zero and less than 5% w/w, based on the total weight of the composition, b is in the range from zero to 10% w/w, based on the total weight of the composition, and Ce and O constitute the remainder of the composition, is produced by the steps of: (A) adding a solution or solutions of soluble compounds of the metals ruthenium and cerium, and optionally also an alkali metal compound, to a solution of a precipitant comprising a carbonate and/or a bicarbonate and/or a hydroxide of an alkali metal or ammonium under conditions whereby there is formed a precipitate comprising ruthenium and cerium, and optionally also an alkali metal, in the form of compounds thermally decomposable to the metals and/or their oxides, and (B) recovering the precipitate obtained in step (A).

摘要翻译： 在将合成气转化为烃的还原活化后作为催化剂使用的组合物，具有式RuzAbCeOx的组合物，其中A是碱金属，x是满足其它元素对氧气的化合价要求的数 基于组合物的总重量，a大于零且小于5％w / w，b基于组合物的总重量，b在0至10％w / w的范围内，Ce和 O构成组合物的其余部分，是通过以下步骤制备的：（A）将金属钌和铈的可溶性化合物和任选的碱金属化合物的溶液或溶液加入到包含碳酸盐的沉淀剂的溶液中 和/或碱金属或铵的碳酸氢盐和/或氢氧化物，其中形成包含钌和铈的沉淀物，以及任选的碱金属，其形式为可热分解成金属的化合物 d /或其氧化物，和（B）回收步骤（A）中获得的沉淀物。

公开(公告)号：US5118483A

公开(公告)日：1992-06-02

申请号：US768452

申请日：1992-09-27

申请人： Sami I. Barri

发明人： Sami I. Barri

IPC分类号： C01G17/00 ,  B01J29/035 ,  B01J29/04 ,  B01J29/70 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  C01B37/02 ,  C01B39/04 ,  C01B39/12 ,  C01B39/26 ,  C01B39/48 ,  C07B61/00 ,  C07C1/00 ,  C07C1/20 ,  C07C2/86 ,  C07C4/06 ,  C07C11/02 ,  C07C15/02 ,  C07C15/08 ,  C07C51/353 ,  C07C57/04 ,  C07C67/00

CPC分类号： C01B39/48 ,  B01J29/04 ,  B01J29/70

摘要： A crystalline material having, in the dehydrated form the empirical formula:m(M.sub.2/a O): X.sub.z O.sub.xz/2 : yYO.sub.2 (I)in which m is 0.5 to 1.5; M is a cation of valency a; X is a metal of valency x, selected from aluminium, boron, gallium zinc, iron and titanium; z is 2 when x is an odd number, an z is 1 when x is an even number; y is at least 5; and Y is silicon or germanium; and having, in the calcined hydrogen form, an X-ray diffraction pattern including significant peaks substantially as shown in table I herein. The material has been designated SUZ-4.