摘要:
A three-product PSA system which produces three product streams from a feed gas mixture comprising a light key component, at least one heavy key component, and at least one intermediate key component is described. The three-product PSA system produces a high pressure product stream enriched in the light key component, a low pressure tail gas stream enriched in the at least one heavy key component, and an intermediate pressure vent gas stream enriched in the at least one intermediate key component.
摘要:
The present invention relates to large scale pressure swing adsorption systems (i.e., ranging from twelve to sixteen beds) utilizing new and advanced cycles to obtain enhanced hydrogen recovery from a hydrogen containing feed gas (i.e., synthesis gas).
摘要:
Process for producing hydrogen from a gas mixture comprising hydrogen, CO2, CO, CH4 and water, employing a CO2 PSA unit, a cryogenic unit and an H2 PSA unit, in which process: a) said gas mixture is introduced into the CO2 PSA unit, producing a CO2-enriched fraction and CO2-depleted fraction; b) CO2-enriched fraction is introduced into the cryogenic unit, producing a CO2-enriched fraction and an H2-enriched fraction; c) the H2-enriched fraction is recycled upstream of the H2 PSA unit; and d) the CO2-depleted fraction coming from step b) is introduced into the H2 PSA unit, producing a hydrogen-enriched stream and a waste gas.
摘要:
Pressure swing adsorption process for the separation of a feed gas mixture comprising (a) providing a pressure swing adsorption system comprising one or more composite beds, each composite bed comprising adsorbent material disposed in two or more vessels in parallel flow configuration, each vessel having a feed end and a product end; (b) performing cyclic sequential steps comprising adsorption/make product, withdrawing gas at decreasing pressure from the composite bed, purging the composite bed, and introducing gas into the composite bed at increasing pressure; and (c) for any of the sequential steps, setting a flow rate or flow rates of one or more gases selected from the group consisting of gas introduced into or withdrawn from the feed end or ends of any of the two or more vessels and gas introduced into or withdrawn from the product end or ends of any of the two or more vessels.
摘要:
The present invention generally relates to vacuum pressure swing adsorption (VPSA) processes and apparatus to recover carbon dioxide having a purity of approximately ≧90 mole % from streams containing at least carbon dioxide and hydrogen (e.g., syngas). The feed to the CO2 VPSA unit can be at super ambient pressure. The CO2 VPSA unit produces three streams, a H2-enriched stream, a H2-depleted stream and a CO2 product stream. When the CO2 VPSA unit is installed between an SMR/shift reactor and a H2 PSA unit, hydrogen recovery is expected to be increased by extracting CO2, thereby increasing hydrogen partial pressure in the H2 PSA feed. The recovered CO2 can be further upgraded, sequestered or used in applications such as enhanced oil recovery (EOR).
摘要:
A three-bed pressure swing adsorption system providing a constant continuous supply gas, preferably containing a hydrogen component, in a multi-step and preferably in a twelve-step, process cycle that can produce a purified gas product, preferably hydrogen, on a constant flow.
摘要:
According the present invention, an oxygen enriched gas is generated by adsorbing and removing nitrogen gas from air with an oxygen concentrating apparatus which conducts the steps of (1) pressurizing one of the adsorption cylinders by directing the compressed air; (2) removing the oxygen enriched gas from said one of the adsorption cylinders to the output conduit; (3) reducing the pressure in said one of the adsorption cylinders by directing the oxygen enriched gas into one of the other adsorption cylinders to increase the pressure in the one of the other adsorption cylinders; (4) evacuating the internal gas out of said one of the adsorption cylinders; and (5) increasing the pressure in said one of the adsorption cylinders by directing the oxygen enriched gas into said one of the adsorption cylinders from one of the other adsorption cylinders in which the pressure is decreased in step (3).
摘要:
The present invention is a gas separation method using a plurality of adsorption columns packed with an adsorbent. A cycle including a series of steps (adsorption, first pressure reduction, second pressure reduction, desorption, scrubbing, and repressurization) is repeated in each adsorption column. In the adsorption step, a gas mixture (G1) is introduced into a column (A) so as to cause the adsorbent to adsorb unnecessary components, and a product gas (G2) is led outside of the column (FIG. 3A). In the first pressure reduction step, the internal pressure of the column (A) is reduced by lead-out of a gas (G3) (FIG. 4A). In the second pressure reduction step, the internal pressure of the column (A) is further reduced by lead-out of the gas (FIG. 4B). In the desorption step, the unnecessary components are desorbed from the adsorbent and purged from the column (A) (FIG. 4C). In the scrubbing step, introduction of the gas (G3) and purging of the gas (G4) are performed simultaneously (FIG. 5A). In the repressurizing step, the internal pressure of the column (A) is raised by introducing the gas (G3) (FIG. 5B). The gas (G3) that is led out from the column (A) during the first pressure reduction step is introduced into the column (C) during the scrubbing step (FIG. 4A), and the gas (G3) that is led out from the column (A) during the second pressure reduction step is introduced into the column (C) during the repressurizing step (FIG. 4B).
摘要:
A PSA system that purifies a feed gas, such as a reformate gas in fuel cell system. The PSA system includes a series of vessels housing an adsorbent or combination of adsorbents that adsorb carbon monoxide, carbon dioxide, nitrogen, water and methane in the reformate gas. The adsorbent vessels are connected to each other and a feed manifold, a product manifold and an exhaust manifold through suitable conduits, where the gas flows are controlled by a product rotating valve and feed rotating valve or a series of open/shut valves. A specialized PSA cycle controls the valves so that the vessels cycle through various stages of equalization, blow-down, purge, pressurization and production to purify the feed gas.
摘要:
A gas separation process incorporating the invention combines use of an adsorbent having high intrinsic diffusivity with a low pressure ratio PSA cycle. Further enhancements to the process are derived from the use of fast cycles, shallow beds and small particles—especially in a radial bed configuration. The combination of low pressure ratio, high rate adsorbents and fast cycles has been found to result in an unexpected simultaneous reduction in bed size factor (BSF) and power consumption. These benefits have been achieved while minimizing a decline in product recovery through use of the high rate adsorbent. The net result is a significant reduction in product cost.