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公开(公告)号:US20180354872A1
公开(公告)日:2018-12-13
申请号:US15780725
申请日:2016-12-02
发明人: Jan Pablo JOSCH , Ragavendra Prasad BALEGEDDE RAMACHANDRAN , Philipp GRUENE , Steffan RISSEL , Martin GEMBALA , Ulrike WENNING , Anton WELLENHOFER , Christine TOEGEL , Hendrik REYNEKE
CPC分类号: C07C5/48 , B01D3/40 , B01J19/0053 , B01J2219/00121 , B01J2219/00425 , C07C7/005 , C07C7/08 , C07C7/09 , C07C7/11 , C07C11/167
摘要: A) provision of a feed gas stream a comprising n-butenes;B) introduction of the feed gas stream a comprising n-butenes and an oxygen-comprising gas into a dehydrogenation reactor and oxidative dehydrogenation of n-butenes to butadiene;C) cooling and compression of the product gas stream b in at least one cooling stage comprising a quenching column and in a compression stage comprising a compressor, with the product gas stream b being brought into contact with at least one circulated coolant;D) separation of incondensable and low-boiling gas constituents as gas stream d2 from the gas stream c2 by absorption of the C4-hydrocarbons in at least one circulated absorption medium;E) separation of the C4 product stream d1 by extractive distillation using a solvent which is selective for butadiene into a stream e1 comprising butadiene and the selective solvent and a stream e2 comprising n-butenes;F) distillation of the stream e1 comprising butadiene and the selective solvent to give a stream f1 consisting essentially of the selective solvent and a stream f2 comprising butadiene;wherein the measures (i) to (iii) below are carried out (i) avoidance of formation of explosive gas mixtures by monitoring of the oxygen concentration in the oxygen-comprising gas streams fed into the dehydrogenation zone and control of the mass flows of oxygen-comprising gas streams and gas streams comprising hydrocarbons in such a way that no explosive gas mixtures can be formed; (ii) interruption of the introduction of the oxygen-comprising gas mixture into the dehydrogenation zone when a limit value for the oxygen concentration in the dehydrogenation gas mixture is exceeded; (iii) carrying out of the steps A) to F) in apparatuses which are configured so as to be explosion-protected, where liquid-conveying pipes are configured so as to be explosion-protected and gas conduits are configured so as to be detonation-protected.
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公开(公告)号:US20070161119A1
公开(公告)日:2007-07-12
申请号:US11332190
申请日:2006-01-12
申请人: Bill Peck , Eric Leproust , Heather McCuen
发明人: Bill Peck , Eric Leproust , Heather McCuen
IPC分类号: G01N1/10
CPC分类号: B01J19/0046 , B01J2219/00351 , B01J2219/00378 , B01J2219/00425 , B01J2219/00527 , B01J2219/00585 , B01J2219/00596 , B01J2219/00605 , B01J2219/0061 , B01J2219/00612 , B01J2219/00626 , B01J2219/00637 , B01J2219/00641 , B01J2219/00659 , B01J2219/00677 , B01J2219/00693 , B01J2219/00722 , B01J2219/00725 , C07K1/047 , C07K1/1077 , Y10T436/2575
摘要: Methods for fabricating chemical arrays are provided. Aspects of the invention include methods for providing solid activator in feature locations of a substrate surface. Aspects of the invention also include substrates having solid activator present in feature locations thereof, arrays produced from the substrates, methods for use of the arrays and kits that include the arrays.
摘要翻译: 提供了制造化学阵列的方法。 本发明的方面包括在基底表面的特征位置提供固体激活剂的方法。 本发明的方面还包括在其特征位置存在的具有固体活化剂的底物,从底物产生的阵列,使用阵列的方法和包括阵列的试剂盒。
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