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    Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
    2.
    发明授权
    Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation 有权

    公开(公告)号：US10421700B2

    公开(公告)日：2019-09-24

    申请号：US15561711

    申请日：2016-03-23

    Applicant: BASF SE ,  Linde AG

    Inventor： Jan Pablo Josch ,  Ragavendra Prasad Balegedde Ramachandran ,  Christian Walsdorff ,  Regina Benfer ,  Anton Wellenhofer ,  Ulrike Wenning ,  Heinz Boelt ,  Hendrik Reyneke ,  Christine Toegel

    IPC: C07C5/48 ,  C07C7/00 ,  C07C7/08 ,  C07C7/09 ,  C07C7/11 ,  C07C11/167

    Abstract: The invention relates to a process for producing butadiene from n-butenes which comprises the steps of: A) providing a vaporous n-butenes-comprising input gas stream a1 by evaporating a liquid n-butenes-comprising stream a0; B) introducing the vaporous n-butenes-comprising input gas stream a1 and an at least oxygenous gas into at least one oxidative dehydrogenation zone and oxidatively dehydrogenating n-butenes to butadiene to obtain a product gas stream b comprising butadiene, unconverted n-butenes, steam, oxygen, low-boiling hydrocarbons, high-boiling secondary components, possibly carbon oxides and possibly inert gases, Ca) chilling the product gas stream b by contacting with a cooling medium comprising an organic solvent in at least one chilling zone, the cooling medium being at least partially recycled into the chilling zone, Cb) compressing the chilled product gas stream b which is possibly depleted of high-boiling secondary components in at least one compression stage to obtain at least one aqueous condensate stream c1 and a gas stream c2 comprising butadiene, n-butenes, steam, oxygen, low-boiling hydrocarbons, possibly carbon oxides and possibly inert gases, D) removing noncondensable and low-boiling gas constituents comprising oxygen, low-boiling hydrocarbons, possibly carbon oxides and possibly inert gases as gas stream d2 from the gas stream c2 by absorbing the C4 hydrocarbons comprising butadiene and n-butenes into an absorption medium to obtain a C4-hydrocarbons-laden absorption medium stream and the gas stream d2 and subsequently desorbing the C4 hydrocarbons from the laden absorption medium stream to obtain a C4 product gas stream d1, wherein at least some of the recycled cooling medium from step Ca) is brought into thermal contact with the liquid n-butenes-comprising stream a0 in one or more indirect heat exchangers and at least some of the liquid n-butenes-comprising stream a0 is evaporated by indirect heat transfer with the recycled cooling medium.

    Method for producing 1,3-butadiene by dehydrogenating n-butenes, a material flow containing butanes and 2-butenes being provided
    3.
    发明授权
    Method for producing 1,3-butadiene by dehydrogenating n-butenes, a material flow containing butanes and 2-butenes being provided 有权

    公开(公告)号：US10384990B2

    公开(公告)日：2019-08-20

    申请号：US15525330

    申请日：2015-11-09

    Applicant: BASF SE ,  Linde AG

    Inventor： Jan Ungelenk ,  Philipp Grüne ,  Christian Walsdorff ,  Jan Pablo Josch ,  Michael Bender

    IPC: C07C5/48 ,  C07C2/10 ,  C07C2/62 ,  C07C6/04 ,  C07C7/08 ,  C07C7/11 ,  C07C2/06 ,  C07C2/56 ,  C07C9/16 ,  C07C11/06 ,  C07C11/167

    Abstract: The invention relates to a process for preparing 1,3-butadiene from n-butenes, comprising the steps of: A) providing an input gas stream a comprising butanes, 1-butene, 2-butene and isobutene, with or without 1,3-butadiene, from a fluid catalytic cracking plant; B) removing isobutene from the input gas stream a, giving a stream b comprising butanes, 1-butene and 2-butene, with or without 1,3-butadiene; C) feeding the stream b comprising butanes, 1-butene and 2-butene and optionally an, oxygenous gas and optionally water vapor into at least one dehydrogenating zone and dehydrogenating 1-butene and 2-butene to 1,3-butadiene, giving a product gas stream c comprising 1,3-butadiene, butanes, 2-butene and water vapor, with or without oxygen, with low-boiling hydrocarbons, with high-boiling secondary components, with or without carbon oxides and with or without inert gases; D) cooling and compressing the product gas stream c, giving at least one aqueous condensate stream d1 and a gas stream d2 comprising 1,3-butadiene, butanes, 2-butene and water vapor, with or without oxygen, with low-boiling hydrocarbons, with or without carbon oxides and with or without inert gases; Ea) removing uncondensable and low-boiling gas constituents comprising low-boiling hydrocarbons, with or without oxygen, with or without carbon oxides and with or without inert gases, as gas stream e2 from the gas stream d2 by absorbing the C4 hydrocarbons comprising 1,3-butadiene, butanes and 2-butene in an absorbent, giving an absorbent stream laden with C4 hydrocarbons and the gas stream e2, and Eb) subsequently desorbing the C4 hydrocarbons from the laden absorbent stream, giving a C4 hydrocarbon stream e1; F) separating the C4 hydrocarbon stream e1 by extractive distillation with a 1,3-butadiene-selective solvent into a stream f1 comprising 1,3-butadiene and the selective solvent and a stream f2 comprising butanes and 2-butene, wherein at least 90% of the 1-butene present in stream b is converted in step C) and a product stream f2 comprising butanes and 2-butene is obtained in step F.

    METHOD FOR PRODUCING BUTADIENE BY OXIDATIVELY DEHYDROGENATING N-BUTENES
    6.
    发明申请
    METHOD FOR PRODUCING BUTADIENE BY OXIDATIVELY DEHYDROGENATING N-BUTENES 审中-公开

    公开(公告)号：US20180354872A1

    公开(公告)日：2018-12-13

    申请号：US15780725

    申请日：2016-12-02

    Applicant: BASF SE ,  Linde AG

    Inventor： Jan Pablo JOSCH ,  Ragavendra Prasad BALEGEDDE RAMACHANDRAN ,  Philipp GRUENE ,  Steffan RISSEL ,  Martin GEMBALA ,  Ulrike WENNING ,  Anton WELLENHOFER ,  Christine TOEGEL ,  Hendrik REYNEKE

    IPC: C07C5/48 ,  C07C7/00 ,  C07C7/08 ,  C07C7/09 ,  C07C7/11 ,  C07C11/167 ,  B01D3/40 ,  B01J19/00

    CPC classification number: C07C5/48 ,  B01D3/40 ,  B01J19/0053 ,  B01J2219/00121 ,  B01J2219/00425 ,  C07C7/005 ,  C07C7/08 ,  C07C7/09 ,  C07C7/11 ,  C07C11/167

    Abstract: A) provision of a feed gas stream a comprising n-butenes;B) introduction of the feed gas stream a comprising n-butenes and an oxygen-comprising gas into a dehydrogenation reactor and oxidative dehydrogenation of n-butenes to butadiene;C) cooling and compression of the product gas stream b in at least one cooling stage comprising a quenching column and in a compression stage comprising a compressor, with the product gas stream b being brought into contact with at least one circulated coolant;D) separation of incondensable and low-boiling gas constituents as gas stream d2 from the gas stream c2 by absorption of the C4-hydrocarbons in at least one circulated absorption medium;E) separation of the C4 product stream d1 by extractive distillation using a solvent which is selective for butadiene into a stream e1 comprising butadiene and the selective solvent and a stream e2 comprising n-butenes;F) distillation of the stream e1 comprising butadiene and the selective solvent to give a stream f1 consisting essentially of the selective solvent and a stream f2 comprising butadiene;wherein the measures (i) to (iii) below are carried out (i) avoidance of formation of explosive gas mixtures by monitoring of the oxygen concentration in the oxygen-comprising gas streams fed into the dehydrogenation zone and control of the mass flows of oxygen-comprising gas streams and gas streams comprising hydrocarbons in such a way that no explosive gas mixtures can be formed; (ii) interruption of the introduction of the oxygen-comprising gas mixture into the dehydrogenation zone when a limit value for the oxygen concentration in the dehydrogenation gas mixture is exceeded; (iii) carrying out of the steps A) to F) in apparatuses which are configured so as to be explosion-protected, where liquid-conveying pipes are configured so as to be explosion-protected and gas conduits are configured so as to be detonation-protected.

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