公开(公告)号：US09321024B2

公开(公告)日：2016-04-26

申请号：US14520112

申请日：2014-10-21

Applicant: MITSUI CHEMICALS, INC.

Inventor： Koji Takamatsu ,  Satoshi Kato ,  Takeshi Fukuda ,  Tetsuya Nakano ,  Masaaki Sasaki

IPC: B01J12/00 ,  C07C263/04 ,  C07C269/04 ,  C07C273/04 ,  C07C273/00 ,  C07C273/02

CPC classification number: B01J12/00 ,  C07C263/04 ,  C07C269/04 ,  C07C273/04 ,  C07C271/00 ,  C07C265/00

Abstract: A method for producing carbamate including a urea production step; a carbamate-forming step; an ammonia separation step of absorbing the gas with water in the presence of carbonate to produce a gas absorption water, and separating ammonia; an aqueous alcohol solution separation step of separating an aqueous alcohol solution from the gas absorption water; an ammonia/carbon dioxide separation step of separating carbon dioxide gas from the aqueous ammonia solution in the gas absorption water from which the aqueous alcohol solution is separated; an aqueous ammonia solution reusing step of mixing the aqueous ammonia solution and carbonate with the water to be used for production of the gas absorption water.

公开(公告)号：US08969615B2

公开(公告)日：2015-03-03

申请号：US13434135

申请日：2012-03-29

Applicant: Vanessa Simone Lehr ,  Torsten Mattke ,  Carsten Knösche ,  Heiner Schelling ,  Gerhard Olbert

Inventor： Vanessa Simone Lehr ,  Torsten Mattke ,  Carsten Knösche ,  Heiner Schelling ,  Gerhard Olbert

IPC: C07C263/00 ,  C01B7/04 ,  C07C263/10

CPC classification number: C07C263/10 ,  C01B7/04 ,  Y02P20/22 ,  C07C265/00

Abstract: The present invention relates to gas phase phosgenation of amines for preparation of isocyanates. In the present invention, phosgene is prepared by reacting chlorine with an excess of carbon monoxide in a gas phase. The obtained phosgene-containing reaction mixture is divided into two streams by a thermal and/or a membrane separating process. The first stream is a low-carbon monoxide stream of no more than 1% by weight of carbon monoxide, based on a total weight of the first stream. The second stream is a carbon monoxide-rich stream of more than 10% by weight of carbon monoxide, based on a total weight of the second stream. The first stream is used as the phosgene-containing reactant stream in the gas phase phosgenation of amines to prepare isocyanates. The second stream can be recycled into the phosgene synthesis.

Abstract translation: 本发明涉及用于制备异氰酸酯的胺的气相光气化。 在本发明中，气相中的氯与过量的一氧化碳反应制备光气。 得到的含有光气的反应混合物通过热和/或膜分离方法分成两股。 基于第一料流的总重量，第一料流是不超过1重量％的一氧化碳的低碳一氧化碳流。 基于第二料流的总重量，第二料流是大于10重量％的一氧化碳的一氧化碳浓缩物流。 在胺的气相光气化中，将第一流用作含有光气的反应物流，以制备异氰酸酯。 第二流可以再循环进入光气合成。

公开(公告)号：US08759568B2

公开(公告)日：2014-06-24

申请号：US13256523

申请日：2010-04-07

Applicant: Vanessa Simone Lehr ,  Carsten Knoesche ,  Torsten Mattke

Inventor： Vanessa Simone Lehr ,  Carsten Knoesche ,  Torsten Mattke

IPC: C07C263/00

CPC classification number: C07C263/10 ,  C07C263/20 ,  C07C265/00

Abstract: The invention relates to a process for preparing isocyanates by reacting the corresponding amines with phosgene, optionally in the presence of an inert medium, in which phosgene and amine are first mixed and converted to the isocyanate in a reactor, and in which a reaction gas which comprises isocyanate and hydrogen chloride leaving the reactor is cooled in a quench by adding a liquid quench medium to form a mixture of reaction gas and quench medium as the product stream. The walls of the quench are essentially completely wetted with a liquid.

Abstract translation: 本发明涉及通过使相应的胺与光气反应制备异氰酸酯的方法，任选地在惰性介质存在下，将光气和胺首先在反应器中混合并转化成异氰酸酯，其中反应气体 包括异氰酸酯和氯化氢，离开反应器通过加入液体骤冷介质在骤冷中冷却以形成作为产物流的反应气体和骤冷介质的混合物。 骤冷壁基本上完全用液体润湿。

公开(公告)号：US20130079546A1

公开(公告)日：2013-03-28

申请号：US13701980

申请日：2011-05-19

Applicant: Koji Takamatsu ,  Satoshi Kato ,  Takeshi Fukuda ,  Tetsuya Nakano ,  Masaaki Sasaki

Inventor： Koji Takamatsu ,  Satoshi Kato ,  Takeshi Fukuda ,  Tetsuya Nakano ,  Masaaki Sasaki

IPC: C07C263/04 ,  C07C269/04

CPC classification number: B01J12/00 ,  C07C263/04 ,  C07C269/04 ,  C07C273/04 ,  C07C271/00 ,  C07C265/00

Abstract: A method for producing carbamate including a urea production step; a carbamate-forming step: an ammonia separation step of absorbing the gas with water in the presence of carbonate to produce a gas absorption water, and separating ammonia; an aqueous alcohol solution separation step of separating an aqueous alcohol solution from the gas absorption water; an ammonia/carbon dioxide separation step of separating carbon dioxide gas from the aqueous ammonia solution in the gas absorption water from which the aqueous alcohol solution is separated; an aqueous ammonia solution reusing step of mixing the aqueous ammonia solution and carbonate with the water to be used for production of the gas absorption water.

Abstract translation: 包括尿素生产步骤的生产氨基甲酸酯的方法; 氨基甲酸酯形成步骤：在碳酸盐存在下用水吸收气体以产生气体吸收水并分离氨的氨分离步骤; 将醇水溶液与气体吸收水分离的醇水溶液分离工序; 在从所述醇溶液分离的气体吸收水中分离二氧化碳气体的氨/二氧化碳分离步骤; 将氨水溶液和碳酸钠与用于生产气体吸收水的水混合的氨水溶液重复使用步骤。

公开(公告)号：US20110301380A1

公开(公告)日：2011-12-08

申请号：US13202175

申请日：2010-03-04

Applicant: Carsten Knoesche ,  Torsten Mattke

Inventor： Carsten Knoesche ,  Torsten Mattke

IPC: C07C263/10 ,  B01J19/00

CPC classification number: C07C263/10 ,  C07C265/14 ,  C07C265/00

Abstract: The invention relates to a process for preparing isocyanates by reacting the corresponding amines with phosgene in the gas phase, optionally in the presence of an inert medium, in which the amine is evaporated in an evaporator to give an amine-comprising gas stream, the phosgene is mixed into the amine-comprising gas stream, and the amine and the phosgene are converted to the isocyanate in a reactor, wherein the temperature of surfaces in contact with the gaseous amine is kept above the dew point limit of the amine-comprising gas stream. The invention further relates to an apparatus for preparing isocyanates by reacting the corresponding amines with phosgene in the gas phase, comprising an evaporator to evaporate the amine and a reactor in which the reaction is effected, and means of connection of evaporator and reactor, wherein surfaces which can come into contact with gaseous amine are provided with a coating which is not wetted by amine or have an averaged roughness depth Rz to DIN ISO 4287 of not more than 10 μm, and/or the apparatus has no dead spaces or thermal bridges.

Abstract translation: 本发明涉及一种制备异氰酸酯的方法，该方法通过使气相中的相应胺与光气反应，任选地在惰性介质存在下进行，其中胺在蒸发器中蒸发得到含胺气流，光气 混合到含胺的气流中，并且胺和光气在反应器中转化为异氰酸酯，其中与气态胺接触的表面的温度保持在含胺的气流的露点极限以上 。 本发明还涉及一种用于通过使相应的胺与气相中的光气反应制备异氰酸酯的装置，其包括蒸发器以蒸发胺和其中进行反应的反应器，以及蒸发器和反应器的连接装置，其中表面 可以与气态胺接触的涂层提供有不被胺润湿或者具有DIN ISO 4287的平均粗糙深度Rz不大于10μm的涂层和/或该设备没有死空间或热桥。

公开(公告)号：US20110257428A1

公开(公告)日：2011-10-20

申请号：US13131123

申请日：2009-11-30

Applicant: Carsten Knoesche ,  Torsten Mattke ,  Patric Mueller

Inventor： Carsten Knoesche ,  Torsten Mattke ,  Patric Mueller

IPC: C07C263/10

CPC classification number: C07C263/10 ,  C07C265/00

Abstract: The invention relates to a process for preparing isocyanates by reacting the corresponding amines with phosgene in the gas phase, optionally in the presence of an inert medium, in which the amine and the phosgene are first mixed and converted to the isocyanate in a reactor, and in which a reaction gas (1) which comprises isocyanate and hydrogen chloride leaving the reactor is cooled in a quench (3) by adding a liquid quench medium (5) to form a mixture of reaction gas and quench medium as the product stream (7). The quench medium (5) used is a mixture which comprises at least one solvent and isocyanate and which is withdrawn from the preparation process, any solid particles present in the quench medium (5) being removed before addition to the quench (3).

Abstract translation: 本发明涉及一种制备异氰酸酯的方法，任选在惰性介质存在下，在气相中使相应的胺与光气反应，其中胺和光气首先在反应器中混合并转化成异氰酸酯，以及 其中通过加入液体骤冷介质（5）将通过离开反应器的包含异氰酸酯和氯化氢的反应气体（1）在淬火（3）中冷却，形成作为产物流（7）的反应气体和骤冷介质的混合物 ）。 使用的骤冷介质（5）是包含至少一种溶剂和异氰酸酯并从制备过程中排出的混合物，在加入骤冷（3）之前，将骤冷介质（5）中存在的任何固体颗粒除去。

公开(公告)号：US4975514A

公开(公告)日：1990-12-04

申请号：US349967

申请日：1989-05-08

Applicant: Hiroyuki Watanabe ,  Hiroshi Washita ,  Kazuhiko Kuga

Inventor： Hiroyuki Watanabe ,  Hiroshi Washita ,  Kazuhiko Kuga

IPC: C08G18/70 ,  C08G18/80

CPC classification number: C07C265/10 ,  C07C265/00 ,  C07C265/12 ,  C08G18/8048

Abstract: A polyisocyanate composition containing an amide-modified product, obtained by modifying a polyisocyanate compound with a polybasic carboxylic acid in an equivalent ratio of carboxyl groups/isocyanate groups being at most 0.9.

公开(公告)号：US4810820A

公开(公告)日：1989-03-07

申请号：US84546

申请日：1987-08-12

Applicant: William E. Slack ,  Terry A. Potter ,  Kenneth L. Dunlap

Inventor： William E. Slack ,  Terry A. Potter ,  Kenneth L. Dunlap

IPC: C08G18/73 ,  C07C67/00 ,  C07C241/00 ,  C07C263/16 ,  C07C265/00 ,  C07C265/04 ,  C07C273/18 ,  C07C275/60 ,  C08G18/78 ,  C09D175/00 ,  C07C127/22

CPC classification number: C07C265/10 ,  C07C265/00 ,  C07C273/1809 ,  C08G18/7837

Abstract: Aliphatic and/or cycloaliphatic polyisocyanates containing allophanate groups are produced by reacting (a) a di- and/or polyisocyanate with aliphatic and/or cycloaliphatic isocyanate groups with (b) a hydroxy compound at a temperature of at least 150.degree. C. for no more than 90 minutes and then rapidly cooling the reaction mixture to a temperature of less than 100.degree. C. It is preferred that the reaction be carried out in the absence of oxygen. The products thus obtained are virtually colorless, have a relatively low viscosity and excellent storage stability.

公开(公告)号：US4719245A

公开(公告)日：1988-01-12

申请号：US909546

申请日：1986-09-22

Applicant: Dale F. Regelman

Inventor： Dale F. Regelman

IPC: C07D295/02 ,  C08G18/02 ,  C08G18/16 ,  C08G18/79 ,  C08J9/00

CPC classification number: C07D295/02 ,  C07C255/00 ,  C07C265/00 ,  C07C265/12 ,  C08G18/022 ,  C08G18/168 ,  C08G18/791 ,  C08G2105/02 ,  Y10S521/902

Abstract: Disclosed are novel compositions capable of catalytically trimerizing organic isocyanates said compositions comprising solutions of the reaction products obtained by reacting in an inert solvent in substantially equimolar proportions electron-rich ketene-aminals with electron-poor olefins having the respective formulae (I) and (II) ##STR1## The variously substituted electron-rich ketene-aminals (I), as the name implies, have high electron density associated with the double bond because of the two tertiary amine groups while the electron-poor olefins (II) have the opposite situation due to the presence of electron withdrawing substituents R.sub.9 and R.sub.10.Also discosed is an improved process for trimerizing organic isocyanates using the above catalyst compositions including the preparation of polyisocyanurate polymers and isocyanurate-modified polyisocyanates.

Abstract translation: 公开了能够催化三聚有机异氰酸酯的新型组合物，所述组合物包含通过在惰性溶剂中基本上等摩尔比例的富含电子的乙烯酮 - 胺与具有各自式（I）和（II）的电子不足烯烃反应而获得的反应产物的溶液 （I）如下所述，不同取代的富电子酮乙烯酮（I）由于两个叔胺基团而具有与双键相关的高电子密度，而电子 由于吸电子取代基R9和R10的存在，α-烯烃（II）具有相反的情况。 还提出了使用上述催化剂组合物三聚有机异氰酸酯的改进方法，包括制备聚异氰脲酸酯聚合物和异氰脲酸酯改性的多异氰酸酯。

公开(公告)号：US4622340A

公开(公告)日：1986-11-11

申请号：US604371

申请日：1984-04-26

Applicant: Heinz-Manfred Becher ,  Ricarda Prokic-Immel ,  Walter Wirtz

Inventor： Heinz-Manfred Becher ,  Ricarda Prokic-Immel ,  Walter Wirtz

IPC: A01N43/34 ,  A01N47/34 ,  C07C205/12 ,  C07C275/54 ,  C07C335/26 ,  A01N47/28 ,  C07C127/22 ,  C07C157/12

CPC classification number: C07C265/00 ,  A01N47/34 ,  C07C205/12 ,  C07C265/12 ,  C07C275/54 ,  C07C335/26

Abstract: This invention relates to compounds of the formula ##STR1## Z' is chlorine or fluorine, with the proviso that Z' is chlorine when Q is the moiety of Formula III. The invention also relates to the preparation of the compounds, their use in controlling animal pests in plant protection, and pesticidal agents comprising the compounds as active ingredients.

Abstract translation: 本发明涉及式（Ia）的化合物，其中其中X为（VI）或（III）和Z'为氯或氟，条件是当Q为 公式三。 本发明还涉及化合物的制备，其用于控制​​植物保护中的动物害虫的用途，以及包含该化合物作为活性成分的杀虫剂。