Methods and Systems for Making Thiol Compounds from Terminal Olefinic Compounds
    2.
    发明申请
    Methods and Systems for Making Thiol Compounds from Terminal Olefinic Compounds 审中-公开
    从末端烯烃化合物制备硫醇化合物的方法和系统

    公开(公告)号:US20090264669A1

    公开(公告)日:2009-10-22

    申请号:US12427467

    申请日:2009-04-21

    申请人: Thomas A. Upshaw

    发明人: Thomas A. Upshaw

    IPC分类号: C07C327/00

    摘要: The application discloses thiol ester molecules and α-hydroxy thiol ester molecules having a thiol group located on one of the final two carbon atoms in a carbon chain or a terminal or α-hydroxyl groups, respectively. The disclosed thiol ester molecules and or α-hydroxyl thiol ester molecules es may be made from unsaturated ester molecules having one or more terminal alkene groups. The disclosed techniques also provide methods for making unsaturated ester molecules having one or more terminal alkene groups by the metathesis of unsaturated esters having one or more internal carbon-carbon double bonds (e.g. natural source oils). The thiol ester molecules or α-hydroxy thiol ester molecule may be used in reactions with isocyanate monomers, epoxide monomer, or material having multiple alkene groups to make sealants, coatings, adhesives, and other products.

    摘要翻译: 本申请公开了分别具有位于碳链或末端或α-羟基中的最后两个碳原子之一上的硫醇基的硫羟酸酯分子和α-羟基硫羟酸酯分子。 公开的硫醇酯分子和/或α-羟基硫羟酸酯分子可以由具有一个或多个末端烯烃基团的不饱和酯分子制成。 所公开的技术还提供了通过具有一个或多个内部碳 - 碳双键(例如天然来源油)的不饱和酯的复分解制备具有一个或多个末端烯烃基团的不饱和酯分子的方法。 硫醇酯分子或α-羟基硫羟酸酯分子可用于与异氰酸酯单体,环氧化物单体或具有多个烯烃基团的材料反应以制备密封剂,涂料,粘合剂和其它产品。

    Biosensor and Method
    4.
    发明申请
    Biosensor and Method 审中-公开
    生物传感器和方法

    公开(公告)号:US20080206893A1

    公开(公告)日:2008-08-28

    申请号:US12106523

    申请日:2008-04-21

    IPC分类号: G01N33/544

    摘要: Surface plasmon resonance (SPR) sensor biointerface with a rigid thiol linker layer and/or interaction layer ligand loading with reversible collapse and/or iron oxide nanoparticle sensor response amplification.

    摘要翻译: 具有刚性硫醇接头层和/或相互作用层配体的表面等离子体共振(SPR)传感器生物界面负载有可逆塌陷和/或氧化铁纳米颗粒传感器响应扩增。

    Heavy Metal Remediation Via Sulfur-Modified Bio-Oils
    6.
    发明申请
    Heavy Metal Remediation Via Sulfur-Modified Bio-Oils 有权
    通过硫改性生物油重金属补救

    公开(公告)号:US20140163248A1

    公开(公告)日:2014-06-12

    申请号:US13706551

    申请日:2012-12-06

    摘要: We have now discovered a novel process for the removal or extraction of metal species from a variety of solid, liquid or gas phase materials. Metal species may be removed by contacting the material suspected of containing one or more metals with a thiolated fatty acid or ester thereof for a period of time and under conditions effective for the sequestration of the metal species by the thiolated fatty acid or ester thereof. The thiolated fatty acid or ester thereof comprising sequestered metal species may then be separated and recovered from the treated material. Moreover, following the treatment of aqueous liquids or mixtures, or suspensions or dispersions of solids in aqueous liquids, the resultant thiolated fatty acid or ester thereof comprising the sequestered metal species is insoluble in water and forms a separate layer from the aqueous liquid phase, which layer may be readily removed.

    摘要翻译: 我们现在已经发现了一种用于从各种固体,液体或气相材料中去除或提取金属物质的新方法。 金属物质可以通过将疑似含有一种或多种金属的物质与硫醇化脂肪酸或其酯接触一段时间并且在通过硫醇化脂肪酸或其酯螯合金属物质的条件下被除去。 然后可以从被处理的材料中分离和回收包含隔离金属物质的硫醇化脂肪酸或其酯。 此外,在含水液体或混合物或固体在水性液体中的悬浮液或分散体的处理之后,得到的包含隔离金属物质的硫醇化脂肪酸或其酯不溶于水并与水相液体形成分开的层, 层可以容易地去除。

    Methods and systems for making thiol compounds from terminal olefinic compounds
    8.
    发明授权
    Methods and systems for making thiol compounds from terminal olefinic compounds 有权
    从末端烯烃化合物制备硫醇化合物的方法和系统

    公开(公告)号:US08765984B2

    公开(公告)日:2014-07-01

    申请号:US13465054

    申请日:2012-05-07

    申请人: Thomas A. Upshaw

    发明人: Thomas A. Upshaw

    IPC分类号: C07C321/02 C07C319/04

    摘要: The application discloses thiol ester molecules and α-hydroxy thiol ester molecules having a thiol group located on one of the final two carbon atoms in a carbon chain or a terminal or α-hydroxyl groups, respectively. The disclosed thiol ester molecules and or α-hydroxyl thiol ester molecules es may be made from unsaturated ester molecules having one or more terminal alkene groups. The disclosed techniques also provide methods for making unsaturated ester molecules having one or more terminal alkene groups by the metathesis of unsaturated esters having one or more internal carbon-carbon double bonds (e.g. natural source oils). The thiol ester molecules or α-hydroxy thiol ester molecule may be used in reactions with isocyanate monomers, epoxide monomer, or material having multiple alkene groups to make sealants, coatings, adhesives, and other products.

    摘要翻译: 该申请公开了分别具有位于碳链或末端或α-羟基中的最后两个碳原子之一上的硫醇基的硫羟酸酯分子和α-羟基硫羟酸酯分子。 公开的硫醇酯分子和/或α-羟基硫羟酸酯分子可以由具有一个或多个末端烯烃基团的不饱和酯分子制成。 所公开的技术还提供了通过具有一个或多个内部碳 - 碳双键(例如天然来源油)的不饱和酯的复分解制备具有一个或多个末端烯烃基团的不饱和酯分子的方法。 硫醇酯分子或α-羟基硫羟酸酯分子可用于与异氰酸酯单体,环氧化物单体或具有多个烯烃基团的材料的反应,以制备密封剂,涂料,粘合剂和其它产品。