公开(公告)号：US12030845B2

公开(公告)日：2024-07-09

申请号：US17807024

申请日：2022-06-15

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Wesley Sattler ,  Jihad M. Dakka ,  Guang Cao ,  Xinrui Yu ,  Brandon M. Carcuffe ,  Jason M. Golias ,  Scott J. Weigel ,  Carolyn M. Aimino ,  Megan E. Witzke

IPC: C07C5/27 ,  B01J21/06 ,  B01J23/00 ,  B01J23/30

CPC classification number: C07C5/2705 ,  B01J21/066 ,  B01J23/002 ,  B01J23/30 ,  C07C2521/06 ,  C07C2523/30

Abstract: Isomerization of normal paraffins to form branched paraffins may be complicated by significant cracking of C7+ paraffins under isomerization reaction conditions. This issue may complicate upgrading of hydrocarbon feeds having significant quantities of heavier normal paraffins. Cracking selectivity may be decreased by combining one or more naphthenic compounds with a feed mixture comprising at least one C7+ normal paraffin and/or by utilizing tungstated zirconium catalysts having decreased tungsten loading. Further, C5 and C6 normal paraffins may undergo isomerization in the presence of C7+ normal paraffins. Methods for isomerizing normal paraffins may comprise: providing a feed mixture comprising at least C5-C7 normal paraffins and lacking normal paraffins larger than C8; and contacting the feed mixture with a bifunctional mixed metal oxide catalyst under isomerization reaction conditions effective to form a product mixture comprising one or more branched paraffins formed from each of the C5-C7 normal paraffins.

公开(公告)号：US6162757A

公开(公告)日：2000-12-19

申请号：US357546

申请日：1999-07-20

Applicant: Clarence D. Chang ,  Scott Han ,  Scott A. Stevenson ,  James C. Vartuli

Inventor： Clarence D. Chang ,  Scott Han ,  Scott A. Stevenson ,  James C. Vartuli

IPC: B01J21/06 ,  B01J23/10 ,  B01J37/03 ,  C07C5/27

CPC classification number: B01J37/03 ,  B01J21/066 ,  B01J23/10 ,  C07C5/2705 ,  C07C2521/06 ,  C07C9/00

Abstract: A novel synthesis composition of a solid acid containing zirconium, in addition to a rare earth element, such as cerium, has the potential for catalytic conversions of hydrocarbons, especially for isomerization of paraffins, ring opening of cyclics, hydrocracking, alkylation, hydrogenation of polynuclear aromatics, selective catalytic reduction of nitrogen oxides, and oligomerization of light olefins.

Abstract translation: 含有锆的固体酸的新型合成组合物除了稀土元素如铈之外，具有烃的催化转化的潜力，特别是对于链烷烃的异构化，环化开环，加氢裂化，烷基化，多核氢化 芳族化合物，氮氧化物的选择性催化还原和轻质烯烃的低聚。

公开(公告)号：US4740651A

公开(公告)日：1988-04-26

申请号：US599150

申请日：1984-04-11

Applicant: Marvin R. Klotz

Inventor： Marvin R. Klotz

IPC: B01J29/89 ,  C07C5/27 ,  C10G47/04 ,  C07C5/22

CPC classification number: B01J29/046 ,  C07C5/2705

Abstract: There is provided a catalytic composition which comprises a mixture of a crystalline chromosilicate and an oxide of chromium, said catalytic composition providing a specific X-ray diffraction pattern and having the following composition in terms of mole ratios of oxides:0.9.+-.0.2 M.sub.2/n O:Cr.sub.2 O.sub.3 :YSiO.sub.2 :ZH.sub.2 O,wherein M is at least one cation having a valence of n, Y is a value within the range of about 4 to about 500, and Z is a value within the range of about 0 to about 160. There is also provided a method for preparing such a catalytic composition.There is provided a process for the conversion of a hydrocarbon stream which comprises contacting said stream at conversion conditions with the above catalytic composition. In addition, there is provided a process for the isomerization of a xylene feed which comprises contacting said feed at isomerization conditions with the above catalytic composition.

Abstract translation: 提供了一种催化组合物，其包含结晶铬酸铬和铬的氧化物的混合物，所述催化组合物提供特定的X射线衍射图，并且以氧化物的摩尔比计具有以下组成：0.9 +/- 0.2M2 / nO：Cr 2 O 3 :YSiO 2 :HH 2 O，其中M为至少一个价数为n的阳离子，Y为约4至约500的范围内的值，Z为约0至约160的范围内的值 还提供了制备这种催化剂组合物的方法。 提供了一种转化烃流的方法，其包括在转化条件下将所述物流与上述催化组合物接触。 此外，提供了二甲苯进料异构化的方法，其包括使异构化条件下的进料与上述催化组合物接触。

公开(公告)号：US4405502A

公开(公告)日：1983-09-20

申请号：US281828

申请日：1981-07-09

Applicant: Marvin R. Klotz

Inventor： Marvin R. Klotz

IPC: B01J29/89 ,  C07C5/27 ,  B01J29/00 ,  B01J29/04

CPC classification number: B01J29/046 ,  C07C5/2705 ,  B01J2229/40 ,  Y02P20/52

Abstract: There is provided a catalytic composition which comprises a crystalline chromosilicate and a porous refractory inorganic oxide, said chromosilicate and said inorganic oxide having been intimately admixed with one another, said chromosilicate comprising a molecular sieve material providing a specific X-ray diffraction pattern and having the following composition in terms of mole ratios of oxides:0.9.+-.0.2 M.sub.2/n O:Cr.sub.2 O.sub.3 :YSiO.sub.2 :ZH.sub.2 O,wherein M is at least one cation having a valence of n, Y is within the range of about 4 to about 200, and Z is a value within the range of 0 to about 160. There is also provided a method for preparing such a catalytic composition.There is provided a process for the conversion of a hydrocarbon stream, which process comprises contacting said stream at conversion conditions with the above catalytic composition. In addition, there is provided a process for the isomerization of a xylene feed, which process comprises contacting said feed at isomerization conditions with the above catalytic composition.

Abstract translation: 提供了一种催化组合物，其包含结晶铬酸盐和多孔耐火无机氧化物，所述铬硅酸盐和所述无机氧化物彼此紧密混合，所述含氯硅酸盐包括提供特定X射线衍射图的分子筛材料， 按照氧化物的摩尔比计算以下组成：0.9 +/- 0.2M 2 / nO：Cr 2 O 3 :YSiO 2 :ZH 2 O，其中M是至少一种价数为n的阳离子，Y在约4至约200的范围内， Z为0至约160的范围内的值。还提供了制备这种催化剂组合物的方法。 提供了一种转化烃流的方法，该方法包括在转化条件下将所述物流与上述催化剂组合物接触。 此外，提供了二甲苯进料异构化的方法，该方法包括使异构化条件下的进料与上述催化剂组合物接触。

公开(公告)号：US3766287A

公开(公告)日：1973-10-16

申请号：US3766287D

申请日：1971-07-23

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： STENMARK D ,  WESSELHOFT R

IPC: C07C5/27 ,  C07C15/067 ,  C07C15/08

CPC classification number: C07C15/067 ,  C07C5/2705 ,  C07C5/2724

Abstract: PARAXYLENE IS RECOVERED FROM A MIXTURE OF XYLENES AND ETHYLBENZENE BY SEPARATING THE MIXTURE INTO TWO STREAMSONE WHICH IS RICH IN ETHYLBENZENE AND ORTHOXYLENE AND ANOTHER WHICH IS RICH IN METAXYLENE-AND SEPARATELY ISOMERIZING THE TWO STREAMS UNDER DIFFERENT CONDITIONS TO OBTAIN A MAXIMUM AMOUNT OF PARAXYLENE.
D R A W I N G

公开(公告)号：US3609097A

公开(公告)日：1971-09-28

申请号：US3609097D

申请日：1968-07-05

Applicant: METALLGESELLSCHAFT AG

Inventor： KOPPE HERBERT

IPC: B01J21/20 ,  C07C5/27 ,  B01J11/04

CPC classification number: B01J21/20 ,  C07C5/2705 ,  Y02P20/584 ,  C07C15/067

Abstract: A steam injector is used to circulate regenerating gas through a catalyst bed to burn off carbonaceous deposits on the catalyst.

公开(公告)号：US3484385A

公开(公告)日：1969-12-16

申请号：US3484385D

申请日：1966-12-27

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： AMIR EMANUEL M

IPC: B01J21/12 ,  B01J23/28 ,  B01J37/08 ,  C07C5/27 ,  B01J11/06 ,  B01J11/40 ,  B01J11/44

CPC classification number: C07C5/2705 ,  B01J21/12 ,  B01J23/28 ,  B01J37/08 ,  C07C5/2735 ,  Y02P20/52 ,  Y10S585/906 ,  Y10S585/951 ,  C07C15/02 ,  C07C15/08

公开(公告)号：US3389188A

公开(公告)日：1968-06-18

申请号：US54452266

申请日：1966-04-22

Applicant: KOPPERS CO INC

Inventor： MICHALOWICZ WILLIAM A

IPC: C07C5/27 ,  C07C13/58 ,  C07C15/28 ,  G01N1/14 ,  G01N1/22 ,  G01N21/73 ,  G01N33/20

CPC classification number: G01N33/206 ,  C07C5/2705 ,  C07C13/58 ,  C07C15/28 ,  C07C2603/24 ,  G01N1/1409 ,  G01N1/22 ,  G01N21/73 ,  G01N2001/1463

公开(公告)号：US3085952A

公开(公告)日：1963-04-16

申请号：US77266258

申请日：1958-11-10

Applicant: GULF RESEARCH DEVELOPMENT CO

Inventor： ODIOSO RAYMOND C ,  SCHMID BRUCE K ,  ZABOR ROBERT C

IPC: C07C5/27

CPC classification number: C07C5/2713 ,  C07C5/2705 ,  C07C5/2721 ,  Y10S204/90 ,  Y10S204/905 ,  C07C9/00

公开(公告)号：US4431748A

公开(公告)日：1984-02-14

申请号：US281840

申请日：1981-07-09

Applicant: Marvin R. Klotz

Inventor： Marvin R. Klotz

IPC: B01J29/78 ,  B01J29/89 ,  C07C5/27 ,  B01J23/26 ,  B01J29/00

CPC classification number: B01J29/046 ,  C07C5/2705 ,  Y02P20/52

Abstract: There is provided a catalytic composition which comprises a molecular sieve-containing component and a porous refractory inorganic oxide, said component and said refractory inorganic oxide having been intimately admixed with one another, said component comprising a mixture of a crystalline chromosilicate and an oxide of chromium, providing a specific X-ray diffraction pattern, and having the following composition in terms of mole ratios of oxides:0.9.+-.0.2 M.sub.2/n O:Cr.sub.2 O.sub.3 :YSiO.sub.2 :ZH.sub.2 O,wherein M is at least one cation having a valence of n, Y is a value within the range of about 4 to about 200, and Z is a value within the range of about 0 to about 160. There is also provided a method for preparing such a catalytic composition.There is provided a process for the conversion of a hydrocarbon stream, which process comprises contacting said stream at conversion conditions with the above catalytic composition. In addition, there is provided a process for the isomerization of a xylene feed, which process comprises contacting said feed at isomerization conditions with the above catalytic composition.

Abstract translation: 提供了一种催化组合物，其包含含分子筛的组分和多孔耐火无机氧化物，所述组分和所述耐火无机氧化物彼此紧密混合，所述组分包括铬酸铬结晶和铬的氧化物的混合物 提供特定的X射线衍射图，并且以氧化物的摩尔比为基准具有以下组成：0.9 +/- 0.2M 2 / nO: / Cr 2 O 3 :YSiO 2 :ZH 2 O，其中M是至少一种阳离子的化合价 n，Y为约4-约200范围内的值，Z为约0至约160范围内的值。还提供了制备这种催化剂组合物的方法。 提供了一种转化烃流的方法，该方法包括在转化条件下将所述物流与上述催化剂组合物接触。 此外，提供了二甲苯进料异构化的方法，该方法包括使异构化条件下的进料与上述催化剂组合物接触。