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    Mesogenic adducts
    1.
    发明授权
    Mesogenic adducts 失效
    介晶加合物

    公开(公告)号：US5362822A

    公开(公告)日：1994-11-08

    申请号：US176619

    申请日：1994-01-03

    申请人： Robert E. Hefner, Jr.

    发明人： Robert E. Hefner, Jr.

    IPC分类号： C08G18/58 ,  C08G18/64 ,  C08G18/67 ,  C08G18/76 ,  C08G18/77 ,  C08G18/78 ,  C08G18/81 ,  C08G59/16 ,  C07C43/196 ,  C07C43/23 ,  C08G59/14

    CPC分类号： C08G18/6705 ,  C08G18/581 ,  C08G18/6407 ,  C08G18/7657 ,  C08G18/771 ,  C08G18/775 ,  C08G18/7806 ,  C08G18/7875 ,  C08G18/8125 ,  C08G2101/00 ,  C08G2120/00 ,  C08G2250/00

    摘要： An adduct is prepared by reacting (A) a compound containing at least one epoxy group per molecule, with (B) a compound containing at least one epoxide reactive group per molecule selected from the group consisting of phenolic, thiol, secondary amine and carboxyl; wherein (i) when compound (A) is a polyepoxide, compound (B) contains a single epoxide reactive group per molecule; (ii) when compound (A) is a monoepoxide it is a monoglycidyl ether and compound (B) contains at least two epoxide reactive groups per molecule; and (iii) at least one of components (A) and (B) contains a rodlike mesogenic moiety. These adducts are useful in the preparation of polyurethanes.

    摘要翻译： 通过使（A）每分子含有至少一个环氧基的化合物与（B）每分子中含有至少一个环氧化物反应性基团的化合物选自酚类，硫醇，仲胺和羧基反应来制备加合物; 其中（i）当化合物（A）为聚环氧化物时，化合物（B）每分子含有单个环氧化物反应性基团; （ii）当化合物（A）为单环氧化物时，它是单缩水甘油醚，化合物（B）每分子含有至少两个环氧化物反应性基团; 和（iii）组分（A）和（B）中的至少一种包含棒状介晶部分。 这些加合物可用于制备聚氨酯。

    Isocyanate trimers containing iminooxadiazine dione groups, their preparation and use
    2.
    发明授权
    Isocyanate trimers containing iminooxadiazine dione groups, their preparation and use 失效
    含有亚氨基恶二嗪二酮的异氰酸酯三聚体，其制备和用途

    公开(公告)号：US5914383A

    公开(公告)日：1999-06-22

    申请号：US822072

    申请日：1997-04-30

    申请人： Frank Richter ,  Josef Pedain ,  Harald Mertes ,  Carl-Gerd Dieris

    发明人： Frank Richter ,  Josef Pedain ,  Harald Mertes ,  Carl-Gerd Dieris

    IPC分类号： C07D251/34 ,  C07D229/00 ,  C07D251/32 ,  C07D273/04 ,  C08G18/02 ,  C08G18/78 ,  C08G18/79 ,  C08G18/12

    CPC分类号： C07D251/32 ,  C07D273/04 ,  C08G18/022 ,  C08G18/7875 ,  C08G18/791

    摘要： The present invention relates to a polyisocyanate mixture containing isocyanate trimers provided thati) 30 to 100 mole percent of the trimers are iminooxadiazine diones B and ##STR1## ii) 0 to 70 mole percent of the trimers are isocyanurates A iii) less than 10 mole percent of the polyisocyanate mixture is of the uretone imine structural type, andiv) the ratio of the sum of the mole percents of trimers A and B to the mole percent of uretdiones is greater than 4:1whereinR.sup.1, R.sup.2 and R.sup.3 are the same or different and represent the groups obtained by removing an isocyanate group from an aliphatic, cycloaliphatic, aromatic and/or araliphatic isocyanate having an NCO content of less than 70% and/or their oligomers.The present invention also relates to a process for the preparation of these isocyanate trimers, mixtures of these isocyanate trimers with other polyisocyanates and compositions containing these isocyanate trimers, in which the isocyanate groups may optionally be blocked with blocking agents, and compounds containing two or more isocyanate-reactive groups.

    摘要翻译： 本发明涉及含有异氰酸酯三聚体的多异氰酸酯混合物，条件是i）30-100摩尔％的三聚体是亚氨基恶二嗪二酮B和ii）0-70摩尔％的三聚体是异氰脲酸酯A iii）小于10摩尔％ 多异氰酸酯混合物具有尿素亚胺结构型，并且iv）三聚体A和B的摩尔百分数之和与脲化合物的摩尔百分比之比大于4:1，其中R1，R2和R3相同或不同 并且表示通过从NCO含量小于70％的脂族，脂环族，芳族和/或芳脂族异氰酸酯和/或其低聚物除去异氰酸酯基而获得的基团。 本发明还涉及制备这些异氰酸酯三聚体的方法，这些异氰酸酯三聚物与其它多异氰酸酯的混合物和含有这些异氰酸酯三聚体的组合物，其中异氰酸酯基团可以任选地被封闭剂封闭，以及含有两个或多个 异氰酸酯反应性基团。

    Preparation of isocyanate derivatives of 1,3[oxazoles, oxazines, diazoles and diazines]
    4.
    发明授权
    Preparation of isocyanate derivatives of 1,3[oxazoles, oxazines, diazoles and diazines] 失效
    制备1,3 [恶唑，恶嗪，二唑和二嗪]的异氰酸酯衍生物

    公开(公告)号：US4247689A

    公开(公告)日：1981-01-27

    申请号：US47515

    申请日：1979-06-11

    申请人： Kurt Findeisen ,  Kuno Wagner ,  Walter Uerdingen

    发明人： Kurt Findeisen ,  Kuno Wagner ,  Walter Uerdingen

    IPC分类号： C07D233/88 ,  C07D235/02 ,  C07D239/22 ,  C07D263/38 ,  C07D263/48 ,  C07D263/52 ,  C08G18/78 ,  C08G18/80 ,  C07D265/04 ,  C07D233/70 ,  C07D263/04

    CPC分类号： C07D235/02 ,  C07D233/88 ,  C07D239/22 ,  C07D263/48 ,  C07D263/52 ,  C08G18/7875 ,  C08G18/8061

    摘要： The present invention relates to a new organic heterocyclic isocyanate which is the reaction product of an organic diisocyanate and an amino or hydroxy nitrile. The invention also relates to a process of producing such isocyanates by reacting an excess of the diisocyanate with the nitrile under conditions under which the nitrile will not decompose and then maintaining the reaction mixture at an elevated temperature until the isocyanate nitrile adduct cyclizes. The reaction may be carried out in the presence of a catalyst for isocyanate addition reactions. Additionally, the invention relates to a process for the production of polyurethane by the reaction of the heterocyclic isocyanates with compounds carrying at least two isocyanate reactive hydrogen atoms per molecule.

    摘要翻译： 本发明涉及作为有机二异氰酸酯与氨基或羟基腈的反应产物的新的有机杂环异氰酸酯。 本发明还涉及通过使过量的二异氰酸酯与腈在腈不分解的条件下反应然后将反应混合物保持在升高的温度直到异氰酸酯加合物环化来生产这种异氰酸酯的方法。 该反应可以在用于异氰酸酯加成反应的催化剂的存在下进行。 此外，本发明涉及通过杂环异氰酸酯与每分子携带至少两个异氰酸酯反应性氢原子的化合物的反应生产聚氨酯的方法。

    Process for preparing polyurethanes
    5.
    发明授权
    Process for preparing polyurethanes 失效
    制备聚氨酯的方法

    公开(公告)号：US4242489A

    公开(公告)日：1980-12-30

    申请号：US47517

    申请日：1979-06-11

    申请人： Kurt Findeisen ,  Kuno Wagner ,  Walter Uerdingen

    发明人： Kurt Findeisen ,  Kuno Wagner ,  Walter Uerdingen

    IPC分类号： C07D233/88 ,  C07D235/02 ,  C07D239/22 ,  C07D263/38 ,  C07D263/48 ,  C07D263/52 ,  C08G18/78 ,  C08G18/80 ,  C08G18/77 ,  C08G18/14

    CPC分类号： C07D235/02 ,  C07D233/88 ,  C07D239/22 ,  C07D263/48 ,  C07D263/52 ,  C08G18/7875 ,  C08G18/8061

    摘要： The present invention relates to a new organic heterocyclic isocyanate which is the reaction product of an organic diisocyanate and an amino or hydroxy nitrile. The invention also relates to a process of producing such isocyanates by reacting an excess of the diisocyanate with the nitrile under conditions under which the nitrile will not decompose and then maintaining the reaction mixture at an elevated temperature until the isocyanate nitrile adduct cyclizes. The reaction may be carried out in the presence of a catalyst for isocyanate addition reactions. Additionally, the invention relates to a process for the production of polyurethane by the reaction of the heterocyclic isocyanates with compounds carrying at least two isocyanate reactive hydrogen atoms per molecule.

    摘要翻译： 本发明涉及作为有机二异氰酸酯与氨基或羟基腈的反应产物的新的有机杂环异氰酸酯。 本发明还涉及通过使过量的二异氰酸酯与腈在腈不分解的条件下反应然后将反应混合物保持在升高的温度直到异氰酸酯加合物环化来生产这种异氰酸酯的方法。 该反应可以在用于异氰酸酯加成反应的催化剂的存在下进行。 此外，本发明涉及通过杂环异氰酸酯与每分子携带至少两个异氰酸酯反应性氢原子的化合物的反应生产聚氨酯的方法。

    Isocyanate derivatives of 1,3[oxazoles, oxazines, diazoles and diazines]
    6.
    发明授权
    Isocyanate derivatives of 1,3[oxazoles, oxazines, diazoles and diazines] 失效
    1,3 [恶唑，恶嗪，二唑和二嗪]的异氰酸酯衍生物

    公开(公告)号：US4173567A

    公开(公告)日：1979-11-06

    申请号：US656909

    申请日：1976-02-10

    申请人： Kurt Findeisen ,  Kuno Wagner ,  Walter Uerdingen

    发明人： Kurt Findeisen ,  Kuno Wagner ,  Walter Uerdingen

    IPC分类号： C07D233/88 ,  C07D235/02 ,  C07D239/22 ,  C07D263/38 ,  C07D263/48 ,  C07D263/52 ,  C08G18/78 ,  C08G18/80 ,  C07D233/70 ,  C07D265/06

    CPC分类号： C07D235/02 ,  C07D233/88 ,  C07D239/22 ,  C07D263/48 ,  C07D263/52 ,  C08G18/7875 ,  C08G18/8061

    摘要： The present invention relates to a new organic heterocyclic isocyanate which is the reaction product of an organic diisocyanate and an amino or hydroxy nitrile. The invention also relates to a process of producing such isocyanates by reacting an excess of the diisocyanate with the nitrile under conditions under which the nitrile will not decompose and then maintaining the reaction mixture at an elevated temperature until the isocyanate nitrile adduct cyclizes. The reaction may be carried out in the presence of a catalyst for isocyanate addition reactions. Additionally, the invention relates to a process for the production of polyurethane by the reaction of the heterocyclic isocyanates with compounds carrying at least two isocyanate reactive hydrogen atoms per molecule.

    摘要翻译： 本发明涉及作为有机二异氰酸酯与氨基或羟基腈的反应产物的新的有机杂环异氰酸酯。 本发明还涉及通过使过量的二异氰酸酯与腈在腈不分解的条件下反应然后将反应混合物保持在升高的温度直到异氰酸酯加合物环化来生产这种异氰酸酯的方法。 该反应可以在用于异氰酸酯加成反应的催化剂的存在下进行。 此外，本发明涉及通过杂环异氰酸酯与每分子携带至少两个异氰酸酯反应性氢原子的化合物的反应生产聚氨酯的方法。