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公开(公告)号：US06383433B1
公开(公告)日：2002-05-07
申请号：US09906577
申请日：2001-07-13
IPC分类号： B29C4788
CPC分类号： C08G63/6924 , C08G63/668 , D01F6/86 , Y10T428/2913
摘要： The present invention provides a copolyester fiber consisting of a copolyester with primarily C2-4 alkylene terephthalate units and a process for producing these copolyester fibers. The copolyester contains more than 4 wt % up to 12 wt % poly(C2-4 alkylene glycol) units and 60 to 260 ppm pentaerythritol units and/or a total of 150 to less than 2500 ppm carboxy methylene phosphonic acid units and/or carboxy ethylene phosphonic acid units polymerized into it.
摘要翻译： 本发明提供了由主要具有C2-4亚烷基对苯二甲酸酯单元的共聚酯和这种共聚酯纤维的生产方法组成的共聚酯纤维。共聚酯含有多于4重量％的至多12重量％的聚（C 2-4亚烷基二醇）单元 和60至260ppm的季戊四醇单元和/或总共150至小于2500ppm的羧基亚甲基膦酸单元和/或其中聚合的羧基乙烯膦酸单元。
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公开(公告)号：US06261686B1
公开(公告)日：2001-07-17
申请号：US09353165
申请日：1999-07-14
IPC分类号： D02G300
CPC分类号： C08G63/6924 , C08G63/668 , D01F6/86 , Y10T428/2913
摘要： The present invention provides a copolyester fiber consisting of a copolyester with primarily C2-4 alkylene terephthalate units and a process for producing these copolyester fibers. The copolyester contains more than 4 wt % up to 12 wt % poly(C2-4 alkylene glycol) units and 60 to 260 ppm pentaerythritol units and/or a total of 150 to less than 2500 ppm carboxy methylene phosphonic acid units and/or carboxy ethylene phosphonic acid units polymerized into it.
摘要翻译： 本发明提供了由主要具有C2-4亚烷基对苯二酸酯单元的共聚酯和这些共聚酯纤维的制备方法组成的共聚酯纤维。 共聚多酯包含多于4重量％的至多12重量％的聚（C 2-4亚烷基二醇）单元和60至260ppm的季戊四醇单元和/或总共150至小于2500ppm的羧基亚甲基膦酸单元和/或羧基 乙烯膦酸单元聚合成它。
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公开(公告)号：US5965259A
公开(公告)日：1999-10-12
申请号：US21611
申请日：1998-02-10
IPC分类号： C08K5/5317 , D01F6/84 , D02G3/00 , C08G79/02
CPC分类号： D01F6/84 , C08K5/5317 , Y10T428/2913
摘要： The present invention is a pre-oriented, non-stretched polyester fiber spun with spooling speeds of at least 3,000 m/min., wherein the polyester is a copolymer comprised essentially of ethylene terephthalate units and up to 10 weight % of other dicarboxylic acids or other diols, and carboxy phosphonic acid units of the formula: ##STR1## wherein R is selected from C.sub.1-10 -alkylene, C.sub.1-10 -cycloalkylene or C.sub.6-10 -arylene, in a quantity corresponding to 30 to 500 ppm phosphorus, in relation to polyester. The invention also comprises a process for the production of this fiber.
摘要翻译： 本发明是一种预卷取的非拉伸聚酯纤维，其纺丝速度为至少3,000m / min，其中聚酯是基本上由对苯二甲酸乙二醇酯单元和至多10重量％的其它二羧酸组成的共聚物或 其它二醇和羧基膦酸单元，其结构式如下：其中R选自C 1-10 - 亚烷基，C 1-10 - 亚环烷基或C 6-10 - 亚芳基，相对于聚酯，其量相当于30-500ppm磷 。 本发明还包括生产该纤维的方法。
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公开(公告)号：US5859173A
公开(公告)日：1999-01-12
申请号：US968607
申请日：1997-11-13
IPC分类号： C08G63/692 , C08G63/00
CPC分类号： C08G63/6926
摘要： The present invention comprises a process for the production of flame-resistant polyesters with at least 50 mol-% ethylene carboxylate units through esterification or ester interchange and co-polycondensation of at least one diol and a dicarboxylic acid or its dialkyl ester with a carboxyphosphinic acid, whereby the carboxyphosphinic acid, before being added to the co-polycondensation mixture, is dissolved in ethylene glycol of not more than 90.degree. C., and the acid number of this solution is standardized to 50 to 350 mg KOH/g of carboxyphosphinic acid by adding at least one basic alkali metal compound in the absence of oxygen, and said solution is added to the co-polycondensation mixture during the second half of the esterification or ester interchange reaction.
摘要翻译： 本发明包括通过酯化或酯交换和至少一种二醇和二羧酸或其二烷基酯与羧基次膦酸的共缩聚生产具有至少50mol％乙烯羧酸酯单元的阻燃聚酯的方法 ，由此将羧基次膦酸在加入共缩合混合物中之前溶于不超过90℃的乙二醇中，该溶液的酸值标准化为50-350mg KOH / g羧基次膦酸 通过在不存在氧的情况下加入至少一种碱式碱金属化合物，并且在酯化或酯交换反应的后半段期间将所述溶液加入到共缩聚混合物中。
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公开(公告)号：US5962131A
公开(公告)日：1999-10-05
申请号：US129624
申请日：1998-08-05
申请人： Helmut Schwind , Wolfgang Janas , Klaus Dorn , Peter Kempf , Dietmar Wandel , Joachim Cziollek , Ulrich Thiele , Alexander Klein , Heinz-Dieter Schumann
发明人： Helmut Schwind , Wolfgang Janas , Klaus Dorn , Peter Kempf , Dietmar Wandel , Joachim Cziollek , Ulrich Thiele , Alexander Klein , Heinz-Dieter Schumann
IPC分类号： C08F220/14 , C08F222/04 , C08F222/40 , D01F6/92 , D02G3/00 , C08F20/00
CPC分类号： C08F222/40 , C08F220/14 , C08F222/04 , D01F6/92 , Y10T428/249921 , Y10T428/2913
摘要： Process for the production of preoriented filaments from polyester-based polymer mixtures by spinning the polymer mixtures with a draw-off speed v of at least 2500 m/min, a second amorphous, thermoplastically processable copolymer having a glass transition temperature of more than 100.degree. C. being added to the polyester, wherein the ratio of the melt viscosity of the copolymer to the melt viscosity of the polyester is 1:1 to 10:1, in that the amount of copolymer added to the polyester is at least 0.05 wt. %, in that the maximum amount M of the copolymer added to the polyester depends on the draw-off speed v, and in that ##EQU1##
摘要翻译： 通过以至少2500m / min的拉脱速度v纺丝聚合物混合物，具有玻璃化转变温度大于100℃的第二种非晶态，热塑性可加工共聚物，由聚酯类聚合物混合物生产预取向长丝的方法 加入到聚酯中，其中共聚物的熔体粘度与聚酯的熔体粘度的比例为1:1至10:1，其中加入到聚酯中的共聚物的量为至少0.05wt。 ％，因为添加到聚酯中的共聚物的最大量M取决于吸附速度v，因此
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公开(公告)号：US5235027A
公开(公告)日：1993-08-10
申请号：US786531
申请日：1991-11-01
IPC分类号： C08G63/181 , C08G63/183 , C08G63/20 , C08G63/672 , C08G63/82
CPC分类号： C08G63/82 , C08G63/181 , C08G63/183 , C08G63/20 , C08G63/672
摘要： Modified copolyethylene terephthalate, for processing by extrusion blow molding, containing units of isophthalic acid, diethylene glycol and pentaerythritol, antimony and phosphorus plus small amounts of red toner and a blue toner. Also a process for producing same by direct esterification, melt polycondensation and heat treatment in the solid phase.
摘要翻译： 改性共聚对苯二甲酸乙二醇酯，用于挤出吹塑加工，含有间苯二甲酸，二甘醇和季戊四醇的单元，锑和磷加少量的红色调色剂和蓝色调色剂。 也是通过在固相中直接酯化，熔融缩聚和热处理来生产它的方法。
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公开(公告)号：US5563209A
公开(公告)日：1996-10-08
申请号：US568874
申请日：1995-12-07
CPC分类号： C08G63/916
摘要： A process for the reduction of the carboxyl end groups of linear polyester through reaction with alkylene carbonate in the melt phase in the presence of 40 to 160 ppm of allyltriphenyl phosphonium bromide, based on the weight of the polyester.
摘要翻译： 在40至160ppm的烯丙基三苯基溴化鏻存在下，基于聚酯的重量，通过在熔融相中与碳酸亚烷酯反应来还原直链聚酯的羧基端基的方法。
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公开(公告)号：US5993712A
公开(公告)日：1999-11-30
申请号：US123769
申请日：1998-07-28
摘要： The invention concerns a method of processing polymer blends based on polyester or polyamide with a draw-off speed of .gtoreq.1500 m/min to produce filaments with an elongation at break of .ltoreq.180%, where a second amorphous polymer is added to the polyester or polyamide in the amount of 0.05 to 5 wt % and the polymer is a copolymer composed of at least two of the following monomer units:0 to 90 wt % A, wherein A is a monomer of formula CH.sub.2 .dbd.C(R)--COOR.sup.1, wherein R is --H or --CH.sub.3 and R.sup.1 is straight or branched chain C.sub.1 -C.sub.10 alkyl or cyclohexyl.0 to 40 wt % B, wherein B is a monomer of maleic acid or maleic anhydride, and5 to 85 wt % C, wherein C is a monomer of styrene or methyl substituted styrene such that (wt % A+wt % B+wt % C)=100, and these filaments are processed by a drawing process or a stretch texturing process at high speeds. Preferably R.sup.1 is methyl, ethyl, n-propyl, n-butyl, iso-butyl, 2-ethyl-butyl, 2-ethyl hexyl, n-hexyl, n-heptyl, or cyclohexyl. Preferably, C is styrene, .alpha.-methyl styrene, 3-methyl styrene, or 4-methyl styrene. Most preferably C is styrene.
摘要翻译： 本发明涉及一种以> / = 1500m / min的拉脱速度处理基于聚酯或聚酰胺的聚合物共混物的方法，以产生断裂伸长率为
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公开(公告)号：US5756033A
公开(公告)日：1998-05-26
申请号：US796396
申请日：1997-02-06
IPC分类号： C08K5/5317 , D01F6/84 , D01D5/12 , D01F6/16 , D01F6/62
CPC分类号： D01F6/84 , C08K5/5317 , Y10T428/2913
摘要： The present invention is a pre-oriented, undrawn polyester fiber spun with spooling speeds of at least 3,000 m/min., wherein the polyester is a copolymer comprised essentially of ethylene terephthalate units and up to 10 weight % of other dicarboxylic acids or other diols, and carboxy phosphonic acid units of the formula: ##STR1## wherein R is selected from C.sub.1-10 -alkylene, C.sub.1-10 -cycloalkylene or C.sub.6-10 -arylene, in a quantity corresponding to 30 to 500 ppm phosphorus, in relation to polyester. The invention also comprises a process for the production of this fiber.
摘要翻译： 本发明是一种预卷取的未拉伸聚酯纤维，其纺丝速度为至少3,000m / min，其中聚酯是基本上由对苯二甲酸乙二醇酯单元和至多10重量％的其它二羧酸或其它二醇组成的共聚物 ，和下式的羧基膦酸单元：其中R选自C 1-10 - 亚烷基，C 1-10 - 亚环烷基或C 6-10亚芳基，其量相当于30-500ppm磷，相对于 聚酯。 本发明还包括一种生产该纤维的方法。
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公开(公告)号：US5744572A
公开(公告)日：1998-04-28
申请号：US797461
申请日：1997-02-06
IPC分类号： C08G63/692 , C08G63/80 , C08G63/78
CPC分类号： C08G63/80 , C08G63/6926 , Y10T428/1352
摘要： A process for the acceleration of the polycondensation of polyester made by the esterification of at least one dicarboxylic acid with at least one diol, precondensation, melt phase polycondensation, granulation, crystallization and solid phase polycondensation comprising the addition, prior to the precondensation reaction, of from about 30 to about 900 ppm phosphorus in relation to the polyester in the form of carboxy phosphonic acid of the formula: ##STR1## wherein, R is selected from the group consisting of C.sub.1-10 -alkylene, C.sub.1-10 -cycloalkylene, and C.sub.6-10 -arylene and R.sup.1, R.sup.2, and R.sup.3 are selected from the group consisting of hydrogen, C.sub.1-10 -alkyl, C.sub.1-10 -cycloalkyl, and C.sub.6-10 -aryl, provided that at least two of R.sup.1, R.sup.2, and R.sup.3 are hydrogen.
摘要翻译： 一种通过至少一种二羧酸与至少一种二醇的酯化促进聚酯缩聚的方法，预缩合，熔融相缩聚，制粒，结晶和固相缩聚，其包括在预缩合反应之前加入 相对于具有下式的羧基膦酸形式的聚酯的约30至约900ppm的磷：其中，R选自C 1-10 - 亚烷基，C 1-10 - 亚环烷基和 C 6-10 - 亚芳基，R 1，R 2和R 3选自氢，C 1-10 - 烷基，C 1-10 - 环烷基和C 6-10 - 芳基，条件是R 1，R 2， 和R3是氢。
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