摘要:
A copolymer including a repeating unit represented by (I) wherein: Y is selected from: a carboxylic acid, sulfonic, phosphorous acid and phosphoric acid and their corresponding salt or ester; imino, amide, nitrile, hydrogen, hydroxyl and alkyl comprising from 1 to 6 carbon atoms; and R1, R2, R3, and R4 are independently selected from: hydrogen, alkyl groups comprising from 1 to 6 carbon atoms, and R1 and R2 may collectively form a ketone group or a 9, 9′-fluorene group, and R3 and R4 may collectively form a ketone group or a 9, 9′-fluorene group; R5 and R6 are independently selected from: a bond and an alkylene group comprising from 1 to 6 carbon atoms; R7 is selected from: hydrogen, alkyl, aryl, aralkyl and heteroaryl groups comprising from 1 to 8 carbon atoms which may be unsubstituted or substituted with carboxylic acid, sulfonic acid and phosphoric acid and their corresponding salt or ester, imino and amide; and X and X′ are independently selected from: a carboxylic acid, sulfonic acid and phosphoric acid and their corresponding salt or ester, imino and amide; nitrile, hydrogen, alkyl having from 1 to 6 carbon atoms and alkoxy having from 1 to 6 carbon atoms.
摘要:
The present invention describes a process for preparing a poly(aryl ether ketone) by reacting a nucleophile with 4,4′-difluorobenzophenone (4,4′-DFBP) that is improved through the use of 4,4′-DFBP that meets one or more particular purity conditions. Also described are improved poly(aryl ether ketone) produced using the invention 4,4′-DFBP. Amounts of 2,4′-difluorobenzophenone (2,4′-DFBP), 4-monofluorobenzophenone (4-FBP), chlorine, and monochloromonofluorobenzophenone in 4,4′-DFBP are discussed.
摘要:
A process for making polyarylethers provides a reaction mixture that includes a dipolar aprotic solvent for polyarylether and polyarylether forming reactants, and reacts the polyarylether-forming reactants, with removing of water with nitrogen in the absence of azeotrope forming cosolvent and optionally replacing removed amounts with dipolar aprotic solvent. The process can further include directly wet spinning the reactor solution without recovery of the polymer from the dipolar aprotic solvent through a spinneret to form hollow fibers or flat sheets suitable for membranes.
摘要:
The invention relates to heat treatment of polymorphic semicrystalline or crystallizable polymers to increase the content of the highest melting crystalline form. Such heat treatment results in a polymer powder that has a consistent, uniform melting range, improved flow and improved durability of the powder particle size for applications that require powder flow at elevated temperatures. In addition to improved powder properties, the articles produced from the powders also exhibit better physical properties in both appearance and in mechanical properties. Thus the invention also includes polymer powders and articles produced by the described processes.
摘要:
The presence of certain impurities in diphenyl sulfone have a deleterious effect on the properties of the poly(aryletherketone)s produced therein, including one or more of color, melt stability, molecular weight, crystallinity, etc. and here identify those impurities and provide processes for the removal of such impurities.
摘要:
A polyaryletherketone polymeric material, for example polyetheretherketone and composite materials comprising said polymeric material are described. The polymeric material has a melt viscosity (MV) in the range 0.05 to 0.12 kNsm−2 preferably in the range 0.085 to 0.095 kNsm−2.
摘要:
A polyaryletherketone polymeric material, for example polyetheretherketone and composite materials comprising said polymeric material are described. The polymeric material has a melt viscosity (MV) in the range 0.05 to 0.12 kNsm−2, preferably in the range 0.085 to 0.095 kNsm−2.