公开(公告)号：US5183881A

公开(公告)日：1993-02-02

申请号：US748604

申请日：1991-08-22

Applicant: Horst Jager

Inventor： Horst Jager

IPC: C07C271/28 ,  C09B29/01 ,  C09B29/08 ,  C09B29/085 ,  C09B35/025 ,  C09B43/124 ,  D06P1/39 ,  D06P3/14 ,  D06P3/24

CPC classification number: C09B43/124 ,  C09B29/0007 ,  C09B29/08 ,  C09B29/0838 ,  C09B35/025

Abstract: The new o-aminoazo compounds of the formula ##STR1## in which the substituents D, A, R and R.sub.1 and the index n have the meaning given in the description are valuable intermediates for the preparation of metal complex dyestuffs and are also highly suitable for the dyeing of wool and polyamide.

Abstract translation: 其中取代基D，A，R和R 1以及指数n具有在说明书中给出的含义的式“IMAGE”的新的O-氨基偶氮化合物是制备金属络合物染料的有价值的中间体，并且也非常适用于 染色羊毛和聚酰胺。

公开(公告)号：US5739299A

公开(公告)日：1998-04-14

申请号：US676234

申请日：1996-07-15

Applicant: Nigel Hall

Inventor： Nigel Hall

IPC: C07D333/36 ,  C07D231/38 ,  C07D275/02 ,  C07D275/04 ,  C07D277/20 ,  C07D277/50 ,  C07D277/70 ,  C07D285/08 ,  C07D285/12 ,  C07D285/135 ,  C07D307/12 ,  C07D333/38 ,  C09B29/00 ,  C09B29/01 ,  C09B29/033 ,  C09B29/08 ,  C09B29/095 ,  C09B29/15 ,  C09B29/36 ,  C09B62/825 ,  D06P1/04 ,  D06P1/38 ,  D06P3/26 ,  D06P3/82

CPC classification number: D06P3/8233 ,  C09B29/0003 ,  C09B29/0014 ,  C09B29/0025 ,  C09B29/0811 ,  C09B29/0838 ,  C09B29/095 ,  C09B29/10 ,  C09B29/36 ,  C09B62/825 ,  D06P3/26

Abstract: A process for coloring a synthetic textile material or fibre blend thereof which comprises applying to the synthetic textile material a compound or mixture thereof, which is free from water solubilizing groups, of Formula (1): A--N.dbd.N--D Formula (1) wherein A and D each independently is an optionally substituted heterocyclic or carbocyclic group and at least one of A or D carries directly at least one --SO.sub.2 F group or carries a substituent to which at least one --SO.sub.2 F group is attached except for 4-(4-fluorosulphonylphenylazo)-N,N-dimethylaniline, provided that one of A or D is not 3,5-difluorosulphonylthien-2-yl, optionally substituted 1-phenyl-pyrazol-4-yl-5-one or ##STR1## or that one of A or D does not carry an --NCH.sub.2 CH(OH)CH.sub.2 Cl, --NCOCH.sub.2 Cl or --NCH.sub.2 CH.sub.2 SO.sub.2 F substituent. The presence of one or more --SO.sub.2 F groups in a dye molecule generally improves the properties of that dye and confers surprisingly good wet fastness and light fastness properties.

Abstract translation: PCT No.PCT / GB94 / 02831 Sec。 371日期：1996年7月15日 102（e）日期1996年7月15日PCT 1994年12月30日PCT PCT。 第WO95 / 20014号公报 日期1995年7月27日一种用于着色合成纺织材料或其纤维混合物的方法，其包括向合成纺织品材料施加式（1）的无水溶性基团的化合物或其混合物：AN = N-DFormula （1）其中A和D各自独立地是任选取代的杂环或碳环基团，并且A或D中的至少一个直接携带至少一个-SO 2 F基团或携带至少一个-SO 2 F基团连接的取代基，除了4 - （4-氟磺酰基苯偶合）-N，N-二甲基苯胺，条件是A或D之一不是3,5-二氟磺酰基噻吩-2-基，任选取代的1-苯基 - 吡唑-4-基-5-酮或或A或D中的一个不携带-NCH 2 CH（OH）CH 2 Cl，-NCOCH 2 Cl或-NCH 2 CH 2 SO 2 F取代基。 染料分子中一个或多个-SO 2 F基团的存在通常改善了该染料的性质，并赋予令人惊奇的良好的耐湿牢度和耐光性能。

公开(公告)号：US4085099A

公开(公告)日：1978-04-18

申请号：US457681

申请日：1974-04-03

Applicant: Jean Marie Louis Leroy ,  Jacques Pierre Edmond Pechmeze

Inventor： Jean Marie Louis Leroy ,  Jacques Pierre Edmond Pechmeze

IPC: C09B29/08 ,  C09B31/043 ,  C09B31/047 ,  C09B43/20 ,  C09B43/30 ,  C09B29/00 ,  C09B29/26 ,  C09B31/04

CPC classification number: C09B31/043 ,  C09B29/08 ,  C09B29/0802 ,  C09B29/0809 ,  C09B29/0838 ,  C09B31/047 ,  C09B43/202 ,  C09B43/30 ,  Y10S8/922

Abstract: Dyestuffs falling within the formula: ##STR1## in which A represents the residue of a diazotizable amine free from substituents giving rise to an acid dissociation, m is 0 or 1, the benzene nucleus B may be substituted by methyl or methoxy groups, X represents a hydrogen atom or a methyl, methoxy or ethoxy group, Y represents a hydrogen or chlorine atom or a methyl, methoxy or acylamino group, n is 1, 2 or 3, Z represents --O--CO--CH.sub.2 CH.sub.2 C.sub.2 F.sub.5 or --CO--O--CH.sub.2 CH.sub.2 C.sub.2 F.sub.5 or, provided that Y is --NHCO--CH.sub.2 CH.sub.2 C.sub.2 F.sub.5, a hydrogen atom or a hydroxy, cyano, alkoxycarbonyl or acyloxy group, and R represents a substituted or unsubstituted alkyl group of low molecular weight or --(CH.sub.2).sub.n --Z wherein n and Z have the meanings given above; mixture of such dyestuffs; processes for their preparation; process for the coloration of hydrophobic fibres in which the coloring agent is a dyestuff of the formula given above or a mixture thereof; textile materials dyed or printed with a dyestuff of the formula given above or with a mixture thereof and intermediate products of the formula: ##STR2##

Abstract translation: 落在式中的染料：其中A表示不含引发酸解离的取代基的重氮化胺的残基，m为0或1，苯核B可被甲基或甲氧基取代 X表示氢原子或甲基，甲氧基或乙氧基，Y表示氢或氯原子或甲基，甲氧基或酰氨基，n为1,2或3，Z表示-O-CO-CH2CH2C2F5或-CO -O-CH 2 CH 2 C 2 F 5，或者Y为-NHCO-CH 2 CH 2 C 2 F 5，氢原子或羟基，氰基，烷氧基羰基或酰氧基，R为取代或未取代的低分子量烷基或 - （CH 2）n Z，其中n Z具有上述含义; 这种染料的混合物; 其准备过程; 疏水性纤维的着色方法，其中着色剂是上述式所示的染料或其混合物; 用上面给出的式子的染料或其混合物染色或印刷的纺织品材料和下式的中间产物：（III）

公开(公告)号：US3822246A

公开(公告)日：1974-07-02

申请号：US25358172

申请日：1972-05-15

Applicant: EASTMAN KODAK CO

Inventor： WEAVER M ,  PRIDGEN H

IPC: C09B29/08 ,  C09B31/043 ,  C09B29/36

CPC classification number: C09B29/08 ,  C09B29/0838 ,  C09B31/043

Abstract: AZO COMPOUNDS CONSISTING OF A DISPERSE DYE, PHENYL DIAZO COMPONENT AND AN ANILINE COUPLING COMPONENT SUBSTITUTED WITH AN IMIDOALKANOYLAMINO GROUP PRODUCE YELLOW TO BLUE SHADES ON POLYESTER FIBERS AND EXHIBIT EXCELLENT FASTNESS TO LIGHT AND RESISTANCE TO SUBLIMATION.

公开(公告)号：US5120872A

公开(公告)日：1992-06-09

申请号：US621392

申请日：1990-12-03

Applicant: Harald Walter ,  Rudolf Hurter

Inventor： Harald Walter ,  Rudolf Hurter

IPC: C09B29/08 ,  C09B31/047 ,  D06P1/08

CPC classification number: C09B29/0838 ,  C09B29/0803 ,  C09B29/084 ,  C09B31/047 ,  Y10S534/02

Abstract: A compound of the formula ##STR1## in which R.sub.1 and R.sub.2 independently of one another are each C.sub.1 -C.sub.10 alkyl which is unsubstituted or substituted by hydroxyl, C.sub.1 -C.sub.4 alkoxy, phenyl, sulfo, sulfato, thiosulfato, cyano or halogen, C.sub.5 -C.sub.7 cycloalkyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl, or C.sub.1 -C.sub.4 alkoxy, or phenyl or naphthyl which both are unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkanoylamino, benzoylamino, halogen or sulfo, R.sub.3 is hydrogen, halogen, C.sub.1 -C.sub.10 alkyl which is unsubstituted or substituted by hydroxyl, C.sub.1 -C.sub.4 alkoxy, phenyl, sulfo, sulfato, thiosulfato, cyano or halogen, C.sub.1 -C.sub.10 alkoxy which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkoxy, or phenoxy which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkanoylamino, benzoylamino, halogen or sulfo, X is --CO-- or --SO.sub.2 --, n is the number 1,2,3,4,5 or 6 and M is a cation.

公开(公告)号：US4994563A

公开(公告)日：1991-02-19

申请号：US372402

申请日：1989-06-27

Applicant: Harald Walter ,  Rudolf Hurter

Inventor： Harald Walter ,  Rudolf Hurter

IPC: C09B29/08 ,  C09B31/047 ,  D06P1/08

CPC classification number: C09B29/0838 ,  C09B29/0803 ,  C09B29/084 ,  C09B31/047 ,  Y10S534/02

Abstract: The azo dyes of the formula ##STR1## in which D is a diazo component, R.sub.1 and R.sub.2 independently of one another are each a C.sub.1 -C.sub.10 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or naphthyl radical each of which is substituted or unsubstituted, or R.sub.1 and R.sub.2, together with the nitrogen atom linking them, are a 5-membered, 6-membered or 7-membered ring each of which is unsubstituted or substituted by heteroatoms, R.sub.3 is hydrogen, halogen or a C.sub.1 -C.sub.10 alkyl, C.sub.1 -C.sub.10 alkoxy or phenoxy radical each of which is substituted or unsubstituted, X is --CO-- or --SO.sub.2 --, n is the number 1, 2, 3, 4, 5 or 6 and M is a cation, produce dyeings of good fastness properties on fibre materials containing nitrogen or containing hydroxyl groups. This application also relates to the preparation and use of said azo dyes and to intermediates utilized in the preparation of said azo dyes.

Abstract translation: 式（1）的偶氮染料其中D是重氮组分，R1和R2彼此独立地是C1-C10烷基，C5-C7环烷基，苯基或萘基，其各自为取代或未取代的， 或R 1和R 2与连接它们的氮原子一起为5元，6元或7元环，其各自为未取代或被杂原子取代，R 3为氢，卤素或C 1 -C 10烷基，C 1 -C 10烷基， 各自为取代或未取代的C 10烷氧基或苯氧基，X为-CO-或-SO 2 - ，n为1,2,3,4,5或6号，M为阳离子，产生良好的牢度性染色 含有氮或含羟基的纤维材料。 本申请还涉及所述偶氮染料和用于制备所述偶氮染料的中间体的制备和用途。

公开(公告)号：US5973127A

公开(公告)日：1999-10-26

申请号：US147435

申请日：1999-03-05

Applicant: Andrew John Greaves

Inventor： Andrew John Greaves

IPC: C09B29/085 ,  C09B29/01 ,  C09B29/08 ,  D06P3/26 ,  C09B29/09

CPC classification number: C09B29/0838 ,  C09B29/0807

Abstract: Dyes of formula (1) ##STR1## wherein the variables are as defined in the specification and at least one of R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 or a substituent on A being --SO.sub.2 F or a substituent to which at least one --SO.sub.2 F group is attached are water-insoluble monoazo dyes useful for coloring synthetic textile materials.

Abstract translation: PCT No.PCT / GB97 / 01705 Sec。 371日期1999年3月5日 102（e）1999年3月5日PCT Filted 1997年6月24日PCT公布。 公开号WO97 / 49770 PCT 日期1997年12月31日，式（1）的染料，其中变量如本说明书中所定义，R 1，R 2，R 3，R 4和R 5中的至少一个或A上的取代基为-SO 2 F或至少一个 -SO2F基团是用于着色合成纺织材料的水不溶性单偶氮染料。

公开(公告)号：US4667023A

公开(公告)日：1987-05-19

申请号：US382680

申请日：1982-05-27

Applicant: Ruedi Altermatt

Inventor： Ruedi Altermatt

IPC: C09B29/08 ,  C09B29/01 ,  C09B29/085 ,  D06P1/18 ,  D06P3/54

CPC classification number: C09B29/08 ,  C09B29/0838

Abstract: Monoazo compounds of the formula ##STR1## wherein R.sub.1 is chloro, bromo nitro, C.sub.1-4 alkylsulfonyl, phenylsulfonyl, (C.sub.1-4 alkyl)carbonyl or benzoyl,each of R.sub.2 and R.sub.3, independently, is hydrogen, chloro or bromo, with the proviso that at least one of R.sub.2 and R.sub.3 is hydrogen,each of R.sub.4 and R.sub.5, independently, is C.sub.1-4 alkyl, ##STR2## or in which each of R.sub.10, R.sub.11 and R.sub.12, independently, is hydrogen, chloro, bromo, methyl, methoxy or ethoxy, andR.sub.6 is C.sub.1-4 alkyl, (C.sub.1-4 alkoxy)C.sub.2-4 alkyl, phenyl or phenyl substituted by up to three substituents selected from the group consisting of choro, bromo, methyl, methoxy and ethoxy,which compounds are useful as disperse dyes for substrates consisting of or comprising hydrophobic, high molecular weight synthetic or semi-synthetic organic fibers such as polyesters, synthetic polyamides and cellulose 21/2 acetate and triacetate. The dyeings exhibit notable fastness to light, thermofixation, sublimation, pleating, wet treatments, perspiration, solvents, lubricants, rubbing, cross dyeing, ozone, gas fumes and chlorine and stability to reduction when dyed with wool. The dyes build-up particularly well on polyesters.

Abstract translation: 其中R 1是氯，溴代硝基，C 1-4烷基磺酰基，苯基磺酰基，（C 1-4烷基）羰基或苯甲酰基的单偶氮化合物，R 2和R 3各自独立地是氢，氯或溴，条件是 R 2和R 3中的至少一个是氢，R 4和R 5各自独立地是C 1-4烷基，或者其中R 10，R 11和R 12各自独立地是氢，氯，溴 ，甲基，甲氧基或乙氧基，R 6为C 1-4烷基，（C 1-4烷氧基）C 2-4烷基，苯基或被至多三个选自氯，溴，甲基，甲氧基和乙氧基的取代基取代的苯基， 可用作由疏水，高分子量合成或半合成有机纤维（如聚酯，合成聚酰胺和纤维素21/2乙酸酯和三醋酸酯）组成或包含的底物的分散染料。 染色具有显着的耐光牢度，热固性，升华，打褶，湿处理，出汗，溶剂，润滑剂，摩擦，交叉染色，臭氧，气体烟雾和氯气，并且在用羊毛染色时具有稳定性。 染料在聚酯上特别好地积聚。

公开(公告)号：US3997520A

公开(公告)日：1976-12-14

申请号：US487586

申请日：1974-07-11

Applicant: Ruedi Altermatt

Inventor： Ruedi Altermatt

IPC: C09B29/039 ,  C09B29/00 ,  C09B29/08 ,  C09B29/09 ,  C09B29/36

CPC classification number: C09B29/0838 ,  C09B29/0085 ,  C09B29/08 ,  Y10S8/921 ,  Y10S8/922 ,  Y10S8/924

Abstract: This invention relates to monoazo compounds of the formula I, ##STR1## in which R.sub.1 signifies a hydrogen atom, an alkyl radical or an unsubstituted or substituted phenyl radical,Each of R.sub.2 and R.sub.3 signifies a hydrogen atom, a cycloalkyl radical, an alkenyl radical or an unsubstituted or substituted alkyl radical, with the proviso that when one of R.sub.2 and R.sub.3 signifies a hydrogen atom, the other has a significance other than hydrogen,R.sub.4 signifies an .alpha.- or .beta.-chloro- or bromoethyl radical,R.sub.5 signifies a hydrogen atom or a methoxy or ethoxy radical, andX signifies a group of the formula --CO--or --CO--O--.These compounds are useful as disperse dyes, particularly for the exhaust dyeing, pad dyeing and printing of synthetic and semi-synthetic hydrophobic materials such as linear and aromatic polyesters, cellulose acetates and polyamides. The dyeings exhibit good fastness to light, heat treatments, wet treatments, solvents, lubricants, rubbing, cross-dyeing, ozone, gas fumes and chlorine.

Abstract translation: 本发明涉及式I的单偶氮化合物，其中R 1表示氢原子，烷基或未取代或取代的苯基，每个R 2和R 3表示氢原子，环烷基，烯基 或未取代或取代的烷基，条件是当R 2和R 3中的一个表示氢原子时，另一个具有除氢以外的含义，R 4表示α-或β-氯 - 或溴乙基，R 5表示氢 原子或甲氧基或乙氧基，X表示式-CO-或-CO-O-的基团。