RECIRCULATION AND DISPOSAL OF AQUEOUS CATALYST SOLUTIONS IN AMINE CATALYTIC PROCESSES
    2.
    发明申请
    RECIRCULATION AND DISPOSAL OF AQUEOUS CATALYST SOLUTIONS IN AMINE CATALYTIC PROCESSES 有权
    氨催化工艺中水性催化剂溶液的回收和处理

    公开(公告)号:US20160138804A1

    公开(公告)日:2016-05-19

    申请号:US14904898

    申请日:2014-07-15

    申请人: EVONIK RÖHM GMBH

    IPC分类号: F23G7/00 C07C45/75

    摘要: The present invention relates to the oxidative combustion of amine-containing wastewaters, especially in a process for preparing methacrolein. Methacrolein is used in chemical synthesis particularly as an intermediate for preparation of methacrylic acid, methyl methacrylate, or else of active ingredients, odorants or flavorings. More particularly, the present invention relates to an oxidative combustion of the amine-containing wastewaters with only low nitrogen oxide formation.

    摘要翻译: 本发明涉及含胺废水的氧化燃烧,特别是在制备异丁烯醛的方法中。 甲基丙烯醛用于化学合成,特别是作为制备甲基丙烯酸,甲基丙烯酸甲酯或其他活性成分,气味剂或调味剂的中间体。 更具体地,本发明涉及仅含低氮氧化物形成的含胺废水的氧化燃烧。

    Method and apparatus for operating a furnace
    3.
    发明授权
    Method and apparatus for operating a furnace 有权
    操作炉子的方法和装置

    公开(公告)号:US08974226B2

    公开(公告)日:2015-03-10

    申请号:US14007906

    申请日:2012-03-27

    申请人: Frank Rheker

    发明人: Frank Rheker

    摘要: The present invention relates to a method for operating combustion process in a furnace whereby a primary fuel and a secondary fuel are burnt, to an apparatus for injecting liquid oxygen into the furnace and also to the corresponding furnace. The method comprises at least the following steps: the primary fuel and a primary oxidizer are injected into the furnace to create a primary combustion zone, liquid oxygen is injected in as secondary oxidizer such that the secondary fuel combusts with the secondary oxidizer thereby creating a distinct secondary combustion zone. The invention makes it possible for a secondary fuel having a significantly lower calorific value than the primary fuel to be burnt completely in the furnace, such that a product to be produced in the furnace has an improved quality.

    摘要翻译: 本发明涉及一种在燃烧主燃料和二次燃料的炉中操作燃烧过程的方法,用于将液体氧注入炉内以及相应炉中的装置。 该方法至少包括以下步骤:将一次燃料和一次氧化剂注入炉中以产生主燃烧区,将液氧作为次级氧化剂注入,使得次级燃料与次级氧化剂一起燃烧,从而产生明显的 二次燃烧区。 本发明使得具有比初级燃料显着低的发热量的二次燃料可以在炉中完全燃烧,使得在炉中产生的产品具有改进的质量。

    Method for reducing nitrogen oxide on the primary side in a two-stage combustion process
    5.
    发明授权
    Method for reducing nitrogen oxide on the primary side in a two-stage combustion process 有权
    在两级燃烧过程中还原初级侧的氮氧化物的方法

    公开(公告)号:US08544394B2

    公开(公告)日:2013-10-01

    申请号:US12278385

    申请日:2007-01-18

    申请人: Hans Hunsinger

    发明人: Hans Hunsinger

    IPC分类号: F23L7/00 F23G5/00

    摘要: Method for reducing a formation of nitrogen oxide on a primary side of a furnace and reducing or avoiding nitrous oxide and ammonia slip in an offgas of the furnace in which a fuel is burned in a combustion process having at least two stages. The method includes passing a fuel consecutively through each of a plurality of bed areas of a combustion bed of the furnace. A primary gas including oxygen is fed individually to each of the bed areas so as to burn the fuel in the combustion chamber of the furnace. A secondary gas including oxygen is introduced into a downstream offgas burn-out zone, so as to after-burn incompletely burned offgas components formed during the burning of the fuel. Partial offgas streams from the combustion bed areas are axially mixed by injecting a water-gas mixture as at least one free jet above a surface of the combustion bed upstream from the downstream offgas burn-out zone so that the at least one free jet penetrates the partial offgas streams of the combustion bed areas to reduce a heating value of the offgas between the surface of the combustion bed and the downstream offgas burn-out zone.

    摘要翻译: 一种用于减少在炉的初级侧上形成氮氧化物并减少或避免一氧化二氮和氨在其燃料在具有至少两个阶段的燃烧过程中燃烧的废气中脱落的方法。 该方法包括使燃料连续地通过炉的燃烧床的多个床区域中的每一个。 包括氧的主要气体被单独地供给到每个床区域,以便燃烧在炉的燃烧室中的燃料。 将包括氧气的二次气体引入下游废气排出区域,以便在燃烧燃烧期间形成的后燃烧不完全燃烧的废气部件。 从燃烧床区域的部分废气流通过将水煤气混合物作为至少一个在下游废气排出区上游的燃烧床表面的自由射流喷射,从而使至少一个自由射流渗入 燃烧床区域的部分废气流以减少燃烧床表面和下游废气烧尽区域之间的废气的加热值。

    METHOD FOR REDUCING NITROGEN OXIDE ON THE PRIMARY SIDE IN A TWO-STAGE COMBUSTION PROCESS
    8.
    发明申请
    METHOD FOR REDUCING NITROGEN OXIDE ON THE PRIMARY SIDE IN A TWO-STAGE COMBUSTION PROCESS 有权
    在两阶段燃烧过程中减少主要氧化氮的方法

    公开(公告)号:US20090020048A1

    公开(公告)日:2009-01-22

    申请号:US12278385

    申请日:2007-01-18

    申请人: Hans Hunsinger

    发明人: Hans Hunsinger

    IPC分类号: F23G5/00 F23J15/00

    摘要: Method of reducing the nitrogen oxide formation (NOx) on the primary side and of at the same time avoiding the formation of nitrous oxide (N2O) and ammonia slip (NH3) in the exhaust gas of a two-stage combustion process and of improving the slag balance, comprising a fixed-bed burn-out zone, through which an oxygenous primary gas flows, above a fuel bed and a downstream exhaust-gas burn-out zone into which oxygenous secondary gas is additionally introduced. The object is to propose a simple and reliably controllable method for reducing nitrogen oxide formation on the primary side in combustion plants, for example grate combustion plants, with considerably higher efficiency, wherein no additional pollutants are produced or the utilization of the energy of the heat content of the combustion gases is only marginally impaired. The object is achieved in that the calorific value of the exhaust gas between the fuel bed surface and upstream of the exhaust-gas burn-out zone is reduced in such a way that an average calorific value of less than 1 MJ/m3 occurs, and the temperature of the fuel bed surface is at least 950° C. until the exhaust gas leaves the exhaust-gas burn-out zone, and the gas temperature above the fuel bed in the region of the rear grate half is more than 1000° C.

    摘要翻译: 减少初级侧的氮氧化物形成(NOx)的方法,同时避免在二级燃烧过程的废气中形成一氧化二氮(N2O)和氨气(NH3),并改善 炉渣平衡,包括固定床燃尽区,氧气一次气体通过该固定床燃尽区流过燃料床和下游排气废气区,再次引入氧二次气体。 本发明的目的是提出一种简单且可靠地控制的方法,用于减少燃烧装置中的初级侧的氮氧化物形成,例如炉排燃烧装置,其效率相当高,其中不产生额外的污染物或利用热能 燃烧气体的含量仅略微受损。 其目的在于,燃料床表面与排气废气区上游之间的废气的发热量减少,发生平均发热量小于1MJ / m3, 燃料床表面的温度至少为950℃,直到废气离开排气废气区域,并且后炉排半部分区域内的燃料床上方的气体温度大于1000℃ 。

    Device and Method for Destroying Liquid, Powder or Gaseous Waste Using an Inductively Coupled Plasma
    9.
    发明申请
    Device and Method for Destroying Liquid, Powder or Gaseous Waste Using an Inductively Coupled Plasma 有权
    使用电感耦合等离子体破坏液体,粉末或气体废物的装置和方法

    公开(公告)号:US20080286169A1

    公开(公告)日:2008-11-20

    申请号:US10588955

    申请日:2005-02-16

    IPC分类号: B01J19/08 H05H1/26 F23G5/10

    摘要: The invention relates to a thermal destruction process for at least one organic or halogenated organic product in liquid, gaseous or powder form. The process includes mixing: of the aforementioned one or more organic products with water in sufficient quantities to ensure that at least stoichiometric ratios between atoms of carbon and oxygen in the mixture are obtained, or of the aforementioned one or more halogenated organic products with water in sufficient quantities to ensure that at least the stoichiometric ratios for, on the one hand, atoms of carbon and oxygen in the mixture, and on the other hand, for hydrogen and halogen atoms in the mixture are obtained, introduction of this mixture and of plasmagenic gases into the coil of an inductively coupled plasma torch to produce gas in which decomposition into atomic elements has occurred, an initial thermal destruction operation of the aforementioned gas in which decomposition into atomic elements has occurred, this initial destruction operation taking place in a reaction chamber, a second thermal destruction operation of the gas that has undergone the initial destruction operation, this second destruction operation taking place in a stirring device with no energy being added, this gas which undergoes the second thermal destruction operation being stirred with air and/or oxygen, recombination by cooling of at least a part of the gas emerging from the stirring device, discharge of the gas that has been destroyed. The invention also relates to a device that allows this destruction process to be applied.

    摘要翻译: 本发明涉及至少一种液体,气态或粉末形式的有机或卤化有机产物的热破坏过程。 该方法包括将上述一种或多种有机产物与足够量的水混合,以确保获得混合物中碳和氧原子之间的至少化学计量比,或上述一种或多种含水的卤代有机产物 足以确保至少一方面混合物中碳和氧原子的化学计量比,另一方面获得混合物中的氢和卤素原子的化学计量比,引入该混合物和等离子体发生 气体进入电感耦合等离子体焰炬的线圈,以产生其中已经发生分解为原子元素的气体,其中已经发生分解成原子元素的上述气体的初始热破坏操作,这种初始破坏操作发生在反应室 ,是经历了初始破坏剧场的气体的第二次热破坏操作 在没有加入能量的搅拌装置中发生第二次破坏操作,经历第二热破坏操作的气体与空气和/或氧气一起搅拌,通过冷却至少一部分从 搅拌装置,排放已被破坏的气体。 本发明还涉及允许应用该破坏过程的装置。

    Incineration process using high oxygen concentrations
    10.
    发明授权
    Incineration process using high oxygen concentrations 失效
    使用高氧浓度的焚烧过程

    公开(公告)号:US06952997B2

    公开(公告)日:2005-10-11

    申请号:US10481205

    申请日:2002-06-24

    摘要: A process for incinerating combustible materials including the steps of: delivering combustible material and inlet gases to a primary combustion chamber, the inlet gases having an oxygen content of at least 50 vol %; burning the combustible material with the oxygen of the inlet gases in the primary combustion chamber producing flue gases and solid particulates as thermal decomposition products of the burnt combustible material; passing the flue gases and particulates to a secondary combustion chamber where further combustion occurs; cooling the flue gases exiting the secondary combustion chamber; returning a portion of the cooled flue gases to at least one of the combustion chambers where the cooled gases moderate the temperature in the at least one chamber; and passing the remaining portion of cooled flue gases on to a flue gas purification system where pollutants in the flue gases and particulates are substantially converted to benign compounds or removed entirely before the flue gases are emitted into the atmosphere.

    摘要翻译: 一种用于焚烧可燃材料的方法,包括以下步骤:将可燃材料和入口气体输送到主燃烧室,所述入口气体具有至少50vol%的氧含量; 用主燃烧室中的入口气体的氧气燃烧可燃材料,产生烟气和固体颗粒作为燃烧的可燃材料的热分解产物; 将烟道气和微粒通过二次燃烧室,进一步燃烧; 冷却离开二次燃烧室的烟气; 将一部分冷却的烟道气返回到至少一个燃烧室,其中冷却的气体调节至少一个室中的温度; 并将剩余部分的冷却烟道气通入烟道气净化系统,其中烟道气和微粒中的污染物基本上转化为良性化合物,或者在烟气排放到大气中之前完全去除。