N-substituted amino acid derivatives
    1.
    发明授权
    N-substituted amino acid derivatives 失效
    N-取代氨基酸衍生物

    公开(公告)号:US4054668A

    公开(公告)日:1977-10-18

    申请号:US619125

    申请日:1975-10-02

    CPC classification number: A01N37/44

    Abstract: Novel N-substituted amino acid derivatives of the formula: ##STR1## wherein R.sub.1 is an alkenyl group having 2 to 5 carbon atoms, a halogen-substituted alkenyl group having 2 to 5 carbon atoms or an alkynyl group having 2 to 5 carbon atoms, R.sub.2 is a methyl or ##STR2## group in which R.sub.2 ' is an alkyl group having 1 to 4 carbon atoms or a halogen-substituted alkyl group having 1 to 4 carbon atoms; and R.sub.3 is a hydrogen atom, an alkyl having 1 to 20 carbon atoms, cycloalkyl having 3 to 6 carbon atoms, benzyl, hydroxyethyl or methoxyethyl group, and inorganic or organic acid addition salts thereof, which possess useful soil fungicidal activities and can be produced by reacting a sarcosine derivative of the formula:CH.sub.3 HNCH.sub.2 COOR.sub.3 (II)wherein R.sub.3 is as defined above, with a halogen compound of the formula:R.sub.1 -- X (III)wherein R.sub.1 is as defined above and X is a halogen atom, or by reacting an N-substituted glycine derivative of the formula: ##STR3## wherein R.sub.1 and R.sub.3 are as defined above, with an acyl compound of the formula: ##STR4## wherein R.sub.2 ' is as defined above and X is a halogen atom.

    Abstract translation: 式(I)的新型N-取代氨基酸衍生物:其中R 1是具有2至5个碳原子的烯基,具有2至5个碳原子的卤素取代的烯基或具有2至5个炔基的新的N-取代的氨基酸衍生物 碳原子,R2是甲基或者基团,其中R2'是具有1至4个碳原子的烷基或具有1至4个碳原子的卤素取代的烷基; R3为氢原子,碳原子数1〜20的烷基,碳原子数为3〜6的环烷基,苄基,羟乙基或甲氧基乙基,以及无机或有机酸加成盐,具有有效的土壤杀真菌活性, 通过使下式的肌氨酸衍生物:

    N-carboalkoxymethyl-N-halomethyl amides
    2.
    发明授权
    N-carboalkoxymethyl-N-halomethyl amides 失效
    N-烷氧基甲基-N-卤代甲基酰胺

    公开(公告)号:US4535181A

    公开(公告)日:1985-08-13

    申请号:US609921

    申请日:1984-05-14

    Inventor: Raymond A. Felix

    CPC classification number: C07F9/4006 C07C233/47 C07F9/3813

    Abstract: A method of preparing N-phosphonomethylglycine comprising (a) reacting a substituted triazine with an acyl halide to form the N-carboalkoxymethyl-N-halomethyl amide of the acyl halide; reacting the said amide with a phosphite to form a phosphonate compound; and hydrolyzing said phosphonate to yield N-phosphonomethylglycine.

    Abstract translation: 一种制备N-膦酰基甲基甘氨酸的方法,包括(a)使取代的三嗪与酰基卤反应形成酰卤的N-烷氧基甲基-N-卤甲基酰胺; 使所述酰胺与亚磷酸酯反应以形成膦酸酯化合物; 并水解所述膦酸酯以产生N-膦酰基甲基甘氨酸。

    Di-mixed alky aspartate salts
    6.
    发明授权
    Di-mixed alky aspartate salts 失效
    二混合天冬氨酸盐

    公开(公告)号:US4026915A

    公开(公告)日:1977-05-31

    申请号:US608376

    申请日:1975-08-27

    CPC classification number: C07D295/13 C11D1/62 C11D3/001 D06M13/461

    Abstract: Novel fabric softener compounds having the formula ##STR1## wherein R is hydrogen or methyl, R.sub.1 and R.sub.2 are the same or different and are selected from linear and branched chain alkyl groups having from 8 to 22 carbon atoms; R.sub.3 is selected from hydrogen, formyl, acetyl, benzoyl; R.sub.4 and R.sub.5 being the same or different and selected from lower alkyl groups having from 1 to 4 carbon atoms, -hydroxyalkyl groups having from 2 to 4 carbon atoms and R.sub.4 and R.sub.5 taken together are diethylene oxide, R.sub.6 is selected from hydrogen, lower alkyl having from 1 to 4 carbon atoms and benzyl; n is a whole number selected from 2 to 10; and A is an anion selected from methyl sulfate, ethyl sulfate, chlorides, fluorides, sulfates, acetates, bromides, iodides, benzoates and gluconates.

    Abstract translation: 具有式的新型织物柔软剂化合物,其中R是氢或甲基,R 1和R 2相同或不同,并且选自具有8至22个碳原子的直链和支链烷基; R3选自氢,甲酰基,乙酰基,苯甲酰基; R4和R5相同或不同,并且选自具有1至4个碳原子的低级烷基,具有2至4个碳原子的羟基烷基和R 4和R 5一起是二亚乙基氧,R 6选自氢,低级烷基 具有1至4个碳原子和苄基; n是选自2至10的整数; A是选自甲基硫酸盐,乙基硫酸盐,氯化物,氟化物,硫酸盐,乙酸盐,溴化物,碘化物,苯甲酸盐和葡萄糖酸盐的阴离子。

    N,N-Disubstituted acryl- and methacrylamides
    8.
    发明授权
    N,N-Disubstituted acryl- and methacrylamides 失效
    N,N-二取代的丙烯酰基和甲基丙烯酰胺

    公开(公告)号:US4159383A

    公开(公告)日:1979-06-26

    申请号:US235815

    申请日:1972-03-17

    CPC classification number: C08F20/58

    Abstract: N,N-disubstituted acryl- and methacrylamides are disclosed wherein one of the amido nitrogen atom substituents is an n-propionate radical and the other of such substituents is a hydrocarbyl group. The disclosed compounds are useful as comonomers for the preparation of polyvinyl resinous systems in general.

    Abstract translation: 公开了N,N-二取代的丙烯酰胺和甲基丙烯酰胺,其中酰氨基氮原子取代基之一是正丙酸根,而另一个这样的取代基是烃基。 所公开的化合物通常用作制备聚乙烯基树脂体系的共聚单体。

    Preparation of n-acyl amino alkanoic acids
    10.
    发明授权
    Preparation of n-acyl amino alkanoic acids 失效
    N-亚氨基氨基酸的制备

    公开(公告)号:US3796751A

    公开(公告)日:1974-03-12

    申请号:US3796751D

    申请日:1970-10-12

    Applicant: ALLIED CHEM

    CPC classification number: C07C233/46

    Abstract: A PROCESS FOR TRANSFORMING AN ALKYL AMINO ACID SALT OF A MINERAL ACID INTO THE CORRESPONDING N-ACYL AMINO ALKANOIC ACID COMPRISING NEUTRALIZING THE MINERAL ACID PORTION. THE AMMONIUM SALT IS SEPARATED OUT BY ADDING ALKADROXIDE, SEPARATING OUT THE THEREBY FORMED AMMONIUM SALT OF THE MINERAL ACID, AND ACYLATING THE REMAINING SOLUTION. THE AMMONIUM SALT IS SEPARATED OUT BY ADDING ALKANOC ACID TO THE NEUTRALIZED SOLUTION.

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