摘要:
A stabilized chlorinated solvent composition useful in removing grease from metals wherein the solvent is perchloroethylene or trichloroethylene, and the stabilizer is N-methyl pyrrole in combination with ethyl acetate, acetonitrile or pyrazine.
摘要:
All or a portion of chlorinated hydrocarbons convertible to trichloroethylene and/or perchloroethylene by chlorination, dehydrochlorination or dehydrogenation and optionally also dechloroination are recovered from a C.sub.2 chlorinated hydrocarbon waste stream and contacted with a molten mixture of, for example, cuprous chloride, cupric chloride and copper oxychloride and hydrogen chloride and/or chlorine, to produce an effluent which contains as reaction product trichloroethylene and/or perchloroethylene. Chlorinated components in the waste stream not contacted with the molten mixture can be burned and the chlorine values used to enrich the chlorine content of the melt.
摘要:
A bed of calcium oxide and/or barium oxide in particulate form is continuously moved through a contact reaction zone such that it enters into countercurrent reaction with the feedstock and the reaction is performed in a reaction column equipped with an agitating/moving device by which the halide which is the product of reaction between the organic halide and the oxide is continuously discharged to the outside of the reaction zone.
摘要:
The pyrolytic dehydrochlorination of haloalkanes is carried out with an initiator comprising chiefly decachlorobutane and octachloro-1-butene.The process can be applied particularly to the production of chloroethylenes from the corresponding polychloroethanes.
摘要:
The process of preparing trichloroethylene from 1,1,1,2-tetrachloroethane by decomposition of the tetrachloroethane under a pressure within the range of 1.5 to 10 bars and at a temperature within the range of 135.degree. to 250.degree. C and the treatment of the effluent from the reaction zone for recovery of components thereof.
摘要:
PROCESS FOR PRODUCING POLYCHLORINATED ETHANES CONTAINING AT LEAST THREE CHLORINE ATOMS IN THE MOLECULE OR POLYCHLORINATED ETHYLENES AT LEAST TWO CHLORINE ATOMS IN THE MOLECULE WHICH COMPRISES THE CONTINUOUS REACTION STEPS OF PRODUCING POLYCHLORINATED ETHANES CONTAINING AT LEAST THREE CHLORINE ATOMS IN THE MOLECULE BY CONTACTING CHLORINE WITH 1,2-DICHLOROETHANE IN THE PRESENCE OF CHLORINATED ETHYLNESS CONTAINING AT LEAST ONE CHLORINE ATOM, PYROLYZING THE RESULTANT MIXTURE, AND ADDING HYDROGEN CHLORIDE TO THE PYROLYZED MIXTURE EITHER AS IT IS OR AFTER SEPARATION OF TRICHLOROETHYLENE AND TETRACHLOROETHYLENE THEREFROM; THE INTENDED POLYCHLORINATED ETHANES OR ETHYLENES BEING RECOVERED AT ONE OF THESE THREE STEPS.