-
公开(公告)号：US5414109A
公开(公告)日：1995-05-09
申请号：US198918
申请日：1994-02-18
申请人： Eit Drent , Eric Kragtwijk
发明人： Eit Drent , Eric Kragtwijk
IPC分类号： B01J31/28 , C07B61/00 , C07C51/14 , C07C57/05 , C07C57/16 , C07C67/38 , C07C69/54 , C07C69/618 , C07C67/36
摘要： A process for the carbonylation of acetylenically unsaturated compounds in the presence of a nucleophilic compound having one or more removable hydrogen atoms and a catalyst system based on a source of platinum, a bisphosphine of the formula R.sub.1 R.sub.2 PRPR.sub.3 R.sub.4 wherein each of R.sub.1,R.sub.2,R.sub.3 and R.sub.4 independently represents a hydrocarbyl group and R represents a bivalent bridging group and a source of anions from a conjugated base of an acid having a pKa of less than 4.
摘要翻译： 在具有一个或多个可移除氢原子的亲核化合物存在下羰基化炔属不饱和化合物的方法和基于铂源的催化剂体系，式R1R2PRPR3R4的双膦，其中R 1，R 2，R 3和R 4各自 独立地表示烃基，R表示二价桥连基团和来自pKa小于4的酸的共轭碱的阴离子源。
-
公开(公告)号：US3143408A
公开(公告)日：1964-08-04
申请号：US25430463
申请日：1963-01-28
申请人： ROHM & HAAS
发明人： SMYTHE CARL V , KRASKIN KENNETH S
-
公开(公告)号：US10337034B2
公开(公告)日：2019-07-02
申请号：US15964465
申请日：2018-04-27
摘要： This disclosure relates to compositions and methods for converting biomass to various chemical intermediates and final products including fuels. Aspects include the depolymerization of lignin, cellulose, and hemicellulose to a wide slate of depolymerization compounds that can be subsequently metabolized by genetically modified bacterium, and converted to cis,cis-muconic acid. Other aspects include the use of monometallic catalysts for converting the cis,cis-muconic acid to commodity chemicals and fuels, for example adipic acid and/or nylon.
-
4.发明授权Preparation of muconic acid mononitriles and copper(II)-ammonia reagent therefor 失效制备粘酸单体和铜（II） - 氨试剂
公开(公告)号：US4335010A
公开(公告)日：1982-06-15
申请号：US230761
申请日：1981-02-02
IPC分类号： C01G3/14 , C07C57/16 , C07C120/00
CPC分类号： C07C255/00 , C01G3/14
摘要： Substituted and unsubstituted phenols, catechols and orthobenzoquinones are converted to muconic acid mononitriles by reaction with copper(II)-ammonia reagents. The copper(II)-ammonia reagents can be prepared by the reaction of cuprous chloride with oxygen or air in liquid ammonia or in ammonium hydroxide or in pyridine followed by addition of ammonia or ammonium hydroxide. The muconic acid mononitriles are useful as monomers or comonomers and as intermediates in the manufacture of substituted and unsubstituted 6-aminocaproic acids, caprolactams and polyamides.
摘要翻译： 通过与铜（II） - 氨试剂的反应将取代和未取代的酚，儿茶酚和邻苯醌被转化成粘康酸单腈。 铜（II） - 氨试剂可以通过氯化亚铜与氧气或空气在液氨或氢氧化铵或吡啶中反应，然后加入氨或氢氧化铵来制备。 粘康酸单腈可用作单体或共聚单体，也可用作制备取代和未取代的6-氨基己酸，己内酰胺和聚酰胺的中间体。
-
公开(公告)号：US4725542A
公开(公告)日：1988-02-16
申请号：US457808
申请日：1983-01-13
申请人： Sol J. Barer , Peter C. Maxwell , Jih-Han Hsieh
发明人： Sol J. Barer , Peter C. Maxwell , Jih-Han Hsieh
CPC分类号： C08G69/28 , C07C57/16 , C12P7/44 , Y10S435/877
摘要： This invention provides a process for producing nylon 6,6 salt which involves bioconversion of toluene to muconic acid in the presence of hexamethylenediamine to yield hexamethylenediamine muconate salt. Hydrogenation of this salt provides an aqueous solution of the desired hexamethylenediamine adipate salt.
摘要翻译： 本发明提供了一种生产尼龙6,6盐的方法，该方法涉及在六亚甲基二胺存在下将甲苯生物转化为粘康酸，以产生六亚甲基二胺粘酸盐。 该盐的氢化提供所需的己二胺己二酸盐的水溶液。
-
公开(公告)号：US4031136A
公开(公告)日：1977-06-21
申请号：US651263
申请日：1976-01-22
申请人： Lorenz Heiss
发明人： Lorenz Heiss
摘要： Process for the preparation of trans, trans-muconic acid by reacting a glyoxalacetal with ketene in the presence of an acid catalyst and hydrolyzing the .beta., .beta.'-dialkoxy-adipic acid-alkylester formed with alkali. By this new process trans, trans-muconic acid is easily obtained in better yield, which compound is an important intermediate for the production of 1,4-naphthalene-dicarboxylic acid esters.
摘要翻译： 通过在酸催化剂存在下使乙二醛缩醛与烯酮反应并水解由碱形成的β，β'-二烷氧基 - 己二酸 - 烷基酯制备反式，反式 - 粘酸的方法。 通过这种新方法反式，以更好的产率容易地获得反式 - 粘酸，该化合物是生产1,4-萘二羧酸酯的重要中间体。
-
公开(公告)号：US3481977A
公开(公告)日：1969-12-02
申请号：US3481977D
申请日：1968-07-10
申请人： ARMOUR & CO
发明人： MILLER EUGENE J JR , MAIS AGO , SAY DOMINGO
-
公开(公告)号：US20190135727A1
公开(公告)日：2019-05-09
申请号：US16304317
申请日：2017-05-31
IPC分类号： C07C51/377 , C07C57/16
摘要： According to an example aspect of the present invention, there is provided a continuous method of producing muconic acid from aldaric acid in the presence of a solid heterogeneous catalyst and an alcohol solvent with short reaction time. Another aspect of the present invention is the use of a non-expensive solid heterogenous catalyst, which is automatically separated from the product.
-
公开(公告)号：US20180291405A1
公开(公告)日：2018-10-11
申请号：US15964465
申请日：2018-04-27
CPC分类号： C12P7/44 , C07C51/36 , C07C51/43 , C07C51/47 , C12N9/88 , C12Y113/11001 , C12Y401/01063 , C12Y402/01118 , C07C55/14 , C07C57/16
摘要： This disclosure relates to compositions and methods for converting biomass to various chemical intermediates and final products including fuels. Aspects include the depolymerization of lignin, cellulose, and hemicellulose to a wide slate of depolymerization compounds that can be subsequently metabolized by genetically modified bacterium, and converted to cis,cis-muconic acid. Other aspects include the use of monometallic catalysts for converting the cis,cis-muconic acid to commodity chemicals and fuels, for example adipic acid and/or nylon.
-
公开(公告)号：US4929396A
公开(公告)日：1990-05-29
申请号：US661705
申请日：1984-10-17
申请人： Sol J. Barer , Peter C. Maxwell , Jih-Han Hsieh
发明人： Sol J. Barer , Peter C. Maxwell , Jih-Han Hsieh
摘要： This invention provides hexamethylenediamine muconate salt. This novel salt can be produced by bioconversion of toluene to muconic acid in the presence of hexamethylenediamine. Hydrogenation of this salt provides hexamethylenediamine adipate salt.
摘要翻译： 本发明提供六亚甲基二胺粘酸盐。 这种新型盐可以通过在六亚甲基二胺的存在下将甲苯生物转化成粘康酸来生产。 该盐的氢化得到己二胺己二酸盐。
-
-
-
-
-
-
-
-
-
搜索结果
10 条记录 (耗时 0.014 秒)
