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    Substituted tetrathiotetracenes and tetraselenotetracenes
    1.
    发明授权
    Substituted tetrathiotetracenes and tetraselenotetracenes 失效

    公开(公告)号：US4981962A

    公开(公告)日：1991-01-01

    申请号：US356824

    申请日：1989-05-24

    申请人： Marcus Baumann ,  Walter Fischer ,  Vratislav Kvita ,  Carl W. Mayer ,  Wolfgang Wernet

    发明人： Marcus Baumann ,  Walter Fischer ,  Vratislav Kvita ,  Carl W. Mayer ,  Wolfgang Wernet

    IPC分类号： B05D1/20 ,  C07D495/06 ,  C07D517/06 ,  C07D517/16 ,  C08G61/12 ,  C09K9/02 ,  H01B1/12

    CPC分类号： C07D495/06 ,  B05D1/202 ,  B82Y30/00 ,  B82Y40/00 ,  C07D517/06 ,  C07D517/08 ,  C08G61/123 ,  C09K9/02 ,  H01B1/121

    摘要： Substituted tetrathiotetracenes and tetraselenotetracenes of the formula I ##STR1## in which Z is --S-- or --Se-- and (a) R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are H and R.sup.5 to R.sup.8 are each H and at least one of the radicals R.sup.5 to R.sup.8 independently of one another is a substituent belonging to the group comprising C.sub.1 -C.sub.20 alkyl--X--.sub.p which is unsubstituted or substituted by halogen, --CN, --CONR.sup.9 R.sup.10, --OR.sup.9, --SR.sup.9 or --COOR.sup.9, with the exception of C.sub.1 -C.sub.4 alkyl and methoxy, C.sub.2 -C.sub.18 alkenyl--X--.sub.p, C.sub.2 -C.sub.18 -alkynyl--X--.sub.p, C.sub.3 -C.sub.8 cycloalkyl--X--.sub.p, (C.sub.1 -C.sub.12 alkyl)--C.sub.3 -C.sub.8 cycloalkyl--X--.sub.p, C.sub.3 -C.sub.8 cycloalkyl-C.sub.r H.sub.2r --X--.sub.p, (C.sub.1 -C.sub.12 alkyl)-C.sub.3 -C.sub.8 -cyclo alkyl-C.sub.r H.sub.2r --X--.sub.p, phenyl--X--.sub.p, (C.sub.1 -C.sub.12)alkyl)-phenyl--X--, phenyl-C.sub.r H.sub. 2r --X--.sub.p and (C.sub.1 -C.sub.12 alkyl)-phenyl-C.sub.r H.sub.2r --X--.sub.p, r is 1 or 2 and p is 0 or 1 and X is --O--, --S--, --SO-- or --SO.sub.2 --, or R.sup.5 to R.sup.8 independently are a substituent belonging to the group comprising --Br, --CF.sub.3, --CN, --Si(C.sub.1 -C.sub.4 alkyl).sub.3, --S--(C.sub.m H.sub.2m O)--.sub.n R.sup.11 or --O--C.sub.m H.sub.2m --O--R.sup.11, or each one of R.sup.5 to R.sup.8 is --F or --Cl and at least one further member of R.sup.5 to R.sup.8 is a substituent of the groups defined above, including C.sub.1 -C.sub.4 alkyl and methoxy, R.sup.9 and R.sup.10 independently of one another are H, C.sub.1 -C.sub.12 alkyl, phenyl or --C.sub.m H.sub.2m --O--.sub.q R.sup.11, or R.sup.9 and R.sup.10 together are tetramethylene, pentamethylene, 3-oxapentylene or --CH.sub.2 CH.sub.2 NR.sup.9 CH.sub.2 CH.sub.2 --, R.sup.11 is H or C.sub.1 -C.sub.12 -alkyl, m is a number from 2 to 4, n is a number from 2 to 20 and q is a number from 1 to 20, orb) R.sup.1 to R.sup.8 independently of one another are H or one of the substituents defined above, including C.sub.1 -C.sub.4 alkyl and methoxy, or --COOR.sup.9 or --CONR.sup.9 R.sup.10 or two pairs of adjacent radicals of R.sup.1 to R.sup.8 are --CO--O--CO-- or --CO--NR.sup.9 --CO--, and at least one of R.sup.1 to R.sup.4 and also R.sup.5 to R.sup.8 is a substituent, with the exception of R.sup.2, R.sup.3, R.sup.6 and R.sup.7 when these are --F and methyl, and where R.sup.9 and R.sup.10 are as defined above.With electron acceptors they form charge-transfer complexes which can be used as organic electrical conductors, displays, optical switches and sensors.

    Process for producing 3,4,9,10-tetrathioperylene and 3,4,9,10-tetraselenoperylene
    2.
    发明授权
    Process for producing 3,4,9,10-tetrathioperylene and 3,4,9,10-tetraselenoperylene 失效
    制备3,4,9,10-四硫杂环戊烯和3,4,9,10-四硒代环戊烯的方法

    公开(公告)号：US4505858A

    公开(公告)日：1985-03-19

    申请号：US538022

    申请日：1983-09-30

    申请人： Carl W. Mayer

    发明人： Carl W. Mayer

    IPC分类号： C07D495/06 ,  C07D517/06 ,  C07D333/00

    CPC分类号： C07D495/06 ,  C07D517/06 ,  C07D517/08

    摘要： Chalcogen-substituted perylenes of the formula I ##STR1## wherein X is S or Se can be obtained in a simple manner, under mild reaction conditions and in pure form by heating a compound of the formula II ##STR2## in nitrobenzene, or in a mixture of nitrobenzene and an organic solvent miscible therewith and inert under the reaction conditions, in the presence of a Lewis acid or a protonic acid at 20.degree. to 120.degree. C. The perylenes of the formula I are used for example as donors for the production of organic conductors or semiconductors (charge-transfer-salts).

    摘要翻译： 可以在温和的反应条件下以简单的方式获得其中X为S或Se的式I化合物（I）的硫族原子取代的二萘嵌苯，并且通过加热式II化合物（II） 在硝基苯中，或在硝基苯和可与之混合的有机溶剂的混合物中，在反应条件下，在路易斯酸或质子酸存在下，在20-120℃下，将式I的苝用于 例如作为生产有机导体或半导体（电荷转移盐）的供体。

    Chalcogenated tetracene organic metals
    3.
    发明授权
    Chalcogenated tetracene organic metals 失效
    硫属化四苯有机金属

    公开(公告)号：US4046950A

    公开(公告)日：1977-09-06

    申请号：US668116

    申请日：1976-03-18

    申请人： Lawrence Clair Isett

    发明人： Lawrence Clair Isett

    IPC分类号： C07D495/08 ,  C07D517/06 ,  C09K3/16 ,  D06M23/00 ,  G03C1/85 ,  G03G5/10 ,  G11B5/70 ,  G11B5/72 ,  H01B1/12 ,  H01B1/00

    CPC分类号： D06M23/00 ,  C09K3/16 ,  G03C1/85 ,  G03G5/10 ,  G11B5/70 ,  G11B5/72 ,  H01B1/121

    摘要： Organic ion-radical salts having the electrical properties of metals and elements having a layer containing these salts are disclosed. The salts are salts of a chalcogenated tetracene donor compound and an electron acceptor compound wherein the ratio of donor compound to acceptor compound is from about 3:1 to about 1.5:1. These salts have a resistivity less than about 10.sup.-2 ohm-cm at 295.degree. K. The salts are further characterized by a resistivity that decreases with decreasing temperature. A vapor phase process for preparing these organic metals is also disclosed. The process comprises the steps of:1. forming a first vapor comprising the chalcogenated tetracene compound;2. forming a second vapor comprising the electron acceptor compound; and3. reacting the first vapor with the second vapor at a temperature of about 75.degree. C to about 300.degree. C in a substantially inert atmosphere.

    摘要翻译： 公开了具有金属电学性质和含有这些盐的层的元素的有机离子基盐。 所述盐是硫属化并四苯供体化合物和电子受体化合物的盐，其中供体化合物与受体化合物的比例为约3:1至约1.5:1。 这些盐在295°K时具有小于约10-2欧姆 - 厘米的电阻率。盐的进一步特征在于随温度降低而降低的电阻率。 还公开了制备这些有机金属的气相方法。 该方法包括以下步骤：

    Electroconductive composition
    8.
    发明授权
    Electroconductive composition 失效
    导电组合物

    公开(公告)号：US5871670A

    公开(公告)日：1999-02-16

    申请号：US793716

    申请日：1997-03-03

    申请人： Bruno Hilti ,  Ernst Minder ,  Jurgen Pfeiffer

    发明人： Bruno Hilti ,  Ernst Minder ,  Jurgen Pfeiffer

    IPC分类号： C07D335/02 ,  C07D339/04 ,  C07D339/06 ,  C07D339/08 ,  C07D345/00 ,  C07D495/06 ,  C07D495/22 ,  C07D517/06 ,  C07D517/22 ,  C08K5/45 ,  C08L101/00 ,  H01B1/12 ,  H01B1/20 ,  C08K5/00

    CPC分类号： H01B1/121 ,  Y10S524/91 ,  Y10S524/911

    摘要： A composition comprising a matrix of a thermoplastic, thermosetting or a structurally crosslinked polymer, in which is incorporated an electroconductive network of crystal needles of a charge transfer complex (abbreviated to CT complex) from an electron donor and an electron acceptor, characterized in that:(1) the matrix contains uniformly distributed an excess, with respect to the CT complex formation, either of at least one electron donor or at least one electron acceptor as weakly polymer-soluble finely divided particles,(2) the CT complex is formed either by at least one weakly polymer-soluble electron donor and at least one polymer-soluble electron acceptor or by at least one weakly polymer-soluble electron acceptor and at least one polymer-soluble electron donor, and(3) microcrystalline needles grow from the weakly polymer-soluble particles in the polymer mass, which microcrystalline needles are in contact with and connect the weakly polymer-soluble particles to form a network which penetrates the polymer mass.

    摘要翻译： PCT No.PCT / EP95 / 03537。 371日期1997年3月3日 102（e）1997年3月3日PCT PCT 1995年9月8日PCT公布。 公开号WO96 / 09629 日期：1996年3月28日一种包含热塑性，热固性或结构交联聚合物基体的组合物，其中掺入电子转移络合物（缩写为CT络合物）的晶体针的电导网络和电子受体 其特征在于：（1）相对于CT络合物形成，基质含有均匀分布的过量的至少一种电子给体或至少一种电子受体作为弱聚合物可溶的细碎颗粒，（2） CT复合物由至少一种弱聚合物可溶电子给体和至少一种聚合物可溶电子受体或至少一种弱聚合物可溶电子受体和至少一种聚合物可溶电子给体形成，和（3）微晶 针从聚合物物质中的弱聚合物可溶性颗粒生长，微晶针与弱聚合物可溶性颗粒接触并连接 以形成穿透聚合物质量的网络。

    Heterocyclic pentalene derivatives for use in combating microorganisms
    10.
    发明授权
    Heterocyclic pentalene derivatives for use in combating microorganisms 失效
    用于对抗微生物的杂环柔性衍生物

    公开(公告)号：US4737507A

    公开(公告)日：1988-04-12

    申请号：US883663

    申请日：1986-07-09

    申请人： Susan J. Turner ,  Michael T. Clark

    发明人： Susan J. Turner ,  Michael T. Clark

    IPC分类号： A01N43/90 ,  A01N55/00 ,  A61K31/41 ,  A61P31/04 ,  C07D515/04 ,  C07D515/06 ,  C07D515/16 ,  C07D517/06 ,  C07D517/16 ,  A01N43/02 ,  C07D291/08

    CPC分类号： C07D515/04 ,  A01N43/90 ,  A01N55/00 ,  C07D515/06

    摘要： The invention provides a method of combating a microorganism which comprises allowing a heterocyclic pentalene derivative of general formula I ##STR1## wherein X represents an oxygen atom, a sulphur atom or an --SO-- moiety; Y represents a sulphur, selenium or tellurium atom, provided that when Y represents a selenium or tellurium atom X is an oxygen atom; and R.sup.1 and R.sup.2 together represent a --CH.sub.2 --C(CH.sub.3).sub.2 --CCl(CONH.sub.2)-- or --CH.sub.2 --A--CH.sub.2 -- linkage where A is a --CH.sub.2 --, --CH(CH.sub.3)-- or --S(O).sub.n -- moiety, where n is 0, 1 or 2; provided that when X is an oxygen atom and Y is a sulphur atom R.sup.1 and R.sup.2 together represent a --CH.sub.2 --S(O).sub.n --CH.sub.2 -- linkage and when X is an --SO-- moiety and A is a S(O).sub.n --, n is 2; to act on the microorganism or its environment; and such derivatives for use as a therapeutic substance.

    摘要翻译： 本发明提供了一种抗微生物的方法，其包括使其中X表示氧原子，硫原子或-SO-部分的通式I（I）的杂环柔性烯衍生物; Y表示硫，硒或碲原子，条件是当Y表示硒或碲原子时，X为氧原子; 并且R 1和R 2一起表示-CH 2 -C（CH 3）2 -CCl（CONH 2） - 或-CH 2 -A-CH 2 - 键，其中A是-CH 2 - ， - CH（CH 3） - 或-S（O） n部分，其中n为0,1或2; 条件是当X是氧原子并且Y是硫原子时，R 1和R 2一起表示-CH 2 -S（O）n -CH 2 - 键，并且当X是-SO-部分且A是S（O）n - ，n为2; 对微生物或其环境采取行动; 和用作治疗物质的这种衍生物。