Coated material and use thereof
    4.
    发明授权
    Coated material and use thereof 失效
    涂层材料及其用途

    公开(公告)号:US4898806A

    公开(公告)日:1990-02-06

    申请号:US302076

    申请日:1989-01-23

    申请人: Josef Pfeifer

    发明人: Josef Pfeifer

    IPC分类号: C08G73/00 C08G73/10 G03F7/038

    摘要: A coated photosensitive material on a support comprising a layer of polyamic acids and polyamic acid aryl esters derived from tetracarboxylic acids or aminodicarboxylic acids containing a benzophenone structural unit and aromatic diamines which are substituted in both ortho-positions by at least one amino group. The material is autophotocrosslinkable and is suitable for producing protective coatings and photographic images, with corresponding polyimides being formed after irradiation by a thermal aftertreatment.

    摘要翻译: 包含一种聚酰胺酸和衍生自四羧酸的聚酰胺酸芳基酯或含有二苯甲酮结构单元的氨基二羧酸和在两个邻位被至少一个氨基取代的芳族二胺的涂层感光材料。 该材料是自动双相交联的,适用于生产保护性涂层和摄影图像,在热处理后照射后形成相应的聚酰亚胺。

    Process for irradiating polyimides
    6.
    发明授权
    Process for irradiating polyimides 失效
    辐射聚酰亚胺的方法

    公开(公告)号:US4629685A

    公开(公告)日:1986-12-16

    申请号:US795591

    申请日:1985-11-06

    申请人: Josef Pfeifer

    发明人: Josef Pfeifer

    摘要: Homopolyimides and copolyimides which contain structural elements of the formula I ##STR1## in which R.sup.1 and R.sup.2 are halogen, nitro, aryl, aryloxy, alkyl or alkoxy, m is 0 or a number from 1 to 4, n is 0 or a number from 1 to 3 and p is 0, 1 or 2, the free carbonyl groups are bonded in the ortho-position relative to one another and R is a divalent aromatic radical which is substituted by at least one alkyl group or aralkyl group, are autophotocross-linkable. They are suitable for the production of protective films and photographic relief images.

    摘要翻译: 含有式I的结构元素的均聚酰亚胺和共聚酰亚胺其中R 1和R 2为卤素,硝基,芳基,芳氧基,烷基或烷氧基,m为0或数1至4,n为0或 1至3的数,p为0,1或2,游离羰基相对于彼此的邻位键合,R为被至少一个烷基或芳烷基取代的二价芳族基, 是自动双向交联的。 它们适用于生产保护膜和照片浮雕图像。

    1,10-Substituted 10-amino-deca-3,7-diene-nitriles and process for their
preparation
    7.
    发明授权
    1,10-Substituted 10-amino-deca-3,7-diene-nitriles and process for their preparation 失效
    1,10-取代的10-氨基 - 十烯-3,7-二烯 - 腈及其制备方法

    公开(公告)号:US4472318A

    公开(公告)日:1984-09-18

    申请号:US461045

    申请日:1983-01-26

    CPC分类号: C07C255/00 C08G69/26

    摘要: Novel 10-amino-deca-3,7-diene-nitriles of the formula ##STR1## are described, in which R.sub.1 is C.sub.1-12 -alkyl, R.sub.2 is H or C.sub.1-12 -alkyl, R.sub.3 is C.sub.1-12 -alkyl, cycloalkyl having 4-12 ring C atoms, C.sub.7-8 -aralkyl, substituted or unsubstituted aryl or, if R.sub.4 =H, --Ch.dbd.CH--alkyl or --C(alkyl).dbd.CH--alkyl each having 1-4 C atoms in the alkyl groups, and R.sub.4 =H, C.sub.1-12 -alkyl, cycloalkyl having 4-12 ring C atoms, C.sub.7-8 -aralkyl or substituted or unsubstituted aryl, or R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 together are C.sub.3-11 -alkylene. The compounds (I) can be reduced in a manner known per se to give the corresponding 1,11-diamino-undeca-3,7-dienes. The latter are valuable intermediates and are suitable especially for the preparation of transparent crosslinkable polyamides.

    摘要翻译: 描述了式(I)的新的10-氨基 - 癸-3,7-二烯 - 腈,其中R 1是C 1-12 - 烷基,R 2是H或C 1-12 - 烷基,R 3是C1- 具有4-12个环C原子的环烷基,C7-8-芳烷基,取代或未取代的芳基,或如果R4 = H,-Ch = CH-烷基或-C(烷基)= CH-烷基,各自具有1- 4个C原子,R4 = H,C1-12烷基,具有4-12个环C原子的环烷基,C7-8-芳烷基或取代或未取代的芳基,或R1和R2和/或R3和R4一起 是C3-11-亚烷基。 化合物(I)可以以本身已知的方式还原,得到相应的1,11-二氨基 - 十一碳-3,7-二烯。 后者是有价值的中间体,并且特别适于制备透明的可交联聚酰胺。

    Transparent polyamide from branched chain arylene diamine
    8.
    发明授权
    Transparent polyamide from branched chain arylene diamine 失效
    来自支链亚芳基二胺的透明聚酰胺

    公开(公告)号:US4433137A

    公开(公告)日:1984-02-21

    申请号:US387118

    申请日:1982-06-10

    申请人: Josef Pfeifer

    发明人: Josef Pfeifer

    CPC分类号: C08G69/26

    摘要: New transparent polyamides consisting of recurring structural elements of formula I ##STR1## wherein the carbonyl groups are linked to the benzene ring in 1,3- and/or 1,4-position are described. The novel polyamides are suitable for the manufacture of transparent shaped articles, and are distinguished by good thermoplastic processing characteristics, low water absorption, high stability to hydrolysis and good dimensional stability under the action of moisture.

    摘要翻译: 描述了由式I的重复结构元件(I)组成的新的透明聚酰胺,其中羰基与1,3-和/或1,4-位上的苯环连接。 新型聚酰胺适用于透明成型制品的制造,具有良好的热塑性加工特性,吸水率低,水解稳定性好,水分作用下尺寸稳定性好等特点。

    Transparent copolyamide from 1,10-disubstituted-1,10 diamine
    10.
    发明授权
    Transparent copolyamide from 1,10-disubstituted-1,10 diamine 失效
    透明的共聚酰胺由1,10-二取代的-1,10二胺组成

    公开(公告)号:US4255559A

    公开(公告)日:1981-03-10

    申请号:US083145

    申请日:1979-10-09

    申请人: Josef Pfeifer

    发明人: Josef Pfeifer

    IPC分类号: C08G69/00 C08G69/26 C08G69/28

    CPC分类号: C08G69/265

    摘要: There are described transparent copolyamides which are obtained by reaction of a mixture A) consisting of essentially stoichiometric amounts of a diamine of the formula ##STR1## and isophthalic acid, a mixture of isophthalic acid and terephthalic acid, or amide-forming derivatives thereof, in a molar ratio isophthatic acid(derivative) : terephthalic acid(derivative) of 5:5 to 10:0, with a mixture B) consisting of essentially stoichiometric amounts of a diamine of the formula ##STR2## and a dicarboxylic acid of the formulaHOOC--Z--COOH (III),or an amide-forming derivative thereof [R.sub.1 to R.sub.4 independently of each other are each H or C.sub.1-4 -alkyl, the proportion of mixture A) is 40-60 percent by weight, and R.sub.5 and R.sub.6 independently of one another are each cycloalkyl which has 5-12 ring C atoms and which is unsubstituted or is substituted by C.sub.1-4 -alkyl, or they are each isopropyl, sec-butyl or isobutyl; or the proportion of mixture A) is 50-70 percent by weight, R.sub.5 /R.sub.6 =--CH(R.sub.7) (R.sub.8), R.sub.7 is H or C.sub.2-8 -alkyl, R.sub.8 is C.sub.2-8 -alkyl, and Z is C.sub.4-14 alkylene]. The novel copolyamides are distinguished by good thermoplastic processing characteristics, low water absorption, and good stability to hydrolysis, and they are suitable for producing transparent moulded articles.

    摘要翻译: 描述了透明共聚酰胺,其通过由基本上化学计量的式(I)的二胺和间苯二甲酸,间苯二甲酸和对苯二甲酸的混合物或酰胺形成衍生物 其摩尔比为5:5至10:0的对苯二甲酸(衍生物):对苯二甲酸(衍生物)为5:5至10:0的混合物,B)由基本上化学计量的式(II)的二胺和 式(Ⅳ)的二羧酸或其酰胺形成性衍生物[R 1〜R 4各自独立地为H或C 1-4 - 烷基,混合物A)的比例为40〜60重量% R 5和R 6彼此独立地为环烷基,其具有5-12个环C原子且未被取代或被C 1-4 - 烷基取代,或者它们各自为异丙基,仲丁基或异丁基; 或混合物A)的比例为50-70重量%,R5 / R6 = -CH(R7)(R8),R7为H或C2-8烷基,R8为C2-8-烷基,Z为C4 -14亚烷基]。 新型共聚酰胺的特点是热塑性加工性能好,吸水率低,水解稳定性好,适用于生产透明模塑制品。