摘要:
The present invention relates to a novel process for the preparation of a sterically hindered nitroxyl ether from the corresponding sterically hindered nitroxyl radical by reacting it with a carbonyl compound and a hydroperoxide. The compounds prepared by this process are effective stabilizers for polymers against harmful effects of light, oxygen and/or heat, as flame-retardants for polymers and as polymerization regulators.
摘要:
A power-branched transmission for an agricultural vehicle is configured as a power-branched transmission having a secondary coupling. The transmission comprises a summation planetary gear set (5), the planetary gear of which are configured as a double planetary gear (8).
摘要:
The present invention pertains to a reversible thermochromic system comprising a β-phenylvinylketone or a ω-phenyl polyacetylenyl ketone with at least one acidic hydrogen and a base and to a reversible thermochromic composition comprising the reversible thermochromic system and a carrier material and to novel substituted β-phenylvinylketones or ω-phenyl polyacetylenyl ketones with at least one acidic hydrogen.
摘要:
A continuously variable transmission device comprising a variator and a secondary power splitting. For power splitting, a planetary gear set has a first shaft coupled to the transmission input, a second shaft of the gear set coupled a first shaft of the variator, and a third shaft of the gear set couples a second shaft of the variator. First and second shift elements are provided to switch between first and second gear ratio ranges. Via the variator, the gear ratio is continuously variable within the gear ratio range and the two gear ratio ranges overlap. To implement the first gear ratio range, the second shaft of the gear set is connected, via the first shift element, to the transmission output, and to implement the second gear ratio range, the third shaft of the planetary gear set is connected, via the second shift element, to the transmission output.
摘要:
The present invention pertains to a reversibly thermochromic system comprising a substituted or an unsubstituted 6,11-dihydroxy-naphthacene-5,12-dione and a base and to a reversibly thermochromic composition comprising the reversibly thermochromic system and a carrier material and to novel substituted 6,11-dihydroxy-naphthacene-5,12-diones.
摘要:
A process for the preparation of bis-acylphosphanes of formula R1P(COR )2 wherein R1 is unsubstituted phenyl or phenyl substituted by one to five halogen, C1-C8-alkyl, C1-C8-alkylthio and/or C1-C8-alkoxy; R2 is C1-C18-alkyl or C2-C18-alkenyl; C1-C18-alkyl or C2-C18-alkenyl substituted once or more than once by halogen —OR10, —OCO—R10, —OCO-Hal, —COO—R10, —N(R11)—CO—R10, —N(R11)—CO-Hal, —CO—NR11R10, —CH═CH—CO—OR10 or —CH═CH-phenyl; —C(C1-C4alkyl)=C(C1-C4alkyl)-CO—OR10 or —C(C1-C4alkyl)=(C1-C4alkyl)-phenyl; C5-C12cycloalkyl, C2-C18alkenyl, phenyl-C1-C4alkenyl, phenyl, naphthyl, biphenyl or a 5- or 6-membered -0-, S— or N-containing heterocyclic ring, the radicals phenyl, naphthyl, biphenyl or the 5- or 6-membered -0-, S— or N-containing heterocyclic ring being unsubstituted or substituted by one to five halogen, C1-C8alkyl, C1-C8alkoxy and/or C1-C8alkylthio; the process comprises the steps in a) selective reduction of dichlorophenylphosphanes of the formula R1P(Cl)2 by means of hydrogen at a temperature in the range from 20 to 200° C. and under hydrogen pressure of atmospheric pressure to 20 bar in the presence of a hydrogenation catalyst, a tert. aliphatic amine or an aromatic amine and in the presence of a non protic solvent which is unreactive under the hydrogenation conditions to obtain cyclic phenylphosphanes (R1P)n (n=4 to 6); or b) selective reduction of R1P(Cl)2 by means of hydrogen at a temperature in the range from 80 to 250° C. and under hydrogen pressure of 25 to 250 bar in the presence of a hydrogenation catalyst, a tert. aliphatic amine or an aromatic amine and in the presence of a non protic solvent which is unreactive under the hydrogenation conditions to obtain R1PH2; c) subsequent reaction with an acid halide of formula in the presence of an apropriate base R2COHal wherein R2 is as defined above.
摘要:
A process for the preparation of compounds of formula I wherein the general symbols are as defined in claim 1, which comprises reacting a compound of formula V wherein R1, R2, R3, R4, R5, R6, R7, R8, R9 and R18 are as defined in claim 1, and R18 is especially nitro, chlorine or bromine, with an azide compound of formula IX, wherein M and n are as defined in claim 1, especially with sodium azide.
摘要翻译:制备式I化合物的方法,其中通式如权利要求1所定义,其包括使式Ⅴ化合物其中R 1,R 2, R 3,R 4,R 5,R 6,R 7, R 8,R 9和R 18如权利要求1中所定义,并且R 18特别是硝基, 氯或溴,与式IX的叠氮化合物反应,其中M和n如权利要求1中所定义,特别是与叠氮化钠。
摘要:
The present invention encompasses protective monoclonal antibodies that bind to peptidoglycan of Gram-positive bacteria. The antibodies also bind to whole bacteria and enhance phagocytosis and killing of the bacteria in vitro and block nasal colonization by Gram-positive bacteria in vivo. The invention also provides human, humanized and chimeric antibodies. The invention also sets forth the heavy chain and light chain variable regions of an antibody within the invention.
摘要:
A method and a briquetting press for briquetting metal chips, wherein stable briquettes/pressed component are produced. The actual length (Lact) of the pressed component is obtained by applying pressure (Pmax/Preq) using at least one pressing ram (1, 2) and measuring the length with a measuring device (5, 6). The measured value is compared to a desired nominal value (Lnom) and a difference value (□) is subsequently determined.
摘要翻译:一种用于压块金属屑的压块机,其中产生稳定的压块/压块。 按压部件的实际长度(L<动作< / SUB>)通过使用至少一个按压压头施加压力(P>最大/ P SUB> (1,2),并用测量装置(5,6)测量长度。 将测量值与期望的标称值(L> nom)进行比较,随后确定差值(□)。
摘要:
An assay method incorporating at least two different chemiluminescent compounds for detection and/or quantitation of at least two substances in a test sample is described. The synthesis of chemiluminescent reagents or conjugates for use in such methods as well as kits incorporating such reagents are also disclosed. The assays have particular application in the field of clinical diagnostics.