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31 条记录 (耗时 0.011 秒)

    Vinylidene chloride copolymer
    1.
    发明授权
    Vinylidene chloride copolymer 失效
    VINYLIDENE氯化物共聚物

    公开(公告)号：US3850726A

    公开(公告)日：1974-11-26

    申请号：US27041772

    申请日：1972-07-10

    申请人： STALEY MFG CO A E

    发明人： SMITH D ,  PETERSON H

    IPC分类号： C08F214/08 ,  C08F259/06 ,  C08J7/04 ,  C09D127/08 ,  C09J7/02 ,  B44D1/02

    CPC分类号： C08J7/047 ,  C08F214/08 ,  C08F259/06 ,  C08J2323/02 ,  C08J2427/00 ,  C09D127/08 ,  Y10T428/3192

    摘要： A polyvinylidene chloride latex composition suitable for coating substrates comprising a copolymer of (A) 70 to 95 percent by weight vinylidene chloride, (B) 0.5 to 30 percent by weight hydroxyalkyl ester of an alpha, betaethylenically unsaturated carboxylic acid, (C) 0 to 3 percent by weight ethylenically unsaturated sulfur acid having sulfur in valence state 6, (D) 0 to 5 percent by weight ethylenically unsaturated carboxylic acid and (E) 0 to 29.5 percent by weight ethylenically unsaturated monomer other than (A), (B), (C) or (D).

    摘要翻译： 适用于涂覆基材的聚偏二氯乙烯胶乳组合物，其包含（A）70-95重量％偏二氯乙烯的共聚物，（B）0.5至30重量％的α，β-烯键式不饱和羧酸的羟烷基酯，（C）0至 3重量％的具有硫化价的烯键式不饱和硫酸6，（D）0-5重量％烯属不饱和羧酸和（E）0-29.5重量％的除（A），（B）之外的烯属不饱和单体， ，（C）或（D）。

    Graft copolymers, methods for grafting hydrophilic chains onto hydrophobic polymers, and articles thereof
    4.
    发明申请
    Graft copolymers, methods for grafting hydrophilic chains onto hydrophobic polymers, and articles thereof 审中-公开
    接枝共聚物，将亲水链接枝到疏水性聚合物上的方法及其制品

    公开(公告)号：US20020147282A1

    公开(公告)日：2002-10-10

    申请号：US09951125

    申请日：2001-09-12

    发明人： Anne M. Mayes ,  Jonathan F. Hester ,  Pallab Banerjee ,  Ariya Akthakul

    IPC分类号： C08F259/00 ,  C08F259/04 ,  C08F259/06

    CPC分类号： B01D67/0018 ,  B01D69/02 ,  B01D69/141 ,  B01D71/30 ,  B01D71/34 ,  B01D71/40 ,  B01D71/52 ,  B01D71/78 ,  B01D2323/02 ,  B01D2325/28 ,  B01D2325/32 ,  C08G81/00 ,  C08G81/021

    摘要： The present invention relates to synthetic methods for grafting hydrophilic chains onto polymers, particularly hydrophobic polymers such as poly(vinyl chloride) (PVC), poly(vinylidene fluoride) (PVDF), and chlorinated polypropylene (cPP). Resulting polymers include comb polymers which can have a microphase-separated structure of hydrophilic domains provided by the hydrophilic chains. Articles prepared from these comb polymers, particularly derived from PVDF, include membranes for water filtration in which the hydrophilic domains provide a pathway for water transport. PVC can be plasticized by grafting the PVC with hydrophilic chains. In addition, such articles, particularly articles having biomedical applications, can display anti-thrombogenic properties.

    摘要翻译： 本发明涉及将亲水链接枝到聚合物，特别是疏水性聚合物如聚（氯乙烯）（PVC），聚（偏二氟乙烯）（PVDF）和氯化聚丙烯（cPP））上的合成方法。 得到的聚合物包括梳状聚合物，其可以具有由亲水链提供的亲水结构域的微相分离结构。 由这些梳形聚合物制备的，特别是衍生自PVDF的制品包括用于水过滤的膜，其中亲水域提供水输送途径。 PVC可以通过亲水链接PVC来增塑。 此外，这些制品，特别是具有生物医学应用的制品，可以显示抗血栓形成性质。

    Vinylidene chloride polymer microgel powders and acrylic fibers containing same
    5.
    发明授权
    Vinylidene chloride polymer microgel powders and acrylic fibers containing same 失效
    偏二氯乙烯聚合物微凝胶粉末和含有相同的丙烯酸纤维

    公开(公告)号：US4164522A

    公开(公告)日：1979-08-14

    申请号：US942257

    申请日：1978-09-15

    申请人： Dale S. Gibbs

    发明人： Dale S. Gibbs

    IPC分类号： C08F259/06 ,  C08L51/00 ,  D01F6/54 ,  C08L33/20

    CPC分类号： D01F6/54 ,  C08F259/06 ,  C08L51/003 ,  Y10S260/24

    摘要： Crosslinked vinylidene chloride polymer microgel powders are recovered from a latex obtained by emulsion polymerizing in sequence (a) a first monomer mixture comprising a predominant amount of vinylidene chloride, an ethylenically unsaturated comonomer, and a crosslinking polyfunctional monomer; (b) a minor amount of a polyfunctional monomer for providing graft sites on the product of (a); and (c) a second monomer mixture which is predominantly acrylonitrile, the amount of the second monomer mixture being in the range of about 10 to 25 percent of the weight of the first monomer mixture. The so-formed microgels, having a particle size less than about 1 micron, are admixed with an acrylic polymer and a suitable solvent and then spun into fibers having improved flame-retardancy.

    摘要翻译： 从通过乳液聚合获得的胶乳中回收交联的偏二氯乙烯聚合物微凝胶粉末（a）包含主要量的偏二氯乙烯，烯属不饱和共聚单体和交联多官能单体的第一单体混合物; （b）少量多官能单体，用于在（a）的产物上提供移植部位; 和（c）主要是丙烯腈的第二单体混合物，第二单体混合物的量在第一单体混合物重量的约10至25％的范围内。 将具有小于约1微米粒度的如此形成的微凝胶与丙烯酸聚合物和合适的溶剂混合，然后纺丝成具有改善的阻燃性的纤维。

    Supported vinyl chloride emulsion (co) polymers and process for making the same
    9.
    发明授权
    Supported vinyl chloride emulsion (co) polymers and process for making the same 失效
    支持氯乙烯乳液（共）聚合物及其制备方法

    公开(公告)号：US6020438A

    公开(公告)日：2000-02-01

    申请号：US094243

    申请日：1998-06-09

    申请人： Alexander V. Lubnin ,  John E. Fitzwater ,  Vic Stanislawczyk ,  Michael W. Topp

    发明人： Alexander V. Lubnin ,  John E. Fitzwater ,  Vic Stanislawczyk ,  Michael W. Topp

    IPC分类号： C08F257/00 ,  C08F259/04 ,  C08F14/00 ,  C08F14/16 ,  C08F114/16 ,  C08F259/06

    CPC分类号： C08F257/00 ,  Y10S525/902

    摘要： An emulsion polymer comprising as one of its components a graft copolymer of a residual aromatic monomer-free support resin polymer and a vinyl chloride (co)polymer is disclosed. The emulsion polymer is prepared using a two-stage process. In the first stage, a chasing monomer is reacted in the presence of a support resin polymer having at least one aromatic monomer to form an polymer which is free of residual monomer and has monomeric units derived from the aromatic monomer(s). In a second stage, the vinyl chloride emulsion (co)polymer is made in situ in a reaction mixture comprising the polymer which is free of residual monomer. An extensive grafting at the second stage yields a novel water dispersible graft copolymer containing both styrene and vinyl chloride.

    摘要翻译： 公开了一种乳液聚合物，其包含作为其组分之一的残留的不含芳族单体的载体树脂聚合物和氯乙烯（共）聚合物的接枝共聚物。 使用两步法制备乳液聚合物。 在第一阶段中，在具有至少一种芳族单体的载体树脂聚合物的存在下，使追逐单体反应，形成不含残余单体且具有源自芳族单体的单体单元的聚合物。 在第二阶段中，氯乙烯乳液（共）聚合物在包含不含残余单体的聚合物的反应混合物中原位制备。 在第二阶段的广泛接枝得到含有苯乙烯和氯乙烯的新型水分散性接枝共聚物。

    Latexes of encapsulated vinylidene chloride copolymer particles
    10.
    发明授权
    Latexes of encapsulated vinylidene chloride copolymer particles 失效
    封装的偏二氯乙烯共聚物颗粒的胶乳

    公开(公告)号：US4156669A

    公开(公告)日：1979-05-29

    申请号：US899209

    申请日：1978-04-24

    申请人： Do I. Lee

    发明人： Do I. Lee

    IPC分类号： C08F259/06 ,  C08F279/02 ,  C08L9/08 ,  C08L9/10 ,  C08L13/02 ,  C08L15/02

    CPC分类号： C08F259/06 ,  C08F279/02 ,  Y10T428/2998

    摘要： Improved aqueous vinylidene chloride copolymer latexes are provided in which the dispersed polymer particles are heterogeneous and comprise from about 35 to about 75 weight percent of polymerized vinylidene chloride. The heterogeneous polymer particles of such latexes contain a major amount of a soft copolymer core comprising vinylidene chloride and an aliphatic conjugated diene. Such particles also contain a minor amount of a polymeric shell which encompasses the core portion and which consists essentially of (a) a monomer selected from the group consisting of aliphatic conjugated dienes, monovinylidene aromatic monomers and saturated aliphatic esters of monoethylenically unsaturated carboxylic acids; (b) optionally, up to about 30 weight percent (based upon the shell) of vinylidene chloride; and (c) optionally, up to about 10 weight percent based upon such shell of a monoethylenically unsaturated carboxylic acid.

    摘要翻译： {PG，1提供改进的偏二氯乙烯共聚物胶乳，其中分散的聚合物颗粒是不均匀的，并且包含约35至约75重量％的聚偏二氯乙烯。 这种胶乳的非均相聚合物颗粒含有大量的包含偏二氯乙烯和脂族共轭二烯的软共聚物芯。 这种颗粒还含有少量聚合物壳，其包含核心部分，其基本上由（a）选自脂族共轭二烯，单亚乙烯基芳族单体和单烯属不饱和羧酸的饱和脂肪族酯的单体组成; （b）任选地，至多约30重量％（基于壳）的偏二氯乙烯; 和（c）任选地，基于所述壳的单烯属不饱和羧酸至多约10重量％。