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1.发明授权Supported vinyl chloride emulsion (co) polymers and process for making the same 失效支持氯乙烯乳液（共）聚合物及其制备方法
公开(公告)号：US6020438A
公开(公告)日：2000-02-01
申请号：US094243
申请日：1998-06-09
IPC分类号： C08F257/00 , C08F259/04 , C08F14/00 , C08F14/16 , C08F114/16 , C08F259/06
CPC分类号： C08F257/00 , Y10S525/902
摘要： An emulsion polymer comprising as one of its components a graft copolymer of a residual aromatic monomer-free support resin polymer and a vinyl chloride (co)polymer is disclosed. The emulsion polymer is prepared using a two-stage process. In the first stage, a chasing monomer is reacted in the presence of a support resin polymer having at least one aromatic monomer to form an polymer which is free of residual monomer and has monomeric units derived from the aromatic monomer(s). In a second stage, the vinyl chloride emulsion (co)polymer is made in situ in a reaction mixture comprising the polymer which is free of residual monomer. An extensive grafting at the second stage yields a novel water dispersible graft copolymer containing both styrene and vinyl chloride.
摘要翻译： 公开了一种乳液聚合物，其包含作为其组分之一的残留的不含芳族单体的载体树脂聚合物和氯乙烯（共）聚合物的接枝共聚物。 使用两步法制备乳液聚合物。 在第一阶段中，在具有至少一种芳族单体的载体树脂聚合物的存在下，使追逐单体反应，形成不含残余单体且具有源自芳族单体的单体单元的聚合物。 在第二阶段中，氯乙烯乳液（共）聚合物在包含不含残余单体的聚合物的反应混合物中原位制备。 在第二阶段的广泛接枝得到含有苯乙烯和氯乙烯的新型水分散性接枝共聚物。
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公开(公告)号：US07582698B2
公开(公告)日：2009-09-01
申请号：US10733027
申请日：2003-12-11
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , C08G18/28 , C08G18/48 , C08G18/08 , C08G18/81 , B32B27/00 , B32B27/40
CPC分类号： C08G18/758 , C08G18/0823 , C08G18/10 , C08G18/12 , C08G18/4009 , C08G18/4238 , C08G18/4825 , C08G18/6692 , C08G18/755 , Y10S524/908 , Y10S525/902 , Y10S525/903 , Y10T428/31551 , C08G18/3231
摘要： A novel method of preparing an aqueous dispersion of non-uniform polyurethane particles which comprises (a) preparing at least two isocyanate-terminated polyurethane prepolymers having different hydrophilicities; (b) preparing a uniform mixture of said prepolymers; and (c) dispersing the mixed prepolymers in an aqueous medium. The resulting dispersion of the prepolymers may optionally be chain extended. This method enables the preparation of core-shell particles as well as particles of other morphologies, including “raspberry”, interpenetrating network, “salt-and-pepper”, “ice-cream cone” and particles of gradient composition. Similarly, an aqueous dispersion of two different polyurethane polymers may be obtained by first preparing at least two different isocyanate-terminated polyurethane prepolymers, preparing a uniform mixture of such prepolymers and thereafter dispersing the mixture in an aqueous medium.
摘要翻译： 一种制备非均匀聚氨酯颗粒的水性分散体的新方法，其包括（a）制备具有不同亲水性的至少两种异氰酸酯封端的聚氨酯预聚物; （b）制备所述预聚物的均匀混合物; 和（c）将混合的预聚物分散在水性介质中。 所得到的预聚物分散体可任选地进一步延伸。 这种方法能够制备核 - 壳颗粒以及其他形态的颗粒，包括“覆盆子”，互穿网络，“盐和胡椒”，“冰淇淋锥”和梯度组成的颗粒。 类似地，可以通过首先制备至少两种不同的异氰酸酯封端的聚氨酯预聚物，制备这种预聚物的均匀混合物，然后将该混合物分散在水性介质中来获得两种不同聚氨酯聚合物的水分散体。
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3.发明授权Multiple phase polymeric vinyl chloride systems and related core-shell particles 失效多相聚合氯乙烯体系和相关的核 - 壳颗粒公开(公告)号：US06316107B1
公开(公告)日：2001-11-13
申请号：US09287918
申请日：1999-04-07
IPC分类号： B32B516
CPC分类号： C08F259/04 , Y10T428/2998
摘要： An emulsion or suspension polymer comprising a vinyl chloride polymeric core and an acrylic ester-acrylonitrile polymeric shell is disclosed. The emulsion polymer is preferably prepared using a two-stage process. In the first stage, a vinyl chloride monomer is polymerized or copolymerized to form a first phase of a polymeric hard core having a relatively high chlorine content. In a second stage, the soft acrylic ester—acrylonitrile copolymer is made in situ in a reaction mixture comprising the first phase. The product provides both flame retardancy and low MFFT, and is useful in a variety of coating and binding applications.
摘要翻译： 公开了一种包含氯乙烯聚合物芯和丙烯酸酯 - 丙烯腈聚合物壳的乳液或悬浮聚合物。 乳液聚合物优选使用两阶段方法制备。 在第一阶段中，将氯乙烯单体聚合或共聚以形成具有较高氯含量的聚合物硬核的第一相。 在第二阶段中，软质丙烯酸酯 - 丙烯腈共聚物在包含第一相的反应混合物中原位制备。 该产品提供阻燃性和低MFFT，并且可用于各种涂层和结合应用。
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公开(公告)号：US08242205B2
公开(公告)日：2012-08-14
申请号：US12546025
申请日：2009-08-24
CPC分类号： C08G18/758 , C08G18/0823 , C08G18/10 , C08G18/12 , C08G18/4009 , C08G18/4238 , C08G18/4825 , C08G18/6692 , C08G18/755 , Y10S524/908 , Y10S525/902 , Y10S525/903 , Y10T428/31551 , C08G18/3231
摘要： A novel method of preparing an aqueous dispersion of non-uniform polyurethane particles which comprises (a) preparing at least two isocyanate-terminated polyurethane prepolymers having different hydrophilicities; (b) preparing a uniform mixture of said prepolymers, and (c) dispersing the mixed prepolymers in an aqueous medium. The resulting dispersion of the prepolymers may optionally be chain extended. This method enables the preparation of core-shell particles as well as particles of other morphologies, including “raspberry”, interpenetrating network, “salt-and-pepper”, “ice-cream cone” and particles of gradient composition. Similarly, an aqueous dispersion of two different polyurethane polymers may be obtained by first preparing at least two different isocyanate-terminated polyurethane prepolymers, preparing a uniform mixture of such prepolymers and thereafter dispersing the mixture in an aqueous medium.
摘要翻译： 一种制备非均匀聚氨酯颗粒的水性分散体的新方法，其包括（a）制备具有不同亲水性的至少两种异氰酸酯封端的聚氨酯预聚物; （b）制备所述预聚物的均匀混合物，和（c）将混合的预聚物分散在水性介质中。 所得到的预聚物分散体可任选地进一步延伸。 这种方法能够制备核 - 壳颗粒以及其他形态的颗粒，包括“覆盆子”，互穿网络，“盐和胡椒”，“冰淇淋锥”和梯度组成颗粒。 类似地，可以通过首先制备至少两种不同的异氰酸酯封端的聚氨酯预聚物，制备这种预聚物的均匀混合物，然后将该混合物分散在水性介质中来获得两种不同聚氨酯聚合物的水分散体。
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公开(公告)号：US20100048765A1
公开(公告)日：2010-02-25
申请号：US12546025
申请日：2009-08-24
IPC分类号： C08L75/04
CPC分类号： C08G18/758 , C08G18/0823 , C08G18/10 , C08G18/12 , C08G18/4009 , C08G18/4238 , C08G18/4825 , C08G18/6692 , C08G18/755 , Y10S524/908 , Y10S525/902 , Y10S525/903 , Y10T428/31551 , C08G18/3231
摘要： A novel method of preparing an aqueous dispersion of non-uniform polyurethane particles which comprises (a) preparing at least two isocyanate-terminated polyurethane prepolymers having different hydrophilicities; (b) preparing a uniform mixture of said prepolymers, and (c) dispersing the mixed prepolymers in an aqueous medium. The resulting dispersion of the prepolymers may optionally be chain extended. This method enables the preparation of core-shell particles as well as particles of other morphologies, including “raspberry”, interpenetrating network, “salt-and-pepper”, “ice-cream cone” and particles of gradient composition. Similarly, an aqueous dispersion of two different polyurethane polymers may be obtained by first preparing at least two different isocyanate-terminated polyurethane prepolymers, preparing a uniform mixture of such prepolymers and thereafter dispersing the mixture in an aqueous medium.
摘要翻译： 一种制备非均匀聚氨酯颗粒的水性分散体的新方法，其包括（a）制备具有不同亲水性的至少两种异氰酸酯封端的聚氨酯预聚物; （b）制备所述预聚物的均匀混合物，和（c）将混合的预聚物分散在水性介质中。 所得到的预聚物分散体可任选地进一步延伸。 这种方法能够制备核 - 壳颗粒以及其他形态的颗粒，包括“覆盆子”，互穿网络，“盐和胡椒”，“冰淇淋锥”和梯度组成颗粒。 类似地，可以通过首先制备至少两种不同的异氰酸酯封端的聚氨酯预聚物，制备这种预聚物的均匀混合物，然后将该混合物分散在水性介质中来获得两种不同聚氨酯聚合物的水分散体。
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公开(公告)号：US09527328B2
公开(公告)日：2016-12-27
申请号：US13881919
申请日：2011-10-28
申请人： Alexander V. Lubnin , Dennis Malaba
发明人： Alexander V. Lubnin , Dennis Malaba
IPC分类号： B41M5/00 , B41M5/52 , C08F283/00 , C08G18/08 , C08G18/12 , C08G18/28 , C08G18/32 , C08G18/36 , C08G18/40 , C08G18/42 , C08G18/48 , C08G18/66 , C08G18/72 , C08G18/75 , C09D175/04 , C09D175/08 , C08L75/00 , C08J3/00 , C08K3/20
CPC分类号： B41M5/52 , B41M5/508 , B41M5/5245 , B41M5/5281 , C08F283/006 , C08G18/0814 , C08G18/12 , C08G18/2875 , C08G18/3275 , C08G18/36 , C08G18/4018 , C08G18/4238 , C08G18/4808 , C08G18/4825 , C08G18/4833 , C08G18/4854 , C08G18/6688 , C08G18/6696 , C08G18/722 , C08G18/755 , C08G18/758 , C08G2270/00 , C08J3/00 , C08K3/20 , C08L75/00 , C09D175/04 , C09D175/08 , D21H11/00 , D21H13/00 , C08G18/302
摘要： An aqueous cationic polyurethane dispersion for waterborne digital print and other applications comprising an aqueous dispersion of polyurethane having properly positioned tertiary amino groups, e.g., tethered tertiary amino group separated from backbone by at least two intervening atoms or terminal tertiary amino groups with multiple tertiary amino groups per terminus, where said amino groups are optionally partially quaternized and/or neutralized.
摘要翻译： 一种用于水性数字印刷和其它应用的水性阳离子聚氨酯分散体，其包含具有适当定位的叔氨基的聚氨酯的水性分散体，例如通过至少两个插入原子或具有多个叔氨基的末端叔氨基与主链分离的连接的叔氨基 其中所述氨基任选地被部分季铵化和/或中和。
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公开(公告)号：US07598315B2
公开(公告)日：2009-10-06
申请号：US11813686
申请日：2006-01-24
申请人： Alexander V. Lubnin
发明人： Alexander V. Lubnin
CPC分类号： C08G18/6692 , C08G18/0823 , C08G18/12 , C08G18/4854 , C08G18/6659 , C09D175/06 , Y10S977/773 , C08G18/3231
摘要： An aqueous dispersion of nanoparticle/polyurethane composites is made by forming a mixture of nanoparticles and a continuous mass of a polyurethane prepolymer in the substantial absence of water and dispersing the mixture so made in aqueous medium. Alternatively, a polyurethane prepolymer or a mixture of nanoparticles and a continuous mass of a polyurethane prepolymer is dispersed into an aqueous dispersion of nanoparticles.
摘要翻译： 纳米颗粒/聚氨酯复合材料的水分散体通过在基本上不存在水的情况下通过形成纳米颗粒和连续质量的聚氨酯预聚物的混合物来制备，并将如此制备的混合物在水性介质中分散。 或者，将聚氨酯预聚物或纳米颗粒和连续质量的聚氨酯预聚物的混合物分散到纳米颗粒的水性分散体中。
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公开(公告)号：US20080153975A1
公开(公告)日：2008-06-26
申请号：US11816217
申请日：2006-03-16
申请人： Alexander V. Lubnin
发明人： Alexander V. Lubnin
IPC分类号： C08L23/06
CPC分类号： C08J3/212 , C08F2/18 , C08F2/44 , C08J3/205 , C08J3/2053
摘要： Vinyl polymers formed by bulk or solution polymerization techniques are combined with nanoparticles to produce aqueous dispersions of nanoparticle/vinyl polymer composites.
摘要翻译： 通过本体或溶液聚合技术形成的乙烯基聚合物与纳米颗粒组合以产生纳米颗粒/乙烯基聚合物复合材料的水分散体。
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9.发明授权公开(公告)号：US06576702B2
公开(公告)日：2003-06-10
申请号：US09908045
申请日：2001-07-18
申请人： Gary A. Anderle , Susan L. Lenhard , Alexander V. Lubnin , George E. Snow , Krishnan Tamareselvy
发明人： Gary A. Anderle , Susan L. Lenhard , Alexander V. Lubnin , George E. Snow , Krishnan Tamareselvy
IPC分类号： C08J300
CPC分类号： A61Q5/06 , A61K8/87 , A61Q17/04 , A61Q19/00 , C08G18/0823 , C08G18/0866 , C08G18/10 , C08G18/12 , C08G18/4202 , C08G18/6659 , C08G18/6692 , C08G18/68 , C08G18/722 , C08G18/724 , C08G18/73 , C08K5/11 , C08K5/521 , C08G18/3225 , C08G18/3271 , C08G18/3231 , C08L75/04
摘要： Waterborne polyurethane dispersions are prepared by reacting (1) at least one polyisocyanate; (2) at least one active hydrogen containing compound, such as a polyol or a polyamide; and (3) preferably also at least one water-dispersability enhancing compound having water-dispersion enhancing groups, in order to form an isocyanate terminated prepolymer. The prepolymer subsequently is (1) optionally neutralized by reaction with at least one neutralizing agent, (2) dispersed in water, and then (3) chain extended by reaction with at least one of water, inorganic or organic polyamine having an average of about 2 or more primary and/or secondary amine groups, or combinations thereof. At least one plasticizer is introduced into the reaction mixture at any time during prepolymer formation or before the prepolymer is dispersed in water. The plasitcizer substantially or completely replaces other organic diluents or solvents. Various types of plasticizers may be employed, including reactive plasticizers.
摘要翻译： 水性聚氨酯分散体是通过使（1）至少一种多异氰酸酯与 （2）至少一种含活性氢的化合物，例如多元醇或聚酰胺; 和（3）优选还有至少一种具有水分散增强基团的水分散性增强化合物，以形成异氰酸酯封端的预聚物。 随后将预聚物（1）任选地通过与至少一种中和剂反应中和，（2）分散在水中，然后（3）通过与至少一种水，无机或有机多胺的平均约为 2个或更多个伯和/或仲胺基团，或其组合。 在预聚物形成期间或预聚物分散在水中之前的任何时间，至少一种增塑剂被引入反应混合物中。 该改性剂基本上或完全替代其它有机稀释剂或溶剂。 可以使用各种类型的增塑剂，包括反应性增塑剂。
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10.发明授权Aldehyde-telechelic polyisobutylenes, catalytic method for preparing the same with high conversion and selectivity, and block copolymers made thereform 失效醛 - 遥爪聚异丁烯，具有高转化率和选择性的催化方法，以及由其制备的嵌段共聚物
公开(公告)号：US5340881A
公开(公告)日：1994-08-23
申请号：US976532
申请日：1992-11-16
CPC分类号： C08F8/00 , C08F110/10 , C08F8/26 , C08F2810/30 , C08F2810/40
摘要： Aldehyde-telechelic polyisobutylenes free of other end groups such as alcohols, olefins, etc., are made by the hydroformylation of polyisobutylene having one or more olefinic end groups in the presence of a rhodium catalyst in combination with an organic phosphorus ligand. Very high conversions of olefin to aldehyde are obtained. Depending upon the number of aldehyde end groups per macromolecule, the telechelic polyisobutylene polymers can be utilized as precursors to form various types of block copolymers, e.g., AB, ABA, or radial block copolymers, with other polymers such as polyurethanes, polyesters, polyamines, and the like.
摘要翻译： 通过在铑催化剂与有机磷配体的组合的存在下，具有一个或多个烯属端基的聚异丁烯的加氢甲酰基化来制备不含其它端基的醇 - 遥爪聚异丁烯，例如醇，烯烃等。 获得非常高的烯烃与醛的转化率。 根据每个大分子的醛端基的数目，遥爪聚异丁烯聚合物可以用作前体以形成各种类型的嵌段共聚物，例如AB，ABA或径向嵌段共聚物，与其它聚合物如聚氨酯，聚酯，聚胺， 等等。
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