Flame retardant polycarbonate/graft copolymer blends exhibiting heat aging stability
    1.
    发明授权
    Flame retardant polycarbonate/graft copolymer blends exhibiting heat aging stability 失效
    具有热老化稳定性的阻燃聚碳酸酯/接枝共聚物共混物

    公开(公告)号:US06740696B1

    公开(公告)日:2004-05-25

    申请号:US08841027

    申请日:1997-04-29

    IPC分类号: C08K5521

    摘要: A flame retardant composition is provided containing (a) an aromatic polycarbonate resin, (b) a rubber modified graft copolymer, (c) a vinyl aromatic-unsaturated nitrile rigid copolymer, (d) a phosphate and (e) a tetrafluoroethylene polymer. The compositions contain elevated rubber loadings and/or utilize low molecular weight polycarbonate and/or low molecular weight vinyl aromatic-vinyl cyanide rigid copolymer. The composition exhibits enhanced retention of izod impact properties upon exposure to heat and humidity. The compositions are useful for making pellets which are stored and/or shipped in hot humid conditions, and which are then utilized for making molded business machine housings.

    摘要翻译: 提供了一种阻燃剂组合物,其包含(a)芳族聚碳酸酯树脂,(b)橡胶改性的接枝共聚物,(c)乙烯基芳族不饱和腈刚性共聚物,(d)磷酸酯和(e)四氟乙烯聚合物。 组合物含有较高的橡胶负载量和/或利用低分子量聚碳酸酯和/或低分子量乙烯基芳族乙烯基氰化物刚性共聚物。 该组合物在暴露于热和湿度下表现出增强的izod冲击性能的保留性。 所述组合物可用于制备在热潮湿条件下储存和/或运输的颗粒,然后将其用于制造模制商业机器壳体。

    Flameproof styrene containing graft resin compositions substantially free of phenolic resins and containing styrene/acrylonitrile resin compatabilizer
    3.
    发明授权
    Flameproof styrene containing graft resin compositions substantially free of phenolic resins and containing styrene/acrylonitrile resin compatabilizer 失效
    含防火苯乙烯的接枝树脂组合物基本上不含酚醛树脂,并含有苯乙烯/丙烯腈树脂复合材料

    公开(公告)号:US06716900B2

    公开(公告)日:2004-04-06

    申请号:US10052205

    申请日:2002-01-16

    IPC分类号: C08K5521

    摘要: A flameproof thermoplastic resin composition is substantially free of phenolic resin, red phosphorous and silicone resin and comprises (A) about 40-95 parts by weight of a rubber modified styrene-containing resin comprising (a1) about 20-95% by weight of a styrene-containing graft copolymer resin containing about 19-50% by weight of acrylonitrile in the copolymer excluding rubber and (a2) about 5-80% by weight of a styrene-containing copolymer containing about 19-50% by weight of acrylonitrile; (B) about 5-60 parts by weight of a polyphenylene ether resin; (C) about 2-40 parts by weight of a compatabilizer comprising (c1) a styrene-containing copolymer containing about 5-18% by weight of acrylonitrile in the copolymer per 100 parts by weight of the sum of (A) and (B) or (c2) a styrene-containing graft copolymer having up to about 60% by weight of rubber wherein the compatabilizer contains about 5-18% by weight of acrylonitrile in the copolymer excluding rubber, per 100 parts by weight of the sum of (A) and (B); and (D) about 5-30 parts by weight of an aromatic phosphoric acid ester per 100 parts by weight of the sum of (A) and (B). The physical properties and flame retardance of the resin compositions according to the present invention are adversely affected by the presence of 3% or more by weight of polycarbonate based on the total weight of the composition.

    摘要翻译: 防火热塑性树脂组合物基本上不含酚醛树脂,红磷和有机硅树脂,并且包含(A)约40-95重量份的含橡胶改性苯乙烯的树脂,其包含(a1)约20-95重量%的 在包含橡胶的共聚物中含有约19-50重量%丙烯腈的含苯乙烯接枝共聚物树脂和(a2)约5-80重量%含有约19-50重量%丙烯腈的含苯乙烯共聚物; (B)约5-60重量份聚苯醚树脂; (C)约2-40重量份的组合物,其包含(c1)含有共聚物中约5-18重量%丙烯腈的含苯乙烯共聚物,每100重量份(A)和(B )或(c2)含有至多约60重量%的橡胶的含苯乙烯的接枝共聚物,其中所述组合物在除橡胶之外的共聚物中含有约5-18重量%的丙烯腈,每100重量份的( A)和(B); 和(D)每100重量份(A)和(B)之和约5-30重量份的芳族磷酸酯。 根据本发明的树脂组合物的物理性能和阻燃性受到基于组合物总重量的3重量%或更多重量的聚碳酸酯的不利影响。

    Method of making masterbatches of liquid additives and, in particular, antimicrobial masterbatches
    6.
    发明授权
    Method of making masterbatches of liquid additives and, in particular, antimicrobial masterbatches 失效
    制备液体添加剂的母料的方法,特别是抗微生物母料

    公开(公告)号:US06284814B1

    公开(公告)日:2001-09-04

    申请号:US09143741

    申请日:1998-08-31

    申请人: Chakra V. Gupta

    发明人: Chakra V. Gupta

    IPC分类号: C08K5521

    摘要: A method for introducing relatively large quantities of liquid additives into polymer-containing composition includes increasing the free volume between polymer chains of the polymer(s) present in the composition and introducing at least one liquid additive into the free volume between the polymer chains. The method can optionally include the introduction of low melting additives into the polymer This method allows for the production of polymer masterbatchs from a wide variety of liquid additives that can contain upwards of 50% by weight active components. Such masterbatches can be a particularly useful technique for introducing biocides and/or antimicrobials into polymeric materials.

    摘要翻译: 将相对大量的液体添加剂引入含聚合物的组合物中的方法包括增加组合物中存在的聚合物的聚合物链之间的自由体积,并将至少一种液体添加剂引入到聚合物链之间的自由体积中。 该方法可以任选地包括将低熔点添加剂引入聚合物中。该方法允许从多种可以含有50重量%活性组分的液体添加剂生产聚合物母料。 这种母料可以是将杀生物剂和/或抗微生物剂引入聚合物材料中的特别有用的技术。

    Polyphenylene ether resin composition
    8.
    发明授权
    Polyphenylene ether resin composition 有权
    聚苯醚树脂组合物

    公开(公告)号:US06469077B1

    公开(公告)日:2002-10-22

    申请号:US09416892

    申请日:1999-10-13

    IPC分类号: C08K5521

    CPC分类号: C08K5/523 C08L71/12

    摘要: There is provided a polyphenylene ether resin composition, comprising: a component (A) containing a polyphenylene ether resin; a component (B) containing a phosphate compound represented by the following formula (I); and a component (C) containing a condensed phosphate compound represented by the following formula (II), wherein R1, R2 and R3 are independently of one another an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms or a hydroxyl group; R4, R5, R6 and R7 are independently of one another a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 6 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms or a hydroxyl group, provided that a case of R4=R5=R6=R=H is excluded; n is an integer of not less than 1; Z is an organic group having 1 to 10 carbon atoms; and q is an integer of from 0 to 4; and wherein said composition contains a content of phosphorus therein of from about 1.8 to 5% by weight based on the total weight of the polyphenylene ether resin composition.

    摘要翻译: 提供聚苯醚树脂组合物,其包含:含有聚苯醚树脂的组分(A);含有下式(I)表示的磷酸酯化合物的组分(B); 和含有下式(II)表示的缩合磷酸酯化合物的组分(C),其中R 1,R 2和R 3彼此独立地为具有1至20个碳原子的烷基,具有3至20个碳原子的环烷基, 碳原子数6〜20的芳基,碳原子数1〜20的烷氧基或羟基; R4,R5,R6和R7彼此独立地为氢原子,碳原子数1〜20的烷基,碳原子数为6〜20的环烷基,碳原子数为6〜20的芳基,烷氧基为 1〜20个碳原子或羟基,条件是R4 = R5 = R6 = R = H的情况除外; n为不小于1的整数; Z为碳原子数1〜10的有机基团。 q为0〜4的整数, 并且其中所述组合物含有基于聚苯醚树脂组合物总重量的约1.8至5重量%的磷含量。

    Water sensitive hot melt adhesive
    9.
    发明授权
    Water sensitive hot melt adhesive 失效
    水敏热熔胶

    公开(公告)号:US06291562B1

    公开(公告)日:2001-09-18

    申请号:US08619859

    申请日:1996-03-19

    申请人: John A. Kreuser

    发明人: John A. Kreuser

    IPC分类号: C08K5521

    摘要: A water sensitive hot melt adhesive composition is described which possesses properties which are desirable with respect to the construction of disposable articles. The adhesive composition includes about 5% to about 95%, by weight, of a poly [vinyl methyl ether]; about 5% to about 70%, by weight, of a tackifying resin; and about 5% to about 35%, by weight, of a water soluble plasticizer.

    摘要翻译: 描述了一种水敏热熔粘合剂组合物,其具有关于一次性制品的构造所需的性质。 粘合剂组合物包含约5%至约95%重量的聚[乙烯基甲基醚]; 约5重量%至约70重量%的增粘树脂; 和约5%至约35%的水溶性增塑剂。