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    Process and composition for desizing cellulosic fabric with an enzyme hybrid
    2.
    发明授权
    Process and composition for desizing cellulosic fabric with an enzyme hybrid 失效
    用酶杂交脱浆纤维素织物的方法和组合物

    公开(公告)号：US6017751A

    公开(公告)日：2000-01-25

    申请号：US812829

    申请日：1997-03-06

    Applicant: Claus von der Osten ,  Mads E. Bjornvad ,  Jesper Vind ,  Michael Dolberg Rasmussen

    Inventor： Claus von der Osten ,  Mads E. Bjornvad ,  Jesper Vind ,  Michael Dolberg Rasmussen

    IPC: C11D3/386 ,  C12N9/20 ,  C12N9/24 ,  C12N9/42 ,  C12P21/04 ,  D06L1/06 ,  D06M16/00 ,  C11D7/42 ,  C12N9/28

    CPC classification number: D06M16/003 ,  C12N9/20 ,  C12N9/2414 ,  C12N9/2437 ,  C12Y302/01001 ,  C12Y302/01004 ,  D06L1/06 ,  C07K2319/00

    Abstract: Cellulose-containing fabric is desized by treating with an enzyme hybrid having a catalytically active amino acid sequence of an enzyme such as a lipase or an amylase linked to an amino acid sequence containing a cellulose-binding domain. The enzyme amino acid sequence may be of an .alpha.-amylase obtainable from a species of Bacillus such as Bacillus licheniformis, or of a lipase obtainable from a species of Humicola, Candida, Pseudomonas or Bacillus. The cellulose-binding domain may be from a cellulase, a xylanase, a mannanase, an arabinofuranosidase, an acetylesterase or a chitinase. The enzyme hybrid is obtained from a transformed host cell containing an expression cassette having a DNA sequence encoding the enzyme hybrid. A desizing composition is formed containing the enzyme hybrid and a wetting agent.

    Abstract translation: 含有纤维素的织物通过用具有酶的催化活性氨基酸序列的酶杂交处理，如与包含纤维素结合结构域的氨基酸序列连接的脂肪酶或淀粉酶。 酶氨基酸序列可以是可从诸如地衣芽孢杆菌的芽孢杆菌种类获得的α-淀粉酶，或可从Humicola，假丝酵母​​属，假单胞菌属或芽孢杆菌属种获得的脂肪酶。 纤维素结合结构域可以来自纤维素酶，木聚糖酶，甘露聚糖酶，阿拉伯呋喃糖苷酶，乙酰酯酶或几丁质酶。 从具有编码酶杂交体的DNA序列的表达盒的转化宿主细胞获得酶杂交体。 形成含有酶杂化物和润湿剂的脱浆组合物。

    Graft polyesters and sized textiles
    4.
    发明授权
    Graft polyesters and sized textiles 失效

    公开(公告)号：US4477525A

    公开(公告)日：1984-10-16

    申请号：US435785

    申请日：1982-10-21

    Applicant: Robert B. Login

    Inventor： Robert B. Login

    IPC: C08F299/04 ,  C08G63/52 ,  D06L1/06 ,  D06M14/18 ,  D06M15/51 ,  D02G3/00

    CPC classification number: C08G63/52 ,  C08F299/0478 ,  D06L1/06 ,  D06M14/18 ,  D06M15/51 ,  Y10T428/2967 ,  Y10T428/2969

    Abstract: There are disclosed graft polyesters useful as adhesives and coatings and especially useful in processes for sizing spun and continuous filament synthetic organic and inorganic fibrous yarn. One embodiment of the invention is a textile size composition having free carboxyl groups which is prepared in situ on a textile yarn by the application of heat or radiation to a mixture of an unsaturated polyester reactant and a monovinyl monomer reactant comprising an acidic monovinyl monomer having at least one carboxyl group or mixtures thereof with any monovinyl monomer. Desizing can be accomplished by partial neutralization of the size to a pH of at least 6 by reacting the size with a base to render the graft polyester water-dispersible or water-soluble.The graft polyester compositions of the invention are especially useful as size compositions since they can be applied to the yarn from a solventless mixture and require only at least one of the application of heat or irradiation to graft polymerize the size in situ on the yarn. The graft polyester of the invention comprises the reaction product of (1) an unsaturated polyester which is the reaction product of at least one polycarboxylic acid reactant, preferably a dicarboxylic acid reactant and at least one polyhydric alcohol reactant, preferably a diol, wherein a minor effective proportion of at least one of said reactants is .alpha.,.beta.-ethylenically unsaturated with (2) at least one monovinyl monomer reactant comprising at least one acidic monovinyl monomer containing at least one carboxyl group or a mixture of said vinyl monomer with any monovinyl monomer.Alternatively, where water-insolubility is desired in the graft polyester under both acid and basic conditions, a polyunsaturated vinyl monomer is utilized having two or more vinyl groups per molecule. The graft polyesters of the invention prepared using monovinyl monomers also can be reacted with cross-linking resins, such as aminoplast resins, to confer water-insolubility under both basic and acid conditions.

    Hot melt size and yarns sized therewith
    5.
    发明授权
    Hot melt size and yarns sized therewith 失效
    热熔体尺寸和纱线尺寸

    公开(公告)号：US4401782A

    公开(公告)日：1983-08-30

    申请号：US441865

    申请日：1982-11-15

    Applicant: Delano M. Conklin ,  John H. Hansen ,  John B. Hodgin

    Inventor： Delano M. Conklin ,  John H. Hansen ,  John B. Hodgin

    IPC: D06M13/224 ,  D06M15/263 ,  C08L23/08 ,  D06L1/06 ,  D06M15/16

    CPC classification number: D06M13/224 ,  D06M15/263 ,  D06M2200/40 ,  Y10T428/2967

    Abstract: Non-aqueous, quick setting sizing compositions suitable for application as a melt to textile yarns, and for later removal by solvent or aqueous means, characterized by substantial amounts of hydrogenated tallow-type triglyceride wax, are disclosed. The compositions may include an approximately 50:50 weight mixture of a specific class of 80/20 ethylene/acrylic acid copolymers intimately blended with an equal amount of the wax. A fatty acid amide may be included in an amount up to about 7 weight percent of the composition or from 1 to 14 weight percent sebacic acid or dodecanedioic acid, the amount of copolymer being reduced accordingly. The compositions may contain up to 62 weight percent of the wax, and rigidify at ambient temperatures.

    Abstract translation: 公开了适用于作为纺织品纱线的熔体的非水性快速凝固施胶组合物，以及随后通过溶剂或水性方法去除的特征在于大量氢化牛脂型甘油三酯蜡。 组合物可以包括与等量的蜡密切混合的特定类别的80/20乙烯/丙烯酸共聚物的约50:50重量的混合物。 脂肪酸酰胺可以以组合物的约7重量％或1至14重量％的癸二酸或十二烷二酸的量包含，共聚物的量相应减少。 组合物可含有至多62重量％的蜡，并在环境温度下硬化。

    Process for desizing and cleaning woven fabrics and garments
    8.
    发明授权
    Process for desizing and cleaning woven fabrics and garments 失效
    退浆和清洁织物和服装的工艺

    公开(公告)号：US5980581A

    公开(公告)日：1999-11-09

    申请号：US148950

    申请日：1998-09-08

    Applicant: Wayne Patterson, Jr. ,  Robert Scott Mauney ,  Drayton Timms Virkler

    Inventor： Wayne Patterson, Jr. ,  Robert Scott Mauney ,  Drayton Timms Virkler

    IPC: C11D1/722 ,  C11D3/12 ,  D06L1/14 ,  D06L1/06

    CPC classification number: D06L1/14 ,  C11D3/1266

    Abstract: A process for desizing and cleaning fabrics and garments which produces a substantially desized fabric or garment while holding the dye that is removed from the garment in suspension in the bath is disclosed. The process includes the steps of immersing the woven fabric or garments in an aqueous bath containing from about 1.0% to about 8.0% owg of a desizing agent and maintaining the fabric in the desizing bath for a time sufficient to desize the goods while minimizing the removal of dye present in the goods. The desizing agent includes from about 1.0% to about 100% by weight of the desizing agent of a clay and up to about 10% by weight of the desizing agent of at least one surfactant.

    Abstract translation: 公开了一种用于退浆和清洁织物和衣服的方法，其产生基本上退浆的织物或衣服，同时保持在衣服中悬浮在服装中的衣物中除去的染料。 该方法包括以下步骤：将织物或衣服浸入含有约1.0％至约8.0％owg脱浆剂的水浴中，并将织物保持在脱浆浴中足够的时间以使料品退浆同时最小化除去 的染料存在于货物中。 脱浆剂包括约1.0％至约100％重量的脱浆剂粘土和至多约10％重量的脱浆剂至少一种表面活性剂。

    Process for desizing and bleaching cloth with a hydrogen peroxide-based bath in a single operation
    9.
    发明授权
    Process for desizing and bleaching cloth with a hydrogen peroxide-based bath in a single operation 失效
    在单次操作中用基于过氧化氢的浴脱浆和漂白布的方法

    公开(公告)号：US4457760A

    公开(公告)日：1984-07-03

    申请号：US335100

    申请日：1981-12-28

    Applicant: Jean-Marie Cholley

    Inventor： Jean-Marie Cholley

    IPC: C12S11/00 ,  D06L1/14 ,  D06L3/02 ,  D06L3/11 ,  D06L1/06 ,  D06L3/00

    CPC classification number: D06L1/14 ,  D06L3/02

    Abstract: Processes for desizing and bleaching cloth in a single operation utilizing a bath containing hydrogen peroxide, sodium hydroxide, a sequestrant, an enzyme preparation based on a starch-degrading enzyme, and a surface active agent, such processes resulting in significant economies in usage of water and of steam, labor, and capital costs.

    Abstract translation: 在使用含有过氧化氢，氢氧化钠，多价螯合剂，基于淀粉降解酶的酶制剂和表面活性剂的浴的单次操作中进行脱浆和漂白布的方法，导致使用水的显着经济 以及蒸汽，劳动和资本成本。

    Graft polyesters and sized textiles
    10.
    发明授权
    Graft polyesters and sized textiles 失效

    公开(公告)号：US4259457A

    公开(公告)日：1981-03-31

    申请号：US59695

    申请日：1979-07-23

    Applicant: Robert B. Login

    Inventor： Robert B. Login

    IPC: C08F299/04 ,  D06L1/06 ,  D06M14/18 ,  D06M15/51 ,  B05D3/06 ,  C08L67/06 ,  D02G3/00

    CPC classification number: C08F299/0478 ,  D06L1/06 ,  D06M14/18 ,  D06M15/51 ,  Y10T428/2933 ,  Y10T428/2969

    Abstract: There are disclosed graft polyesters useful as adhesives and coatings and especially useful in processes for sizing spun and continuous filament synthetic organic and inorganic fibrous yarn. One embodiment of the invention is a textile size composition having free carboxyl groups which is prepared in situ on a textile yarn by the application of heat or radiation to a mixture of an unsaturated polyester reactant and a monovinyl monomer reactant comprising an acidic monovinyl monomer having at least one carboxyl group or mixtures thereof with any monovinyl monomer. Desizing can be accomplished by partial neutralization of the size to a pH of at least 6 by reacting the size with a base to render the graft polyester water-dispersible or water-soluble.The graft polyester compositions of the invention are especially useful as size compositions since they can be applied to the yarn from a solventless mixture and require only at least one of the application of heat or irradiation to graft polymerize the size in situ on the yarn. The graft polyester of the invention comprises the reaction product of (1) an unsaturated polyester which is the reaction product of at least one polycarboxylic acid reactant, preferably a dicarboxylic acid reactant and at least one polyhydric alcohol reactant, preferably a diol, wherein a minor effective proportion of at least one of said reactants is .alpha.,.beta.-ethylenically unsaturated with (2) at least one monovinyl monomer reactant comprising at least one acidic monovinyl monomer containing at least one carboxyl group or a mixture of said vinyl monomer with any monovinyl monomer.Alternatively, where water-insolubility is desired in the graft polyester under both acid and basic conditions, a polyunsaturated vinyl monomer is utilized having two or more vinyl groups per molecule. The graft polyesters of the invention prepared using monovinyl monomers also can be reacted with cross-linking resins, such as aminoplast resins, to confer water-insolubility under both basic and acid conditions.

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