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公开(公告)号：US11986810B1
公开(公告)日：2024-05-21
申请号：US18405177
申请日：2024-01-05
IPC分类号： B01J31/24 , B01J31/20 , B01J31/22 , B01J37/02 , B01J37/03 , B01J37/04 , B01J37/06 , C07F15/00
CPC分类号： B01J31/2409 , B01J31/20 , B01J31/226 , B01J31/2291 , B01J31/2295 , B01J37/0236 , B01J37/031 , B01J37/04 , B01J37/06 , C07F15/0046 , B01J2231/643 , B01J2531/0205 , B01J2531/821
摘要： A 4,4′-divinylazoarylene-bridged diruthenium complex with a general formula [{Ru(CO)(L-κ2[N,S]−)(PiPr3)2}2(μ—{CH═CH—C6H2—(iPr)2-2,6}2—N═N-4,4′)], its synthesis, and its use as an catalyst in inorganic processes.
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公开(公告)号：US20240132427A1
公开(公告)日：2024-04-25
申请号：US18049211
申请日：2022-10-23
申请人： Randolph Belter
发明人： Randolph Belter
IPC分类号： C07C17/281 , B01J19/24 , B01J27/128 , B01J31/02 , B01J31/20 , B01J31/30 , B01J31/40
CPC分类号： C07C17/281 , B01J19/24 , B01J27/128 , B01J31/0258 , B01J31/20 , B01J31/30 , B01J31/403 , B01J2231/4205 , B01J2531/842
摘要： Chemical processes are disclosed that act to both regenerate and create new catalyst for iron salt catalyzed Kharasch coupling reactions during the process of creating halogenated hydrocarbons. Such processes include loading a reactor with a quantity of Fe(0) metal such as iron wire, supplying CCl4 to the reactor, supplying a phosphate compound to the reactor, supplying an alkene to the reactor, and supplying a carbonyl of Fe(0) to the reactor.
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3.发明授权公开(公告)号：US11932592B2
公开(公告)日：2024-03-19
申请号：US17044906
申请日：2019-04-04
发明人： Fabrizio Cavani , Valerio Zanotti , Rita Mazzoni , Carlo Lucarelli , Cristiana Cesari , Tommaso Tabanelli , Francesco Puzzo
CPC分类号： C07C29/34 , B01J31/20 , B01J31/2295 , C07C29/94 , B01J2231/44 , B01J2531/821
摘要： A process for obtaining higher aliphatic alcohols starting from aliphatic primary alcohols by condensation reactions is disclosed. Specifically, the process comprises a step in which an aliphatic primary alcohol is contacted in a homogeneous phase with a catalyst mixture comprising a transition metal, a base and an additive; specifically, this additive can be selected from the classes of compounds of the isoquinolines N-oxide, quinolines N-oxide, pyridines N-oxide, benzoquinones, naphthoquinones, or TEMPO. In particular, the process can be carried out by contacting said aliphatic primary alcohol with a catalyst of a recycled transition metal, with a freshly added base and with a recycled additive of the aforementioned type.
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公开(公告)号：US20240059636A1
公开(公告)日：2024-02-22
申请号：US18269127
申请日：2021-12-20
申请人： Givaudan SA
发明人： Fridtjof SCHRÖDER , Eric EICHHORN
IPC分类号： C07C29/147 , C07C51/08 , C07C231/06 , C07C51/09 , C07C29/09 , C07C233/09 , B01J31/24 , B01J31/20
CPC分类号： C07C29/147 , C07C51/08 , C07C231/065 , C07C51/09 , C07C29/09 , C07C233/09 , B01J31/2409 , B01J31/20 , B01J2231/40 , B01J2531/821
摘要： There is provided a method for preparing homofarnesol (1), the method comprising the steps of:
a) providing homofarnesylnitrile (2);
b) reacting homofarnesylnitrile (2) to homofarnesic acid (3); and
c) reacting homofarnesic acid (3) to homofarnesol (1),
wherein the configuration of the double bonds in the compounds 1, 2 and 3 is preserved.-
5.发明公开公开(公告)号：US20230193030A1
公开(公告)日：2023-06-22
申请号：US17925794
申请日：2021-05-18
CPC分类号： C08L83/16 , B01J31/1641 , B01J31/20 , C08G77/60 , C08L2203/206 , C08L2312/08 , B01J2231/323 , B01J2531/828
摘要： A curable composition comprises: at least one aliphatic carbosilane having m Si—H groups, at least one aliphatic carbosilane having n vinyl groups, and at least one hydrosilylation reaction catalyst. m is an integer greater than or equal to 2, n is an integer greater than or equal to 2, and m+n is at least 5. A cured reaction product and an electronic article including the same are also disclosed.
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公开(公告)号：US11667617B2
公开(公告)日：2023-06-06
申请号：US16919763
申请日：2020-07-02
申请人： Novomer, Inc.
发明人： Sadesh H. Sookraj
IPC分类号： B01J31/20 , C07D305/12 , C07D307/60 , B01J31/22 , B01J31/40 , B01J38/74
CPC分类号： C07D305/12 , B01J31/20 , B01J31/2217 , B01J31/403 , B01J38/74 , C07D307/60 , Y02P20/584
摘要： The present invention provides novel solutions to the problem of recycling carbonylation catalysts in epoxide carbonylation processes. The inventive methods are characterized in that the catalyst is recovered in a form other than as active catalyst. In some embodiments, catalyst components are removed selectively from the carbonylation product stream in two or more processing steps. One or more of these separated catalyst components are then utilized to regenerate active catalyst which is utilized during another time interval to feed a continuous carbonylation reactor.
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公开(公告)号：US20230021218A1
公开(公告)日：2023-01-19
申请号：US17758257
申请日：2021-01-04
申请人： Cornell University
发明人： Greeshma GADIKOTA
摘要： The present disclosure relates to methods for producing hydrogen and calcium- or magnesium-bearing carbonates by capturing, converting, and storing carbon dioxide. The methods may include providing one or more calcium- or magnesium-bearing compounds; providing one or more water-soluble oxygenates; providing a plurality of catalysts; and reacting one or more calcium- or magnesium-bearing compounds and one or more water-soluble oxygenates with plurality of catalysts under conditions to produce hydrogen and calcium- or magnesium-bearing carbonates. The methods may include providing one or more calcium- or magnesium-bearing silicates; providing carbon monoxide; providing water vapor; and reacting one or more calcium- or magnesium-bearing silicates, carbon monoxide, and water vapor. The methods may include providing one or more calcium- or magnesium-bearing compounds; providing one or more water-soluble oxygenates; providing a catalyst; and reacting one or more calcium- or magnesium-bearing compounds and one or more water-soluble oxygenates with said catalyst.
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公开(公告)号：US20220185833A1
公开(公告)日：2022-06-16
申请号：US17540601
申请日：2021-12-02
发明人： Jens Langanke , Christoph Guertler , Matthias Leven , Daniel Schikowski , Walter Leitner , Suresh Raju
摘要： The invention relates to a process for the carbonylation of epoxides in the presence of catalyst systems, in which the carbonylation is carried out in the presence of carbon monoxide, and wherein the catalyst system comprises a vanadium-based, chromium-based, manganese-based and/or tungsten-based compound, preferably a tungsten-based compound. The invention further relates to carbonylation products and carbonylation conversion products and to the use of catalyst systems according to the invention for carbonylation of epoxides.
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9.发明申请公开(公告)号：US20220073344A1
公开(公告)日：2022-03-10
申请号：US17416772
申请日：2019-12-30
发明人： David MILSTEIN , You-Quan ZHOU , Aviel ANABY
摘要： This invention provides a reversible hydrogen loading and discharging system and a reversible method for loading and discharging hydrogen. The system and the methods of this invention comprise ethylene glycol as a liquid organic hydrogen carrier and at least one transition metal. By reacting ethylene glycol with at least one transition metal; at least one hydrogen molecule and at least one oligoester of ethylene glycol are formed (hydrogen releasing)⋅, and by reacting at least one oligoester of ethylene glycol with at least one transition metal and at least one hydrogen molecule, at least one ethylene glycol is formed (hydrogen loading).
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10.发明授权公开(公告)号：US11185852B2
公开(公告)日：2021-11-30
申请号：US16306839
申请日：2018-02-02
申请人： LG CHEM, LTD.
发明人： Tae Yun Kim , Min Ji Choi , Sung Shik Eom , Mi Young Kim , Dong Hyun Ko , Da Won Jung
摘要： The present invention relates to a catalyst composition for hydroformylation and a method of preparing an aldehyde using the same. More specifically, the present invention provides a catalyst composition for hydroformylation including a specific phosphite-based ligand and a transition metal compound in a specific amount range, thereby being capable of greatly lowering a use amount of an expensive transition metal compound and exhibiting excellent catalyst activity or stability. In addition, by using the catalyst composition in hydroformylation, excellent reaction efficiency may be provided and iso-aldehyde may be generated in high yield.
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