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    Process for producing dodecanedioic acid dimethyl
    5.
    发明授权
    Process for producing dodecanedioic acid dimethyl 失效
    十二烷二酸二甲酯的制备方法

    公开(公告)号：US3984462A

    公开(公告)日：1976-10-05

    申请号：US534783

    申请日：1974-12-20

    申请人： Shigeru Tsutsumi ,  Yoshishige Kida

    发明人： Shigeru Tsutsumi ,  Yoshishige Kida

    IPC分类号： C07C69/34 ,  B01J27/00 ,  C07B61/00 ,  C07C409/20 ,  C07C67/42

    CPC分类号： C07C407/00 ,  C07C2101/14

    摘要： A process for producing dodecanedioic acid dimethyl ester comprising the steps of reacting cyclohexanone with methanol and hydrogen peroxide in the presence of an acid catalyst and water at a temperature below the boiling point of the methanol to produce methoxycyclohexyl peroxide, said methanol and hydrogen peroxide being used in an amount of about 15 to about 36 moles and in an amount of about 0.5 to about 1.5 moles per mole of the cyclohexanone respectively, dimerizing the resulting methoxycyclohexyl peroxide as it is contained in the reaction mixture in the presence of a ferrous salt and at least about 25 moles of methanol per mole of the starting cyclohexanone to produce dodecanedioic acid dimethyl ester, and separating the resulting dodecanedioic acid dimethyl ester from the reaction mixture.

    摘要翻译： 一种生产十二烷二酸二甲酯的方法，包括在酸催化剂和水的存在下，在低于甲醇沸点的温度下，使环己酮与甲醇和过氧化氢反应，生成甲氧基环己基过氧化物，所用的甲醇和过氧化氢 分别为每摩尔环己酮约15至约36摩尔和约0.5至约1.5摩尔量的量，将二氯化产生的甲氧基环己基过氧化物在亚铁盐存在下反应在反应混合物中，并在 每摩尔起始环己酮至少约25摩尔甲醇以产生十二烷二酸二甲酯，并将所得十二烷二酸二甲酯从反应混合物中分离。

    Organic peroxides their preparation and their applications
    6.
    发明授权
    Organic peroxides their preparation and their applications 失效
    有机过氧化物的制备及其应用

    公开(公告)号：US3980712A

    公开(公告)日：1976-09-14

    申请号：US374009

    申请日：1973-06-26

    申请人： Egeo Sacrini ,  Claudio Cavallotti

    发明人： Egeo Sacrini ,  Claudio Cavallotti

    IPC分类号： C07C409/20 ,  C07C409/22 ,  C07C179/00

    CPC分类号： C07C409/20 ,  C07C409/22

    摘要： Tetraperoxides of the formula ##EQU1## where X is a bivalent radical such as alkylene; R.sub.1 is hydrogen or an organic radical; R.sub.2 is alkylene alkoxy carbonyl; and R.sub.3 is an organic radical. Method of preparing tetraperoxides by addition reaction between a bis-hydroperoxide and a carbonyl compound to form a dihydroxy diperoxide, followed by condensation of the dihydroxy diperoxide with a tertiary monohydroxide. The tetraperoxides are useful for vulcanizing saturated elastomers, crosslinking plastomers, and initiating radical polymerization.

    摘要翻译： 式R1R1 || R3-OO-C-OO-X-OO-C-R3 || R2R2的四环氧化物其中X是二价基团如亚烷基; R1是氢或有机基团; R2是亚烷基烷氧基羰基; 并且R 3是有机基团。 通过双氢过氧化物和羰基化合物之间的加成反应制备四
    氧化物以形成二羟基二过氧化物，然后二羟基二过氧化物与叔氢氧化物的缩合制备方法。 四元素可用于硫化饱和弹性体，交联塑性体和引发自由基聚合。

    Organic peroxides, their preparation, and their applications
    7.
    发明授权
    Organic peroxides, their preparation, and their applications 失效
    有机过氧化物，它们的制备及其应用

    公开(公告)号：US3928464A

    公开(公告)日：1975-12-23

    申请号：US57060175

    申请日：1975-04-23

    申请人： GOODRICH CO B F

    发明人： SACRINI EGEO ,  CAVALLOTTI CLAUDIO

    IPC分类号： C07C409/20 ,  C07C409/22 ,  C07C179/06

    CPC分类号： C07C409/22 ,  C07C2601/14

    摘要： Tetraperoxides of the formula

    where X is a bivalent radical such as alkylene; R1 is hydrogen or an organic radical; R2 is alkylene alkoxy carbonyl; and R3 is an organic radical. Method of preparing tetraperoxides by addition reaction between a bis-hydroperoxide and a carbonyl compound to form a dihydroxy diperoxide, followed by condensation of the dihydroxy diperoxide with a tertiary monohydroxide. The tetraperoxides are useful for vulcanizing saturated elastomers, crosslinking plastomers, and initiating radical polymerization.

    摘要翻译： 式R1R1 || R3-OO-C-OO-X-OO-C-R3 || R2R2的四环氧化物其中X是二价基团如亚烷基; R1是氢或有机基团; R2是亚烷基烷氧基羰基; 并且R 3是有机基团。 通过双氢过氧化物和羰基化合物之间的加成反应制备四
    氧化物以形成二羟基二过氧化物，然后二羟基二过氧化物与叔氢氧化物的缩合制备方法。 四元素可用于硫化饱和弹性体，交联塑性体和引发自由基聚合。

    Epoxide preparation
    10.
    发明授权
    Epoxide preparation 失效
    环氧化物制备

    公开(公告)号：US3642832A

    公开(公告)日：1972-02-15

    申请号：US3642832D

    申请日：1969-03-18

    申请人： TEXACO INC

    发明人： SMETANA RICHARD DENIS ,  CHAFETZ HARRY ,  ARKELL ALFRED

    IPC分类号： C07C409/20 ,  C07D303/04 ,  C07D1/08 ,  C07D1/12

    CPC分类号： C07D303/04

    摘要： A METHOD OF PRODUCING AN EPOXIDE OF THE FORMULA:

    2-R1,2-R2,3-R3,3-R4-OXIRANE OR 2,3-(-R5-)OXIRANE

    WHERE R1, R2, R3 AND R4 ARE HYDROGEN OR HYDROCARBYL AND R5 IS X,$-ALKYLENE COMPRISING CONTACTING A FIRST OLEFIN OF THE FORMULA:

    R1-C(-R2)=C(-R3)-R4 OR R5
    WHERE R1 THROUGH R5 IS AS HERETOFORE DEFINED WITH AN ALKOXYHYDROPEROXIDE OF THE FORMULA:

    R6-C(-R7)(-O-OH)-O-R10 AND/OR R8-C(-R9)(-O-OH)-O-R10

    WHERE R6, R7, R8 AND R9 ARE HYDROGEN OR HYDROCARBYL IN THE PRESENCE OF A MOLYBDENUM, TUNGSTEN OR VANADIUM EPOXIDE PRODUCING CATALYST, SAID HYDROPEROXIDE PREPARED BY CONTACTING A MIXTURE OF A SECOND OLEFIN OF THE FORMULA:

    R6R7C=CR8R9

    WHERE R6 R7, R8 AND R9 ARE AS HERETOFORE DEFINED, AND AN ALKANOL OF THE FORMULA R10OH WHERE R10 IS ALKYL WITH OZONE.