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    PROCESS AND CATALYST FOR THE PRODUCTION OF PYRIDINE AND ALKYL DERIVATIVES THEREOF
    1.
    发明申请
    PROCESS AND CATALYST FOR THE PRODUCTION OF PYRIDINE AND ALKYL DERIVATIVES THEREOF 有权
    用于生产吡啶和其衍生物的方法和催化剂

    公开(公告)号：US20150239841A1

    公开(公告)日：2015-08-27

    申请号：US14437997

    申请日：2013-10-24

    申请人： W. R. GRACE & CO.-CONN.

    发明人： Dorai Ramprasad

    IPC分类号： C07D213/10 ,  B01J37/08 ,  C07D213/09 ,  B01J29/40

    CPC分类号： B01J29/405 ,  B01J37/0045 ,  B01J37/08 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/42 ,  C07D213/09 ,  C07D213/10

    摘要： A process for increasing the overall yield of pyridine or its alkyl pyridine derivatives during a base synthesis reaction is disclosed. The process comprises reacting a C2 to C5 aldehyde, a C3 to C5 ketone or a combination thereof, with ammonia and, optionally, formaldehyde, in the gas phase and in the presence of an effective amount of a particulate catalyst comprising a zeolite, zinc, a binder, and clay and optionally a matrix, wherein the catalyst has a L/B ratio of about 1.5 to about 4.0. Preferably, the zeolite is ZSM-5. A process for enhancing the catalytic activity of a zinc and zeolite containing catalyst to increase the overall yield of pyridine and/or its derivatives during a base synthesis reaction is also disclosed.

    摘要翻译： 公开了在碱合成反应期间提高吡啶或其烷基吡啶衍生物的总收率的方法。 该方法包括使C2至C5醛，C3至C5酮或其组合与氨和任选的甲醛在气相中和有效量的颗粒催化剂存在下反应，所述颗粒催化剂包含沸石，锌， 粘合剂，粘土和任选的基质，其中催化剂的L / B比为约1.5至约4.0。 优选地，沸石是ZSM-5。 还公开了一种在碱合成反应期间提高含有锌和沸石的催化剂以提高吡啶和/或其衍生物的总产率的催化活性的方法。

    Polymeric hair dyes
    3.
    发明授权
    Polymeric hair dyes 有权
    聚合染发剂

    公开(公告)号：US08118883B2

    公开(公告)日：2012-02-21

    申请号：US12812785

    申请日：2009-01-07

    申请人： Sophie Marquais-Bienewald ,  Christian Cremer ,  Olof Wallquist ,  Robert Hochberg

    发明人： Sophie Marquais-Bienewald ,  Christian Cremer ,  Olof Wallquist ,  Robert Hochberg

    IPC分类号： A61Q5/10 ,  C07D213/09

    CPC分类号： C09B69/106 ,  A61K8/4946 ,  A61K8/69 ,  A61K8/84 ,  A61K2800/57 ,  A61Q5/02 ,  A61Q5/065 ,  A61Q5/12

    摘要： Disclosed are polymeric dyes obtained by the reaction of (a) a basic polycondensate with (b) an electrophilic dye of formula (2) P—X—Ya+ Ana+; wherein the basic polycondensate (a) is obtained by the reaction of (a1) an amine of formula (I) in the presence of an anhydrous solvent with an ammonium salt (a2) with a cyanamide: Wherein P, X, Y, a+, a, a1, a2, An, R1, R2, R3, R4, R5, R6 and A are defined in the claims and in the disclosure. The present invention also relates to compositions comprising these polymeric dyes, to a process for their use for dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides.

    摘要翻译： 公开了通过（a）碱性缩聚物与（b）式（2）的亲电子染料P-X-Ya + Ana +的反应获得的聚合染料; 其中碱性缩聚物（a）通过（a1）式（I）的胺在无水溶剂与铵盐（a2）的存在下与氨基氰反应而获得：其中P，X，Y，a +， a，a1，a2，an，R1，R2，R3，R4，R5，R6和A在权利要求书和本公开内容中定义。 本发明还涉及包含这些聚合染料的组合物，其用于染色有机材料如角蛋白纤维，羊毛，皮革，丝绸，纤维素或聚酰胺的方法。

    Pyridine base synthesis
    4.
    发明授权
    Pyridine base synthesis 失效
    吡啶碱合成

    公开(公告)号：US5780635A

    公开(公告)日：1998-07-14

    申请号：US668580

    申请日：1996-06-21

    申请人： Colin Hugh McAteer ,  Douglas Clifford Brown ,  Robert Drummond Davis, Sr.

    发明人： Colin Hugh McAteer ,  Douglas Clifford Brown ,  Robert Drummond Davis, Sr.

    IPC分类号： C07D213/12 ,  B01J29/06 ,  C07B61/00 ,  C07D213/08 ,  C07D213/09 ,  C07D213/10

    CPC分类号： C07D213/08 ,  C07D213/10

    摘要： A base synthesis process and catalyst for the preparation of pyridine or its alkylpyridine derivatives involving the catalytic reaction of one or more aldehydes and/or ketones containing from one to about five carbon atoms, with at least one reactant having more than one carbon atom, with ammonia in the gas phase. The catalyst comprises an effective amount of a large-pore zeolite having been prepared with a silica to alumina ratio of at least 15, and at least a first dimension having first channels formed by twelve-membered rings, and a second dimension having second channels formed by ten- or twelve-membered rings which intersect the first channels. The preferred zeolite is a zeolite having the structure of zeolite beta.

    摘要翻译： 用于制备吡啶或其烷基吡啶衍生物的基础合成方法和催化剂，其涉及一种或多种含有1至约5个碳原子的醛和/或酮与至少一种具有多于一个碳原子的反应物的催化反应， 氨气在气相中。 催化剂包含有效量的二氧化硅与氧化铝比至少为15的多孔沸石，以及至少具有由十二元环形成的第一通道的第一尺寸和形成有第二通道的第二尺寸 通过与第一通道相交的十二或十二元环。 优选的沸石是具有β沸石结构的沸石。

    Synthesis of pyridine and 3-alkylpyridine
    5.
    发明授权
    Synthesis of pyridine and 3-alkylpyridine 失效
    吡啶和3-烷基吡啶的合成

    公开(公告)号：US5395940A

    公开(公告)日：1995-03-07

    申请号：US73213

    申请日：1993-06-07

    申请人： Philip J. Angevine ,  Cynthia T-W. Chu ,  Thomas C. Potter

    发明人： Philip J. Angevine ,  Cynthia T-W. Chu ,  Thomas C. Potter

    IPC分类号： C07D213/08 ,  C07D213/09 ,  C07D213/10

    CPC分类号： C07D213/08 ,  C07D213/10

    摘要： An improved process is provided for selectively synthesizing pyridine and 3-alkylpyridine in high yield by reacting ammonia and a carbonyl reactant selected from the group consisting of formaldehyde, an aldehyde containing from 2 to 4 carbon atoms, a ketone containing from 3 to 5 carbon atoms, and mixtures thereof under effective conditions in the presence of a catalyst comprising an active form of a synthetic porous crystalline MCM-49 or synthetic porous crystalline material characterized by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07, and 3.42.+-.0.06 Angstroms, e.g., MCM-22, and recovering from the resulting reaction mixture a product enriched in pyridine and 3-alkylpyridine.

    摘要翻译： 提供了一种改进的方法，用于通过使氨和选自甲醛，含有2至4个碳原子的醛，含3至5个碳原子的酮的羰基反应物选择性合成吡咯和3-烷基吡啶 ，以及它们在有效条件下的存在下的混合物，所述催化剂包含活性形式的合成多孔结晶MCM-49或合成多孔结晶材料，其特征在于包括在12.36 +/- 0.4的面间d-间距的X射线衍射图， 11.03 +/- 0.2,8.33 +/- 0.14，6.18 +/- 0.12，6.00 +/- 0.10,4.06 +/- 0.07,3.91 +/- 0.07和3.42 +/- 0.06埃，例如MCM-22， 并从所得反应混合物中回收富含吡啶和3-烷基吡啶的产物。

    2,4-dimethyl-5-oxohexane and a method of use therefor
    6.
    发明授权
    2,4-dimethyl-5-oxohexane and a method of use therefor 失效
    2,4-二甲基-5-氧代己烷及其用途的方法

    公开(公告)号：US5334721A

    公开(公告)日：1994-08-02

    申请号：US98909

    申请日：1993-07-29

    申请人： Anna M. C. F. Castelijns ,  Henricus J. Arts ,  Richard Green

    发明人： Anna M. C. F. Castelijns ,  Henricus J. Arts ,  Richard Green

    IPC分类号： C07C255/17 ,  C07D213/08 ,  C07D213/09 ,  C07D213/12

    CPC分类号： C07D213/08 ,  C07C255/17

    摘要： The invention relates to a process for the preparation of high yields of 5-oxohexane nitriles with minimum formation of 1 undesired isomer. Such nitriles may be utilized as starting materials for the preparation of pharmaceutical and agrochemical intermediates and as well as final products. The process comprises reacting a methyl ketone and an .alpha.,.beta.-unsaturated nitrile in the presence of a catalytically effective amount of a strong base. One of the products which may be created by the process is 2,4-dimethyl-5-oxohexane nitrile.

    摘要翻译： 本发明涉及一种制备高产量的5-氧代己烷腈的方法，最少形成1种不需要的异构体。 这种腈可以用作制备药物和农药中间体以及最终产品的起始原料。 该方法包括在催化有效量的强碱存在下使甲基酮和α，β-不饱和腈反应。 可以通过该方法产生的产物之一是2,4-二甲基-5-氧代己烷腈。

    Process for the preparation of a pyridone-2
    9.
    发明授权
    Process for the preparation of a pyridone-2 失效
    制备吡啶酮-2的方法

    公开(公告)号：US4599421A

    公开(公告)日：1986-07-08

    申请号：US601342

    申请日：1984-04-17

    申请人： Roland E. van der Stoel ,  Marcel A. R. Bosma

    发明人： Roland E. van der Stoel ,  Marcel A. R. Bosma

    IPC分类号： C07D213/08 ,  C07D213/09 ,  C07D213/64 ,  C07D211/88

    CPC分类号： C07D213/08 ,  C07D213/64

    摘要： Pyridone-2 compounds are prepared by reacting an oxoalkanecarboxylic acid having as general formula ##STR1## where R.sub.2 and R.sub.3 represent hydrogen or an alkyl group having 1-4 C atoms, or an ester of such an acid in the gas phase with an amine compound R.sub.1 NH.sub.2,where R.sub.1 represents hydrogen or an alkyl group with 1-4 C atoms, at a temperature of 250.degree.-450.degree. C. in the presence of a dehydrogenating catalyst.

    摘要翻译： 吡啶酮-2化合物通过使具有通式为“IMAGE”的氧代烷基羧酸（其中R 2和R 3表示氢或具有1-4个C原子的烷基）或这种酸的酯在气相中与胺化合物 R1NH2，其中R1表示氢或1-4C原子的烷基，在脱氢催化剂存在下，在250-450℃的温度下进行。