摘要:
A single body, which is a base material that contains a dichromatic dye formed from an azo compound, that exhibits transmissivity of equal to or greater than 35% and a polarization degree adjusted to equal to or greater than 99% and is characterized in that a* and b* values, which are acquired for a polarization element or a polarization plate using JIS⋅Z⋅8729, have an a* and b* absolute value that is: less than 1 at the time of a single-body transmittance measurement; less than 2 when two sheets of the base material are arranged parallel to the absorbing axis direction and the a* and b* values are measured; and less than 2 when two sheets of the base material are arranged orthogonal to the absorbing axis direction and the a* and b* values are measured.
摘要:
The present invention relates to an azo compound represented by the following formula (1): wherein A denotes a phenyl group having 1 to 3 substituents such as sulfonic acid group, amino group, lower alkyl groups and lower alkoxyl groups, or a naphthyl group, B denotes hydrogen atom, sulfonic acid group, a lower alkyl group, a lower alkoxyl group or the like, each of R1 to R4 independently denotes hydrogen atom, a halogen atom, a lower alkyl group, a lower alkoxyl group or the like, D denotes —NHCO—, —N═N— or —NH—, E denotes hydrogen atom, a lower alkyl group or a phenyl group having 1 to 3 substituents such as hydroxyl group and amino group, n denotes 0 or 1, and m denotes 0 or 1, or a salt thereof, or a copper complex compound of either of them, which is used for a polarizing plate having excellent polarization performance and durability and furthermore little color leakage in visible light range.
摘要:
This invention relates to coppered azo dyestuffs containing an alkyl-, aryl or alkoxyalkyl sulfamyl group on one moiety of the molecule and an alkyl-, aryl or alkoxyalkyl ammonium sulfonate or carboxylate group on the other moiety. The invention also relates to various intermediates, to compositions and to processes for preparing the metalized dyestuffs. The compounds are particularly suited for the application in laquers, ink-jet inks and electrographic toners.
摘要:
This invention relates to a polyvinyl alcohol type polarizing film or plate which comprises a water-soluble dye having the formula (1) in a free acid form or a copper complex salt thereof. The said polarizing plate has excellent polarizing performance capability and durability, and is suitably used for the green channel of a liquid crystal projector when B in formula (1) is a benzoylamino group and the water-soluble dye has a wave length for maximum absorption (λmax) of 520 nm or more and less than 580 nm.
摘要:
The new disazo dyestuffs of the formula (I) ##STR1## in which the substituents and indices have the meaning given in the description, and salts thereof are outstandingly suitable for dyeing cellulose-containing materials and leather in blue shades having good wet- and light-fastnesses.
摘要:
Complexes of the formula ##STR1## and salts thereof, wherein each of R.sub.1 -R.sub.4 is independently hydrogen, halo, nitro, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, --NHCOR.sub.8, --COX or --SO.sub.2 Z,wherein R.sub.8 is C.sub.1-4 alkyl or phenyl,X is hydroxy, C.sub.1-4 alkoxy, phenoxy, substituted phenoxy, phenyl(C.sub.1-4 alkoxy), substituted phenyl(C.sub.1-4 alkoxy), C.sub.1-4 alkyl, phenyl, substituted phenyl, cyclohexyl, cyclohexyl substituted by 1 to 3 C.sub.1-4 alkyl groups, amino or substituted amino, andZ is --CH.sub.2 CH.sub.2 OSO.sub.3 H, --CH.dbd.CH.sub.2 or a significance of X with the exception of C.sub.1-4 alkyl,with the proviso that 1 to 3 of R.sub.1 -R.sub.4 are --SO.sub.2 Z or at least two of R.sub.1 -R.sub.4 are --COOH,each R.sub.5 is independently hydrogen, C.sub.1-4 alkyl or C.sub.1-4 alkyl monosubstituted by hydroxy, chloro or cyano,R.sub.6 is halo, hydroxy, C.sub.1-4 alkoxy, phenoxy, amino or substituted amino, andeach R.sub.7 is independently hydrogen or halo,and mixtures of such complexes each of which is independently in free acid or salt form, are useful for dyeing and printing hydroxy group or nitrogen-containing organic substrates, especially paper, leather and cellulosic textile materials; the fastness properties of the obtained dyeings and prints on textile material comprising cellulose fibers may be further improved by after-treating the dyed or printed substrate with a special fixing agent.
摘要:
A process for dyeing paper which comprises the use of dyes of the formula ##STR1## wherein R is hydrogen, hydroxyl or amino, X is the azoxy or azo group, and n is 1 or 2, and the bonds of the complexing oxygen atom in the .alpha.-position and of the azo group in the .beta.-position at the naphthalene nuclei are mutually interchangeable. Dyeings of good wetfastness and lightfastness are obtained.
摘要:
Disazo and polyazo compounds of the formula ##STR1## wherein each A is independently ##STR2## andeach R.sub.1 and the ##STR3## radical to which it is attached, taken together, independently, are ##STR4## wherein ring B may be substituted by one substituent selected from halogen, C.sub.1-4 alkyl and C.sub.1-4 alkoxy, and each R.sub.3 is independently C.sub.1-4 alkyl, orwherein the ** denotes the carbon atom attached to X, or each A, R.sub.3 and the ##STR5## radical to which they are attached, taken together, independently, are each R.sub.1 and the ##STR6## radical to which it is attached, taken together, independently, are the radical of an aromatic carbocyclic or heterocyclic coupling component, ##STR7## wherein each R.sub.21 is independently halo, C.sub.1-4 alkyl or C.sub.1-4 alkoxy,p is 0, 1 or 2,the * denotes the carbon atom attached to the --N.dbd.N-- radical, andthe ** denotes the carbon atom attached to X,eachA.sub.1 and A.sub.2 taken together are --O--Me--O--, wherein Me is copper, cobalt, iron, nickel, manganese or zinc, oreachA.sub.1 is hydroxy, andeachA.sub.2 is independently hydrogen, hydroxy or C.sub.1-4 alkoxy,X is a direct bond or a bridging radical,eachY is independently a direct bond, C.sub.1-4 alkylene, --CO--NH--(CH.sub.2).sub.m -***, --NH--CO--(CH.sub.2).sub.m *** or --SO.sub.2 --NR.sub.4 --(CH.sub.2).sub.m -***, wherein R.sub.4 is hydrogen or C.sub.1-4 alkyl,m is 1, 2, 3 or 4, and the *** denotes the carbon atom attached to the Z group, each Z is independently ##STR8## wherein A.sup..crclbar. is a non-chromophoric anion,m is 1, 2, 3 or 4, andp is 0, 1 or 2, andn is at least 2,with the provisos that (i) the compound is free of sulfo groups, and (ii) when the compound is in metal-free form, each A, R.sub.3 and the ##STR9## radical to which they are attached form a group of formula (b) and each R.sub.1 and the ##STR10## radical to which it is attached together form a 1-phenylpyrazole group the phenyl ring of which is substituted by one --Y--Z group, which compounds are useful for dyeing and printing paper, leather, textile materials comprising natural or regenerated cellulose (for example, cotton, mercerized cotton, alkali treated cotton, hemp, sisal, jute and flax) and fibers, yarns and textile materials comprising polyamide or polyester modified to contain acid groups.
摘要:
A method of directly producing copperized azo-dyestuffs of predetermined inorganic salt content is disclosed wherein an ortho, ortho'-dihydroxyazo-dyestuff is reacted with about one molar equivalent of a copper (II) compound consisting of from 1.0 to 0.1 molar equivalent of a non-salt-forming copper compound selected from CuCO.sub.3.Cu(OH).sub.2, 2CuCO.sub.3.Cu(OH).sub.2, Cu(OH).sub.2, CuO and mixtures thereof, and correspondingly from 0 to 0.9 molar equivalent of a salt-forming copper (II) compound selected from CuSO.sub.4, CuCl.sub.2 and Cu(NO.sub.3).sub.2. The disclosed method provides standard strength copperized dyestuff compositions at increased yields and without the need to precipitate the product from the reaction solution.
摘要:
Compounds of the formula ##STR1## in which A--X-- is the radical of a diazo component,X-- is ortho to the azo group and is a metallizable substituent or a substituent convertible to a metallizable group,Y is --OH or --NH.sub.2,Z is methyl or carboxy,R is hydrogen, halogen, methyl or sulpho,andB is the radical of a coupling component of the heterocyclic, acyclic active methylene or monocyclic benzene series, which coupling component of the monocyclic benzene series contains an amino and/or hydroxy group which groups may be alkylated or acylated, and--N.dbd.N--B is bound to the 3- or 4-position of ring D,which compounds contain at least one water-solubilizing group,and metal complexes thereof, with the proviso that when the compounds are unmetallized, B is other than amonocyclic benzene coupling component radical. The metal complexes are useful as dyes for the dyeing and printing of anionic dyeable.