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    METHOD FOR UTILIZING GAS RESERVES WITH LOW METHANE CONCENTRATIONS AND HIGH INERT GAS CONCENTRATIONS FOR FUELING GAS TURBINES
    1.
    发明申请
    METHOD FOR UTILIZING GAS RESERVES WITH LOW METHANE CONCENTRATIONS AND HIGH INERT GAS CONCENTRATIONS FOR FUELING GAS TURBINES 审中-公开
    利用低甲烷浓度和燃料气体涡轮机高精度气体浓度的气体储存方法

    公开(公告)号：WO2001042400A1

    公开(公告)日：2001-06-14

    申请号：PCT/US2000/033705

    申请日：2000-12-13

    Applicant: EXXON CHEMICAL PATENTS INC.

    Inventor： MITTRICKER, Frank, F. ,  VICTORY, Donald, J.

    IPC: C10L3/08

    CPC classification number: F25J3/0209 ,  C10L3/06 ,  C10L3/08 ,  F02C3/22 ,  F25J3/0233 ,  F25J3/0266 ,  F25J2200/02 ,  F25J2200/70 ,  F25J2270/90 ,  Y02C10/12

    Abstract: The invention is directed to a method of fueling gas turbines from natural gas reserves with relatively low methane concentrations. The invention uses such reserves to generate electric power. The invention permits the use of these reserves at significantly lower cost than by producing pipeline natural gas to fuel gas turbines to generate electric power. These reserves currently generally are used only after the removal of impurities to produce pipeline natural gas quality turbine fuel. The latter current technology is capital intensive, and at current natural gas prices, economically unattractive. The process of the invention can remove the impurities from the gas from the natural gas reserve necessary for protection of the environment, and leaves inert gasses in the fuel in an amount which will increase the output of a gas turbine for the generation of power by about 5 to about 20 %.

    Abstract translation: 本发明涉及一种从具有较低甲烷浓度的天然气储备燃料燃气轮机的方法。 本发明使用这种储备来产生电力。 本发明允许以比通过向燃料燃气轮机生产管道天然气以产生电力的成本低得多地使用这些储备。 这些储量目前一般仅在清除杂质后才能使用，以生产管道天然气质量的涡轮燃料。 后者目前的技术是资本密集型的​​，目前的天然气价格在经济上没有吸引力。 本发明的方法可以从保护环境所需的天然气储备中除去气体中的杂质，并将燃料中的惰性气体以一定的量使燃气涡轮机的输出增加约一 5至约20％。

    HYDROCARBON FUEL COMPOSITION CONTAINING AN ESTER
    2.
    发明申请
    HYDROCARBON FUEL COMPOSITION CONTAINING AN ESTER 审中-公开
    含有ESTER的油料燃料组合物

    公开(公告)号：WO0107540A2

    公开(公告)日：2001-02-01

    申请号：PCT/US0019894

    申请日：2000-07-20

    Applicant: EXXON CHEMICAL PATENTS INC

    Inventor： SCHLOSBERG RICHARD ,  YEZRIELEV ALBERT I

    IPC: C10L1/02

    CPC classification number: C10L1/023

    Abstract: This invention relates to the use of esters with low water solubility as oxygenates in gasoline fuels. This invention relates to a gasoline fuel, comprising an ester and butane, wherein the ester contains 5 to 14 carbon atoms. This invention also relates to using a low water solubility ester as an oxygenate in automotive gasoline used in internal combustion engines. Additionally, the invention provides a gasoline fuel, comprising an ester, wherein the ester has a water solubility of less than about 15,000 mg/L at 20 DEG C, preferably less than about 6,500 mg/L at 20 DEG C and the fuel has an overall water solubility of less than about 5,000 mg/L at 20 DEG C.

    Abstract translation: 本发明涉及在汽油燃料中使用水溶性低的酯作为含氧化合物。 本发明涉及包含酯和丁烷的汽油燃料，其中酯含有5至14个碳原子。 本发明还涉及在内燃机中使用的汽车汽油中使用低水溶性酯作为含氧化合物。 另外，本发明提供了一种包含酯的汽油燃料，其中酯在20℃下的水溶解度小于约15,000mg / L，优选在20℃时小于约6500mg / L，并且燃料具有 总体水溶性在20℃下小于约5,000mg / L

    PROCESS FOR ADJUSTING WVTR AND OTHER PROPERTIES OF A POLYOLEFIN FILM
    3.
    发明申请
    PROCESS FOR ADJUSTING WVTR AND OTHER PROPERTIES OF A POLYOLEFIN FILM 审中-公开
    调整WVTR和其他性质的多孔薄膜的方法

    公开(公告)号：WO0069615A3

    公开(公告)日：2001-02-01

    申请号：PCT/US0013287

    申请日：2000-05-15

    Applicant: EXXON CHEMICAL PATENTS INC

    Inventor： BRADY KEVIN A ,  MACKAY JOHN H

    IPC: A61F13/15 ,  B29C55/18 ,  C08J5/18 ,  C08K3/00

    CPC classification number: A61F13/51462 ,  A61F13/51478 ,  B29C55/18 ,  B29K2023/00 ,  B29K2023/083 ,  B29K2105/04 ,  B29K2105/16 ,  B29K2223/00 ,  B29K2995/0068 ,  C08J5/18 ,  C08J2323/12 ,  C08K3/013 ,  Y10T428/24273 ,  Y10T428/24355 ,  Y10T428/31855 ,  Y10T442/3854 ,  Y10T442/674 ,  C08L23/12

    Abstract: A process for rendering films, film composites, and articles made therefrom less resistant to passage of water vapor by passing a filled precursor film (10) or film composite through the nip of interdigitating grooved rollers (24, 25). The films (10) or film composites are generally formed using a precursor film (10) of a film forming polyolefin or polyolefin blend, with a relatively high filler loading and optionally an elastomer. A process is disclosed for making diapers or other disposable items where a relatively high water vapor is coupled with a resistance to liquid strikethrough. In one embodiment of the invention, the interdigitating grooved rollers (24, 25) are maintained in a temperature range of from about 91 DEG F to about 159 DEG F.

    Abstract translation: 通过使填充的前体膜（10）或膜复合物通过交错的带槽辊（24,25）的辊隙，使膜，膜复合材料和由其制成的制品对水蒸汽的通过不那么耐受。 膜（10）或膜复合材料通常使用成膜聚烯烃或聚烯烃共混物的前体膜（10）形成，具有相对高的填料负载量和任选的弹性体。 公开了一种用于制造尿布或其它一次性物品的方法，其中相对较高的水蒸汽与耐液体穿透线结合。 在本发明的一个实施例中，叉指沟槽辊（24,25）保持在约91°F至约159°F的温度范围内。

    ELASTOMERIC POLYMER VEHICLE PARTS HAVING IMPROVED LOW-TEMPERATURE COMPRESSION SET
    4.
    发明申请
    ELASTOMERIC POLYMER VEHICLE PARTS HAVING IMPROVED LOW-TEMPERATURE COMPRESSION SET 审中-公开
    具有改进的低温压缩设备的弹性聚合物车辆部件

    公开(公告)号：WO0022015A9

    公开(公告)日：2000-10-12

    申请号：PCT/US9922091

    申请日：1999-09-23

    Applicant: EXXON CHEMICAL PATENTS INC

    Inventor： LIOTTA RON ,  RAVISHANKAR PERIAGARAM S

    IPC: C08J5/00 ,  C08F4/659 ,  C08F10/00 ,  C08F210/18 ,  C08L23/16 ,  F16G5/04 ,  F16G5/00

    CPC classification number: F16G5/04 ,  C08F4/65908 ,  C08F10/00 ,  C08F210/18 ,  C08L23/16 ,  C08F4/65927 ,  C08F4/68 ,  C08F210/06 ,  C08F2500/25 ,  C08F2500/17

    Abstract: Motor vehicle parts based on an ethylene, alpha-olefin, diene monomer elastomeric polymers exhibit excellent low temperature compression set. Previously, such compression set performance in the amorphous region was believed to be non-responsive to ethylene content once the amorphous region was reached. However, within certain ranges, ethylene content has been shown to have an effect on low temperature compression set even in the amorphous region. These motor vehicle parts are particularly useful where extremes of ambient temperatures maybe incurred. In a preferred embodiment, the invention is a vehicle part, such a brake part or belt including an ethylene, alpha -olefin, diene elastomeric polymer. The elastomeric polymer has a low ethylene content, and the vehicle part made from a compound based on the elastomeric polymer will have improved low temperature compression set. The vehicle part comprises the elastomeric polymer where the polymer has ethylene present in the range of from 50-60 mole percent, ethyldiene norbornene present in the range of from 0.2-5 mole percent and an alpha -olefin, selected from propylene, hexene-1 and octene-1, where the alpha -olefin makes up the remainder of the elastomeric polymer. The ethylene composition distribution of the elastomeric polymer is such that the ethylene in 90 % of the polymer fractions varies by no more than +/- 4 % by weight. The Mw/Mn will be in the range of 2-4, the inherent viscosity in the range of 1.2-3.2 and the Mooney Viscosity (1+4) @ 125 DEG C in the range of from 10-80. The vehicle part will have an instantaneous compression set at -40 DEG C, less than 80 %.

    Abstract translation: 基于乙烯，α-烯烃，二烯单体弹性体聚合物的汽车零件表现出优异的低温压缩变定。 以前，一旦达到无定形区域，认为无定形区域中的这种压缩永久变形性能对乙烯含量无响应。 然而，在一定的范围内，即使在非晶区域，乙烯含量也显示出对低温压缩变定具有影响。 这些机动车辆部件在可能发生极端环境温度的情况下特别有用。 在一个优选的实施方案中，本发明是车辆部件，例如包括乙烯，α-烯烃，二烯弹性体聚合物的制动部件或带。 弹性体聚合物具有低的乙烯含量，并且由基于弹性体聚合物的化合物制成的载体部分将具有改进的低温压缩永久变形。 载体部分包含弹性体聚合物，其中聚合物的乙烯含量为50-60％（摩尔），乙二烯降冰片烯的含量为0.2-5％（摩尔），α-烯烃选自丙烯，己烯-1 和辛烯-1，其中α-烯烃构成弹性体聚合物的剩余部分。 弹性体聚合物的乙烯组成分布使得90％聚合物部分中的乙烯变化不超过+/- 4重量％。 Mw / Mn在2-4的范围内，特性粘度在1.2-3.2范围内，125℃时的门尼粘度（1 + 4）在10-80的范围内。 车辆部件将具有-40℃的瞬时压缩率，小于80％。

    PROCESS FOR MAKING AROMATIC ALDEHYDES
    5.
    发明申请
    PROCESS FOR MAKING AROMATIC ALDEHYDES 审中-公开
    制备芳香醛的方法

    公开(公告)号：WO0015593A3

    公开(公告)日：2000-07-20

    申请号：PCT/US9920647

    申请日：1999-09-10

    Applicant: EXXON CHEMICAL PATENTS INC

    Inventor： SALEH RAMZI YANNI ,  BECKER CHRIS L ,  MICHAELSON ROBERT C ,  SCHLOSBERG RICHARD H

    IPC: C07D493/04 ,  C07B61/00 ,  C07C7/148 ,  C07C45/49 ,  C07C45/82 ,  C07C47/542 ,  C07C51/235 ,  C07C51/265 ,  C07C63/16 ,  C07C63/26 ,  C07C63/307

    CPC classification number: C07C47/542 ,  C07C7/14858 ,  C07C45/49 ,  C07C45/82 ,  C07C51/235 ,  C07C51/265 ,  C07C63/16 ,  C07C63/26 ,  C07C63/307 ,  C07C15/08

    Abstract: Alkyl aromatic compounds are converted to alkyl aromatic aldehydes by a carbonylation reaction. The carbonylation catalyst can be a high boiling point carbonylation catalyst which allows for the separation of the aldehyde product by selective volatilization. Alternatively, the carbonylation catalyst can be selected from perfluoroalkyl sulfonic acids having 2 to 18 carbon atoms, perfluoroether sulfonic acids having 2 to 18 carbon atoms, BF3.(ROH)x wherein R represents CH3 or H and X is a number within the range of from 0.2 to 2, GaBr3, GaCl3, TaF5, NbF5, and NbBr5, with the proviso that when the catalyst is TaF5, NbF5, or NbBr5, then the reaction takes place in the absence of added HF. Preferably, all of the carbonylation reactions take place in the absence of added HF. The alkyl aromatic aldehydes can be oxidized to form an aromatic acid. A mixed xylene feed stock can be converted to a mixture of diemthylbenzaldehydes and then oxidized to form trimellitic acid without the need to separate the xylene or dimethylbenzaldehyde isomers.

    Abstract translation: 烷基芳族化合物通过羰基化反应转化成烷基芳族醛。 羰基化催化剂可以是高沸点羰基化催化剂，其允许通过选择性挥发来分离醛产物。 或者，羰基化催化剂可以选自具有2至18个碳原子的全氟烷基磺酸，具有2至18个碳原子的全氟醚磺酸，BF 3。（ROH）x其中R表示CH 3或H，X是在 0.2至2，GaBr 3，GaCl 3，TaF 5，NbF 5和NbBr 5，条件是当催化剂为TaF5，NbF5或NbBr5时，则在不加入HF的情况下进行反应。 优选地，所有的羰基化反应都在不加入HF的情况下进行。 烷基芳族醛可被氧化形成芳族酸。 混合的二甲苯原料可以转化为二乙基苯甲醛的混合物，然后氧化形成偏苯三酸，而不需要分离二甲苯或二甲基苯甲醛异构体。

    ETHYLENE COPOLYMERIZATION PROCESS
    6.
    发明申请
    ETHYLENE COPOLYMERIZATION PROCESS 审中-公开
    乙烯共聚工艺

    公开(公告)号：WO9941294B1

    公开(公告)日：1999-09-23

    申请号：PCT/US9903264

    申请日：1999-02-17

    Applicant: EXXON CHEMICAL PATENTS INC

    Inventor： SCHIFFINO RINALDO S ,  CROWTHER DONNA J

    IPC: C08F2/06 ,  C08F4/645 ,  C08F4/659 ,  C08F4/6592 ,  C08F210/18

    CPC classification number: C08F210/18 ,  C08F4/65908 ,  C08F4/65912 ,  Y10S526/943 ,  C08F2/06 ,  C08F4/65927 ,  C08F210/06 ,  C08F236/20 ,  C08F2500/25 ,  C08F2500/08 ,  C08F2500/04 ,  C08F2500/03

    Abstract: This invention is a solution process for the preparation of ethylene- alpha -olefin-diolefin copolymers comprising contacting ethylene, one or more a-olefin monomer, and one or more cyclic diene monomer, with a catalyst composition comprising a bridged, bis(cyclopentadienyl) zirconium compound having an unsubstituted cyclopentadienyl ligand, a multiply substituted cyclopentadienyl ligand, said ligands bridged by a covalent bridging group containing one or more Group 14 element, and two uninegative, activation reactive ligands and a catalyst activator compound. The invention process exhibits high catalyst activity, high comonomer incorporation and high diene monomer conversion rates and is particularly suitable for the preparation of elastomeric ethylene-propylene or ethylene-propylene-diene monomer elastomers.

    Abstract translation: 本发明是制备乙烯-α-烯烃 - 二烯烃共聚物的溶液方法，该方法包括使乙烯，一种或多种α-烯烃单体和一种或多种环状二烯单体与催化剂组合物接触，所述催化剂组合物包含桥接的双（环戊二烯基） 具有未取代的环戊二烯基配体的锆化合物，多取代的环戊二烯基配体，所述配体通过含有一个或多个第14族元素的共价桥连基团和两个单阴性的活化反应性配体和催化剂活化剂化合物桥接。 本发明方法表现出高催化剂活性，高共聚单体结合和高二烯单体转化率，并且特别适用于制备弹性体乙烯 - 丙烯或乙烯 - 丙烯 - 二烯单体弹性体。

    PROCESS FOR SELECTIVELY SEPARATING HYDROGEN, OR BOTH HYDROGEN AND CARBON MONOXIDE FROM OLEFINIC HYDROCARBONS
    7.
    发明申请
    PROCESS FOR SELECTIVELY SEPARATING HYDROGEN, OR BOTH HYDROGEN AND CARBON MONOXIDE FROM OLEFINIC HYDROCARBONS 审中-公开
    氢氧化氢，二氧化碳和二氧化碳的选择性分离方法

    公开(公告)号：WO1998029368A1

    公开(公告)日：1998-07-09

    申请号：PCT/US1997023875

    申请日：1997-12-31

    Applicant: EXXON CHEMICAL PATENTS INC.

    Inventor： EXXON CHEMICAL PATENTS INC. ,  VAUGHN, Stephen, N. ,  OU, John, D. ,  DANIEL, Lawrence, G.

    IPC: C07C07/148

    CPC classification number: B01D53/8671 ,  B01D53/864 ,  B01D53/869 ,  B01D2257/108 ,  B01D2257/504 ,  C07C7/14816 ,  Y02P20/152 ,  C07C11/00

    Abstract: A process for the separation, and removal, of hydrogen, or both hydrogen and carbon monoxide, from a mixture of these gases with olefinic hydrocarbons. In one embodiment, a mixture constituted of hydrogen and one or more reactive unsaturated hydrocarbons is contacted with oxygen or an oxygen-containing gas, over a catalyst at reaction conditions sufficient to oxidize the hydrogen component of the mixture to form water, while suppressing reaction of the reactive unsaturated hydrocarbon. In a second embodiment, there is included a two-reaction-zone series wherein effluent from the first reaction zone, wherein the mixture includes hydrogen, carbon monoxide and at least one reactive unsaturated hydrocarbon, is contacted with oxygen or an oxygen-containing gas, and reacted over an oxidation catalyst at conditions sufficient to oxidize the carbon monoxide component of the mixture to form carbon dioxide and suppress hydrogenation of the reactive unsaturated hydrocarbons. In a third embodiment, there is included a three-reaction-zone series wherein effluent from the second reaction zone, wherein the mixture includes carbon monoxide, water, and at least one reactive unsaturated hydrocarbon, is reacted over a water-gas-shift and hydrogenation catalyst at conditions sufficient to react carbon monoxide component of the mixture to form carbon dioxide and hydrogen, and hydrogenate said reactive unsaturated hydrocarbon with the resulting hydrogen. In each embodiment, reactive unsaturated hydrocarbons denuded of hydrogen, or both hydrogen and carbon monoxide are recovered.

    Abstract translation: 从这些气体与烯烃的混合物中分离和除去氢气或氢气和一氧化碳两者的方法。 在一个实施方案中，将由氢和一种或多种反应性不饱和烃组成的混合物与氧气或含氧气体在催化剂上接触，反应条件足以氧化混合物的氢组分以形成水，同时抑制 反应性不饱和烃。 在第二实施方案中，包括双反应区系列，其中来自第一反应区的流出物，其中混合物包括氢气，一氧化碳和至少一种反应性不饱和烃与氧气或含氧气体接触， 并在足以氧化混合物的一氧化碳组分以形成二氧化碳并抑制反应性不饱和烃氢化的条件下在氧化催化剂上反应。 在第三实施方案中，包括三反应区系列，其中来自第二反应区的流出物，其中混合物包括一氧化碳，水和至少一种反应性不饱和烃，通过水煤气变换和 氢化催化剂在足以使混合物的一氧化碳组分反应形成二氧化碳和氢气的条件下，并将所述反应性不饱和烃与所得氢气氢化。 在每个实施方案中，回收了被解释为氢或氢和一氧化碳的反应性不饱和烃。

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