Abstract:
Nanoscale particles, particle coatings/particle arrays and corresponding consolidated material are described based on an ability to vary the composition involving a wide range of metal and/or metalloid elements and corresponding compositions. In particular, metalloid oxides and metal-metalloid compositions are described in the form of improved nanoscale particles and coatings formed from the nanoscale particles. Compositions comprising rare earth metals and dopants/additives with rare earth metals are described. Complex compositions with a range of host compositions and dopants/additives can be formed using the approaches described herein. The particle coating can take the form of particle arrays that range from collections of disbursable primary particles to fused networks of primary particles forming channels that reflect the nanoscale of the primary particles. Suitable materials for optical applications are described along with some optical devices of interest.
Abstract:
High rate deposition methods comprise depositing a powder coating from a product flow. The product flow results from a chemical reaction within the flow. Some of the powder coatings consolidate under appropriate conditions into an optical coating. The substrate can have a first optical coating onto which the powder coating is placed. The resulting optical coating following consolidation can have a large index-of-refraction difference with the underlying first optical coating, high thickness and index-of-refraction uniformity across the substrate and high thickness and index-of-refraction uniformity between coatings formed on different substrates under equivalent conditions. In some embodiments, the deposition can result in a powder coating of at least about 100 nm in no more than about 30 minutes with a substrate having a surface area of at least about 25 square centimeters.
Abstract:
Nanoscale and submicron particles have been produced with polyatomic anions. The particles can be crystalline or amorphous. The particles are synthesized in a flowing reactor, preferably with an intense light beam driving the reaction. In preferred embodiments, the particles are highly uniform. Batteries can be formed from submicron and nanoscale lithium metal phosphates. Coatings also can be formed from the particles.
Abstract:
High rate deposition methods comprise depositing a powder coating from a product flow. The product flow results from a chemical reaction within the flow. Some of the powder coatings consolidate under appropriate conditions into an optical coating. The substrate can have a first optical coating onto which the powder coating is placed. The resulting optical coating following consolidation can have a large index-of-refraction difference with the underlying first optical coating, high thickness and index-of-refraction uniformity across the substrate and high thickness and index-of-refraction uniformity between coatings formed on different substrates under equivalent conditions. In some embodiments, the deposition can result in a powder coating of at least about 100 nm in no more than about 30 minutes with a substrate having a surface area of at least about 25 square centimeters.
Abstract:
Three dimensional optical structures are described that can have various integrations between optical devices within and between layers of the optical structure. Optical turning elements can provide optical pathways between layers of optical devices. Methods are described that provide for great versatility on contouring optical materials throughout the optical structure. Various new optical devices are enabled by the improved optical processing approaches.
Abstract:
Three dimensional optical structures are described that can have various integrations between optical devices within and between layers of the optical structure. Optical turning elements (500) can provide optical pathways between layers (502, 510) of optical devices. Methods are described that provide for great versatility on contouring optical materials throughout the optical structure. Various new optical devices are enabled by the improved optical processing approaches.
Abstract:
Nanoscale particles, particle coatings/particle arrays and corresponding consolidated material are described based on an ability to vary the composition involving a wide range of metal and/or metalloid elements and corresponding compositions. In particular, metalloid oxides and metal-metalloid compositions are described in the form of improved nanoscale particles and coatings formed from the nanoscale particles. Compositions comprising rare earth metals and dopants/additives with rare earth metals are described. Complex compositions with a range of host compositions and dopants/additives can be formed using the approaches described herein. The particle coating can take the form of particle arrays that range from collections of disbursable primary particles to fused networks of primary particles forming channels that reflect the nanoscale of the primary particles. Suitable materials for optical applications are described along with some optical devices of interest.
Abstract:
Nanoscale and submicron particles have been produced with polyatomic anions. The particles can be crystalline or amorphous. The particles are synthesized in a flowing reactor, preferably with an intense light beam driving the reaction. In preferred embodiments, the particles are highly uniform. Batteries can be formed from submicron and nanoscale lithium metal phosphates. Coatings also can be formed from the particles.
Abstract:
Light reactive deposition uses an intense light beam (684) to form particles that are directly coated onto a substrate (680) surface. In some embodiments, a coating apparatus comprising a noncircular reactant inlet (682), optical elements forming a light path (684), a first substrate (680), and a motor connected to the apparatus. The reactant inlet (682) defines a reaction zone with a product stream path continuing from the reaction zone. The substrate (680) intersects the product stream path. Also, operation of the motor moves the first substrate (680) relative to the product stream. Various broad methods are described for using light driven chemical reactions to produce efficiently highly uniform coatings.
Abstract:
Monolithic optical structures include a plurality of layer with each layer having an isolated optical pathway confined within a portion of the layer. The monolithic optical structure can be used as an optical fiber preform. Alternatively or additionally, the monolithic optical structure can include integrated optical circuits within one or more layers of the structure. Monolithic optical structures can be formed by performing multiple passes of a substrate through a flowing particle stream. The deposited particles form an optical material following consolidation. Flexible optical fibers include a plurality of independent light channels extending along the length of the optical fiber. The fibers can be pulled from an appropriate preform.