公开(公告)号：WO2013089859A1

公开(公告)日：2013-06-20

申请号：PCT/US2012/055298

申请日：2012-09-14

Applicant: UOP LLC ,  LEONARD, Laura E. ,  BOZZANO, Andrea G. ,  TOWLER, Gavin P.

Inventor： LEONARD, Laura E. ,  BOZZANO, Andrea G. ,  TOWLER, Gavin P.

IPC: C07C5/32 ,  C07C5/333 ,  C07C11/02

CPC classification number: C07C5/333 ,  C07C11/06 ,  C07C11/08 ,  C07C11/10 ,  C07C11/02 ,  C07C11/12

Abstract: A hydrocarbon dehydrogenation process includes providing the hydrocarbon feed to a reactor. The hydrocarbon feed includes at least one hydrocarbon selected from light paraffins, heavy paraffins, or combinations thereof. The process further includes introducing an inert diluent into the feed stream, contacting the feed stream and the inert diluent with a catalyst in the reactor, and flowing an effluent stream out of the reactor.

Abstract translation: 烃脱氢方法包括将烃进料提供到反应器。 烃原料包括至少一种选自轻链烷烃，重链烷烃或其组合的烃。 该方法还包括将惰性稀释剂引入进料流中，使进料流和惰性稀释剂与反应器中的催化剂接触，并将流出物流流出反应器。

公开(公告)号：WO2013043279A1

公开(公告)日：2013-03-28

申请号：PCT/US2012/050747

申请日：2012-08-14

Applicant: UOP LLC ,  BOZZANO, Andrea G. ,  GRIFFITHS, Matthew James ,  ANUMAKONDA, Amarendra

Inventor： BOZZANO, Andrea G. ,  GRIFFITHS, Matthew James ,  ANUMAKONDA, Amarendra

IPC: C07C2/64 ,  C07C15/073 ,  C10G3/00

CPC classification number: C07C2/66 ,  C01B3/26 ,  C10G3/00 ,  C10G3/50 ,  C10G9/00 ,  C10G29/205 ,  C10G45/32 ,  C10G57/005 ,  C10G69/00 ,  C10G69/123 ,  C10G69/126 ,  C10G69/14 ,  C10G2300/1014 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/08 ,  Y02E50/13 ,  Y02P30/20 ,  C07C15/107

Abstract: Embodiments of methods for co-production of linear alkylbenzene and biofuel from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form a stream comprising paraffins. A first portion of the paraffins are dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product. A second portion of the paraffins is processed to form biofuel.

Abstract translation: 提供了从天然油共生产直链烷基苯和生物燃料的方法的实施方案。 一种方法包括使天然油脱氧以形成包含石蜡的流的步骤。 将第一部分链烷烃脱氢以提供单烯烃。 然后，在烷基化条件下用单烯烃烷基化苯以提供包含烷基苯和苯的烷基化流出物。 此后，分离烷基苯以提供烷基苯产物。 处理第二部分石蜡以形成生物燃料。

公开(公告)号：WO2012064524A3

公开(公告)日：2012-08-30

申请号：PCT/US2011058254

申请日：2011-10-28

Applicant: UOP LLC ,  BOZZANO ANDREA G ,  EIZENGA DONALD ,  NORTON RALPH CHARLES

Inventor： BOZZANO ANDREA G ,  EIZENGA DONALD ,  NORTON RALPH CHARLES

IPC: C10G65/04 ,  C10G3/00 ,  C10G45/00

CPC classification number: C10L1/02 ,  C10G3/42 ,  C10G3/50 ,  C10G45/02 ,  C10G69/02 ,  C10G2300/1011 ,  C10G2300/1037 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/4018 ,  C10G2300/4081 ,  Y02E50/13 ,  Y02P30/20

Abstract: Methods for co-processing a biorenewable feedstock and a petroleum distillate feedstock are provided. The petroleum distillate feedstock containing sulfur is reacted with hydrogen gas in the presence of a hydrotreating catalyst thereby forming an effluent mixture comprising hydrogen sulfide. A combined feed comprising the effluent mixture, optionally a recycle liquid, and the biorenewable feedstock is contacted with hydrogen gas in a reaction zone with a deoxygenation catalyst under reaction conditions to provide a reaction product comprising a hydrocarbon fraction. The combined feed comprises greater than 50 weight percent biorenewable feedstock.

Abstract translation: 提供了共生处理生物可再生原料和石油馏分原料的方法。 含硫的石油馏出物原料在加氢处理催化剂存在下与氢气反应，由此形成包含硫化氢的流出物混合物。 包含流出物混合物，任选的再循环液体和生物可再生原料的组合原料在反应区与脱氧催化剂在反应条件下与氢气接触以提供包含烃馏分的反应产物。 组合进料包含大于50重量％的生物可再生原料。

公开(公告)号：WO2012021341A3

公开(公告)日：2012-06-07

申请号：PCT/US2011046351

申请日：2011-08-03

Applicant: UOP LLC ,  MONTALBANO JOSEPH A ,  KRUPA STEVEN L ,  SENETAR JOHN J ,  GREGOR JOSEPH ,  BOZZANO ANDREA G ,  SANDHU GARY

Inventor： MONTALBANO JOSEPH A ,  KRUPA STEVEN L ,  SENETAR JOHN J ,  GREGOR JOSEPH ,  BOZZANO ANDREA G ,  SANDHU GARY

IPC: C07C2/86 ,  C07C1/20 ,  C07C4/06 ,  C07C11/08

CPC classification number: C07C41/06 ,  C07C1/20 ,  C07C4/02 ,  C07C4/04 ,  C07C5/03 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  Y02P30/42 ,  C07C43/046 ,  C07C11/02

Abstract: 1-butene is recovered as a purified product from an MTO synthesis and especially from an integrated MTO synthesis and hydrocarbon pyrolysis system in which the MTO system and its complementary olefin cracking reactor are combined with a hydrocarbon pyrolysis reactor in a way that facilitates the flexible production and recovery of olefins and other petrochemical products, particularly butene-1 and MTBE.

Abstract translation: 作为纯化产物从MTO合成中回收1-丁烯，特别是从集成的MTO合成和烃热解系统中回收，其中MTO系统及其互补烯烃裂解反应器以便于柔性生产的方式与烃热解反应器组合 并回收烯烃和其他石化产品，特别是丁烯-1和MTBE。

公开(公告)号：WO2008008597A3

公开(公告)日：2008-03-06

申请号：PCT/US2007071363

申请日：2007-06-15

Applicant: UOP LLC ,  BOZZANO ANDREA G ,  KALNES TOM N ,  STEVENS CARL J ,  POKLOP STEVEN M

Inventor： BOZZANO ANDREA G ,  KALNES TOM N ,  STEVENS CARL J ,  POKLOP STEVEN M

IPC: B01J8/00

CPC classification number: B01J8/0411 ,  B01J8/0278 ,  B01J8/0415 ,  B01J8/0419 ,  B01J8/082 ,  B01J8/085 ,  B01J8/125 ,  B01J2208/00256 ,  B01J2208/00274 ,  B01J2208/00371 ,  B01J2208/025 ,  B01J2219/00006 ,  B01J2219/0004 ,  Y10S585/921 ,  Y10S585/924

Abstract: The present invention provides a reactor system (10) having: (1) a plurality of reactors (12) connected in fluid flow communication and having at least one pair of reactors (12a,b) separated by an interstage position (33); (2) a line (25) for supplying a reactant feed stream separately to an inlet (21) of more than one of the plurality of reactors (12a,b); and (3) a diverter (30) in fluid communication with the interstage position (33) and capable of directing a first portion of a product stream (32a) exiting one reactor (12a) in said pair of reactors (12a,b) to a first location (40) and a second portion of the product flow stream to an inlet (21b) of another reactor (12b) in said pair of reactors (12a,b).

Abstract translation: 本发明提供了一种反应器系统（10），其具有：（1）流体流动连通地连接的多个反应器（12），并具有由级间位置（33）分开的至少一对反应器（12a，b）; （2）用于将反应物原料流分开供应到多个反应器（12a，b）中的多于一个反应器的入口（21）的管线（25）; 和（3）与级间位置（33）流体连通并且能够将离开所述一对反应器（12a，b）中的一个反应器（12a）的产品流（32a）的第一部分引导至分离器 产物流动流的第一位置（40）和第二部分到达所述一对反应器（12a，b）中的另一个反应器（12b）的入口（21b）。

公开(公告)号：WO2007079324A2

公开(公告)日：2007-07-12

申请号：PCT/US2006/061877

申请日：2006-12-11

Applicant: UOP LLC ,  MILLER, Lawrence, W. ,  MILLER, Sterling, T. ,  BOZZANO, Andrea, G.

Inventor： MILLER, Lawrence, W. ,  MILLER, Sterling, T. ,  BOZZANO, Andrea, G.

IPC: C07C1/00 ,  B01J8/00

CPC classification number: C07C11/06 ,  C07C1/20 ,  C07C11/04 ,  C10G2400/20 ,  Y02P30/42 ,  C07C11/02

Abstract: Processing schemes and arrangements are provided for producing light olefins from an oxygenate-containing feedstock and using methanol-water mixtures to recover oxygenates such as for further processing to form additional light olefins.

Abstract translation: 提供加工方案和布置用于从含氧化合物的原料生产轻质烯烃，并使用甲醇 - 水混合物回收含氧化合物，以进一步加工以形成另外的轻质烯烃。

公开(公告)号：WO2013012486A2

公开(公告)日：2013-01-24

申请号：PCT/US2012/041193

申请日：2012-06-07

Applicant: UOP LLC ,  MAJUMDER, Debarshi ,  SOHN, Stephen W. ,  GLOVER, Bryan K. ,  BOZZANO, Andrea G.

Inventor： MAJUMDER, Debarshi ,  SOHN, Stephen W. ,  GLOVER, Bryan K. ,  BOZZANO, Andrea G.

IPC: C07C2/04 ,  C07C5/10 ,  C07C9/00 ,  C07C2/64 ,  C07C15/073

CPC classification number: C07C6/04 ,  C07C2/06 ,  C07C2/64 ,  C07C5/32 ,  C07C303/06 ,  C10G50/00 ,  C10G69/126 ,  C07C11/02 ,  C07C11/10 ,  C07C11/107 ,  C07C15/107 ,  C07C309/31

Abstract: Processes for making C X to C Y olefins are provided. The processes include reacting a feedstock comprising C 5 and C 6 olefins under dimerization or oligomerization conditions to provide a dimerization or oligomerization product. The product is separated into a stream comprising unreacted C 5 and C 6 paraffins, a stream comprising C 10 to C X-1 olefins, and a stream comprising C X to C Y olefins, wherein X is at least 14 and Y is greater than X and less than or equal to 36.

Abstract translation: 提供了用于将C≡X取代为C≡Y烯烃的方法。 该方法包括在二聚或低聚条件下使包含C5和C6烯烃的原料反应以提供二聚或低聚产物。 将产物分离成包含未反应的C 5和C 6链烷烃的物流，包含C 10到C X-1的物流 烯烃和包含C≡X至C≡Y烯烃的物流，其中X至少为14并且Y大于X且小于或等于36

公开(公告)号：WO2012021341A2

公开(公告)日：2012-02-16

申请号：PCT/US2011/046351

申请日：2011-08-03

Applicant: UOP LLC ,  MONTALBANO, Joseph A. ,  KRUPA, Steven L. ,  SENETAR, John J. ,  GREGOR, Joseph ,  BOZZANO, Andrea G. ,  SANDHU, Gary

Inventor： MONTALBANO, Joseph A. ,  KRUPA, Steven L. ,  SENETAR, John J. ,  GREGOR, Joseph ,  BOZZANO, Andrea G. ,  SANDHU, Gary

IPC: C07C2/86 ,  C07C1/20 ,  C07C4/06 ,  C07C11/08

CPC classification number: C07C41/06 ,  C07C1/20 ,  C07C4/02 ,  C07C4/04 ,  C07C5/03 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  Y02P30/42 ,  C07C43/046 ,  C07C11/02

Abstract: 1-butene is recovered as a purified product from an MTO synthesis and especially from an integrated MTO synthesis and hydrocarbon pyrolysis system in which the MTO system and its complementary olefin cracking reactor are combined with a hydrocarbon pyrolysis reactor in a way that facilitates the flexible production and recovery of olefins and other petrochemical products, particularly butene-1 and MTBE.

Abstract translation: 从MTO合成，特别是从整合的MTO合成和烃热解系统中回收1-丁烯作为纯化产物，其中MTO系统及其互补烯烃裂化反应器与烃热解反应器 以便于灵活生产和回收烯烃和其他石化产品，特别是丁烯-1和MTBE。

公开(公告)号：WO2011146262A2

公开(公告)日：2011-11-24

申请号：PCT/US2011/035520

申请日：2011-05-06

Applicant: UOP LLC ,  SECHRIST, Paul A. ,  BOZZANO, Andrea G.

Inventor： SECHRIST, Paul A. ,  BOZZANO, Andrea G.

CPC classification number: C10B21/12 ,  B01D45/16 ,  B04C3/00 ,  B04C9/00 ,  C10B45/00 ,  C10B47/24 ,  C10B53/02 ,  C10B57/12 ,  C10G1/02 ,  C10G2300/1014 ,  Y02E50/14 ,  Y02P20/145 ,  Y02P30/20

Abstract: Processes for controlling afterburn in a reheater and loss of entrained solid particles in reheater flue gas are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium comprising combustible solid particles. The spent heat transfer medium is introduced into a fluidizing dense bed. The combustible solid particles of the spent heat transfer medium are combusted forming combustion product flue gas in a dilute phase above the fluidizing dense bed. The combustion product flue gas comprises flue gas and solid particles entrained therein. The solid particles are separated from the combustion product flue gas to form separated solid particles. At least a portion of the separated solid particles are returned to the fludizing dense bed.

Abstract translation: 提供了一种用于控制再加热器中的后燃烧和在再热器烟道气中夹带的固体颗粒的损失的方法。 使用形成热解产物的热传递介质和包含可燃固体颗粒的废传热介质来热解碳质生物质原料。 将用过的传热介质引入流化致密的床中。 废热传递介质的可燃固体颗粒在流化致密床上方的稀相中燃烧形成燃烧产物烟道气。 燃烧产物烟道气包括烟气和夹在其中的固体颗粒。 将固体颗粒与燃烧产物烟气分离以形成分离的固体颗粒。 分离的固体颗粒的至少一部分返回到凝结致密的床。

公开(公告)号：WO2011126792A2

公开(公告)日：2011-10-13

申请号：PCT/US2011/030137

申请日：2011-03-28

Applicant: UOP LLC ,  MARINANGELI, Richard E. ,  BOZZANO, Andrea G.

Inventor： MARINANGELI, Richard E. ,  BOZZANO, Andrea G.

IPC: C10G67/00 ,  C10G31/00 ,  C10G3/00 ,  C10L1/02 ,  B01F13/00

CPC classification number: C10G3/42 ,  C10G2300/205 ,  C10G2300/42 ,  C10L1/02 ,  C10L1/04 ,  Y02P30/20

Abstract: In the present invention, pyrolysis oil is processed in a well mixed or a back mixed reactor to prevent the plugging up of a reactor that otherwise occurs. The pyrolysis oil can then be further upgraded in a hydroprocessing reactor through use of an appropriate catalyst.

Abstract translation: 在本发明中，热解油在充分混合或反混合反应器中加工，以防止否则发生的反应器堵塞。 然后可以在加氢处理反应器中通过使用合适的催化剂进一步升级热解油。