公开(公告)号：WO2012045736A1

公开(公告)日：2012-04-12

申请号：PCT/EP2011/067303

申请日：2011-10-04

Applicant: BASF SE ,  NISHIMAE, Yuichi ,  KURA, Hisatoshi ,  KUNIMOTO, Kazuhiko ,  YAMAGAMI, Ryuhei ,  TANAKA, Keita

Inventor： NISHIMAE, Yuichi ,  KURA, Hisatoshi ,  KUNIMOTO, Kazuhiko ,  YAMAGAMI, Ryuhei ,  TANAKA, Keita

IPC: C07D209/86 ,  C07D409/06 ,  C07D405/12 ,  C07D409/12 ,  G03F7/031 ,  C08F2/46

CPC classification number: C07D209/86 ,  C07D403/04 ,  C07D405/12 ,  C07D409/06 ,  C07D409/12 ,  C08F2/50 ,  C09B55/003 ,  C09B57/00 ,  G03F7/0007 ,  G03F7/031 ,  G03F7/033 ,  G03F7/038 ,  G03F7/0384

Abstract: Compounds of the formula (I), wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and R 8 for example independently of each other are hydro- gen, C 1 -C 20 alkyl, (II), COR 16 or NO 2 , provided that at least one pair of R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , R 5 and R 6 , R 6 and R 7 , or R 7 and R 8 is (III); R 9 , R 10 , R 11 and R 12 for example independently of each other are hydrogen, C 1 -C 20 alkyl which optionally substituted; or R 9 , R 10 , R 11 , and R 12 independently of each other are unsubstituted or substituted phenyl; X is CO or a direct bond; R 13 is for example C 1 -C 20 alkyl which optionally is substituted, C 2 -C 12 alkenyl, C 4 - C 8 cycloalkenyl, C 2 -C 12 alkinyl, C 3 -C 10 cycloalkyl, phenyl or naphthyl both of which are optionally substituted; R 14 is for example hydrogen, C 3 -C 8 cycloalkyl, C 2 -C 5 alkenyl, C 1 -C 20 alkoxy, C 1 -C 20 alkyl, phenyl or naphthyl; R 15 is for example C 6 -C 20 aryl or C 5 -C 20 heteroaryl; R 16 is for example C 6 -C 20 aryl which is unsubstituted or substituted by one or more C 1 -C 20 alkoxy or C 1 -C 20 alkyl; are in particular suitable as photoinitiators for color filter applications.

Abstract translation: 式（I）的化合物，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7和R 8例如彼此独立地是氢，C 1 -C 20烷基，（II），COR 16或NO 2， 至少一对R1和R2，R2和R3，R3和R4，R5和R6，R6和R7，或R7和R8是（III）; R9，R10，R11和R12彼此独立地是氢，任选取代的C 1 -C 20烷基; 或R 9，R 10，R 11和R 12彼此独立地是未取代或取代的苯基; X是CO或直接键; R13是例如任选被取代的C 1 -C 20烷基，C 2 -C 12烯基，C 4 -C 8环烯基，C 2 -C 12炔基，C 3 -C 10环烷基，苯基或萘基，它们都是任选取代的; R 14是例如氢，C 3 -C 8环烷基，C 2 -C 5烯基，C 1 -C 20烷氧基，C 1 -C 20烷基，苯基或萘基; R 15例如是C 6 -C 20芳基或C 5 -C 20杂芳基; R 16是例如未被取代或被一个或多个C 1 -C 20烷氧基或C 1 -C 20烷基取代的C 6 -C 20芳基; 特别适用于用于滤色器应用的光引发剂。

公开(公告)号：WO2013083505A1

公开(公告)日：2013-06-13

申请号：PCT/EP2012/074190

申请日：2012-12-03

Applicant: BASF SE ,  NISHIMAE, Yuichi ,  KURA, Hisatoshi ,  KUNIMOTO, Kazuhiko ,  YAMAGAMI, Ryuhei ,  TANAKA, Keita

Inventor： NISHIMAE, Yuichi ,  KURA, Hisatoshi ,  KUNIMOTO, Kazuhiko ,  YAMAGAMI, Ryuhei ,  TANAKA, Keita

IPC: C07D209/80 ,  C07D403/12 ,  G03F7/004

CPC classification number: C07D209/80 ,  C07D209/86 ,  C07D403/12 ,  C07D409/04 ,  C07D409/14 ,  C08F2/50 ,  G02B5/201 ,  G03F7/0007 ,  G03F7/20

Abstract: Oxime ester compounds of formula (I), wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , and R 10 independently of each other are hydrogen, C 1 -C 20 alkyl, (A),COR 14 , NO 2 , or OR 15 ; provided that at least one of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , and R 10 is (A), and provided that at |east one of the remaining R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , and R 10 is COR 14 or NO 2 ; R 11 is for example C 1 -C 20 alkyl, M or (B); X and X 1 are for example a direct bond; R 12 and R' 12 are for example hydrogen or C 1 -C 20 alkyl; R 13 and R' 13 are for example C 6 -C 20 aryl or C 3 -C 20 heteroaryl; M is (X), (Y) or (Z); X 3 is O, S or NR 19 ; R 14 and R 15 are for example phenyl; R 20 , R 21 , R 22 , R 23 , R 24 , or R 25 for example are hydrogen, COR 14 , NO 2 , or (B); provided that at least two oxime ester groups are present in the molecule; are useful as photoinitiators.

Abstract translation: 式（I）的肟酯化合物，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9和R 10彼此独立地是氢，C 1 -C 20烷基，（A），COR 14，NO 2或 OR15; 条件是R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9和R 10中的至少一个是（A），并且条件是在剩余的R1，R2，R3，R4，R5 ，R6，R7，R8，R9和R10是COR14或NO2; R 11例如为C 1 -C 20烷基，M或（B）; X和X1例如是直接键; R 12和R 12如氢或C 1 -C 20烷基; R 13和R 13如C 6 -C 20芳基或C 3 -C 20杂芳基; M为（X），（Y）或（Z）; X3是O，S或NR19; R 14和R 15例如为苯基; R 20，R 21，R 22，R 23，R 24或R 25例如是氢，COR 14，NO 2或（B）; 条件是分子中存在至少两个肟酯基团; 作为光引发剂是有用的。

公开(公告)号：WO2012113829A1

公开(公告)日：2012-08-30

申请号：PCT/EP2012/053011

申请日：2012-02-22

Applicant: BASF SE ,  KUNIMOTO, Kazuhiko ,  KURA, Hisatoshi

Inventor： KUNIMOTO, Kazuhiko ,  KURA, Hisatoshi

IPC: C07C305/00 ,  C07C305/06 ,  C07C305/18 ,  C07C305/20 ,  C07C305/24 ,  C07C323/12 ,  C07C323/45 ,  C07C327/58 ,  C07C381/12 ,  C07D307/10 ,  C07D333/16 ,  C07D333/46 ,  C07D333/72 ,  C08G59/68

CPC classification number: C08G59/687 ,  C07C305/00 ,  C07C305/06 ,  C07C305/18 ,  C07C305/20 ,  C07C305/24 ,  C07C323/12 ,  C07C323/45 ,  C07C327/58 ,  C07C381/12 ,  C07C2601/14 ,  C07C2601/20 ,  C07D307/10 ,  C07D307/12 ,  C07D333/16 ,  C07D333/22 ,  C07D333/46 ,  C07D333/50 ,  C07D333/72 ,  C08L63/00

Abstract: The present invention relates to a heat-curable composition comprising (a) at least one compound which is capable of undergoing cationic polymerization; and (b) at least one sulfonium sulfate selected from compounds of the formulae Ia and Ib where Y n- is a monovalent or divalent anion selected from (1) where n, M, R 1 to R 10 are as defined in claim 1 and in the description. The present invention also relates to novel sulfonium sulfates of the formulae Ia and Ib, to a process for curing cationically polymerizable material and to the cured material obtained by said process.

Abstract translation: 本发明涉及一种可热固化组合物，其包含（a）至少一种能够进行阳离子聚合的化合物; 和（b）至少一种选自式Ia和Ib化合物的硫酸锍，其中Yn-是选自（1）中的一价或二价阴离子，其中n，M，R 1至R 10如权利要求1中所定义， 。 本发明还涉及式Ia和Ib的新型硫酸锍，用于固化阳离子可聚合材料的方法和通过所述方法获得的固化材料。

公开(公告)号：WO2012101245A1

公开(公告)日：2012-08-02

申请号：PCT/EP2012/051297

申请日：2012-01-27

Applicant: BASF SE ,  KUNIMOTO, Kazuhiko ,  SAMESHIMA, Kaori ,  MATSUOKA, Yuki ,  KURA, Hisatoshi

Inventor： KUNIMOTO, Kazuhiko ,  SAMESHIMA, Kaori ,  MATSUOKA, Yuki ,  KURA, Hisatoshi

IPC: C07C309/30 ,  C07C327/58 ,  C07D213/59 ,  C07D265/32 ,  C07D277/54 ,  C07D291/02 ,  C07D327/06 ,  H01L21/027

CPC classification number: G03F7/0007 ,  C07C309/00 ,  C07C309/30 ,  C07C309/67 ,  C07C309/73 ,  C07C327/58 ,  C07C327/60 ,  C07C2601/14 ,  C07C2602/42 ,  C07D213/59 ,  C07D213/78 ,  C07D265/32 ,  C07D277/54 ,  C07D279/12 ,  C07D291/02 ,  C07D295/04 ,  C07D307/10 ,  C07D309/08 ,  C07D327/06 ,  C08F220/10 ,  G02B5/201 ,  G02B5/223 ,  G03F7/027 ,  G03F7/028 ,  G03F7/029 ,  G03F7/031 ,  G03F7/032 ,  G03F7/322

Abstract: The present invention relates to a polymerizable composition comprising at least one ethylenically unsaturated, polymerizable compound and at least one oxime sulfonate compound of the formula (I) QA a B b C c where a is 0, 1, 2, 3, 4 or 6, b is 0, 1, 2, 3, 4 or 6, and c is 0, 1, 2, 3, 4 or 6, where the sum of a + b + c is 1, 2, 3, 4 or 6 where (A) is a group (B) is a group (C) is a group where # denotes the point of attachment to Q; X is S or NR 14 and Q, R 1 , R 2 , R 3 and R 14 are as defined in claim 1 and in the description. The present invention also relates to the use of the this composition, to novel oxime sulfonates and the use of the oxime sulfonates as thermal curing promoter.

Abstract translation: 本发明涉及包含至少一种烯属不饱和的可聚合化合物和至少一种式（I）QAaBbCc的肟磺酸酯化合物的可聚合组合物，其中a是0,1,2,3,4或6，b是0， 1，2，3，4或6，c为0,1,2,3,4或6，其中a + b + c的和为1,2,3,4或6，其中（A）为 组（B）是组（C）是其中＃表示与Q的连接点的组; X是S或NR14，Q，R1，R2，R3和R14如权利要求1和说明书中所定义。 本发明还涉及该组合物用于制备新型肟磺酸盐和使用肟磺酸盐作为热固化促进剂的用途。

公开(公告)号：WO2010108835A1

公开(公告)日：2010-09-30

申请号：PCT/EP2010/053468

申请日：2010-03-17

Applicant: BASF SE ,  KURA, Hisatoshi ,  SAMESHIMA, Kaori ,  KUNIMOTO, Kazuhiko ,  NESVADBA, Peter ,  OHWA, Masaki

Inventor： KURA, Hisatoshi ,  SAMESHIMA, Kaori ,  KUNIMOTO, Kazuhiko ,  NESVADBA, Peter ,  OHWA, Masaki

IPC: C08F265/02 ,  C08K5/32 ,  C08K5/3435 ,  C07D295/24 ,  G03F7/039

CPC classification number: G03F7/028 ,  C07D211/94 ,  C07D491/113 ,  C08F110/02 ,  C08F110/06 ,  C08F265/02 ,  C08K5/3435 ,  G03F7/0007 ,  G03F7/031 ,  G03F7/40 ,  C08L33/06

Abstract: The present invention relates to a radically polymerizable composition comprising a hydroxylamine ester used to manufacture color filters. The invention further relates to novel hydroxylamine esters. The invention further relates to the use of hydroxylamine esters in all liquid crystal display components requiring post-baking. The present invention relates to a radically polymerizable composition comprising: (a) at least one alkaline developable resin; (b) at least one acrylate monomer; (c) at least a photoinitiator; (d) at least one hydroxylamine ester compound of formula (I) wherein R a represents an acyl radical; one of R b and R c represents hydrogen and the other one represents a substituent; or R b and R c both represent hydrogen or identical or different substituents; or R b and R c together represent oxygen; or R b and R c together form a ring; R 1 - R 4 each represent C 1 -C 6 alkyl; and R 5 and R 6 each represent independently of one another hydrogen, C 1 -C 6 alkyl or C 6 -C 10 aryl; or R 5 and R 6 together represent oxygen.

Abstract translation: 本发明涉及一种可自由基聚合的组合物，其包含用于制造滤色器的羟胺酯。 本发明还涉及新的羟胺酯。 本发明还涉及在需要后烘烤的所有液晶显示组件中使用羟胺酯。 本发明涉及可自由基聚合的组合物，其包含：（a）至少一种碱性显影树脂; （b）至少一种丙烯酸酯单体; （c）至少一种光引发剂; （d）至少一种式（I）的羟胺酯化合物，其中R a表示酰基; Rb和Rc之一表示氢，另一个表示取代基; 或Rb和Rc都表示氢或相同或不同的取代基; 或Rb和Rc一起代表氧; 或Rb和Rc一起形成环; R 1 -R 4各自表示C 1 -C 6烷基; R 5和R 6各自独立地表示氢，C 1 -C 6烷基或C 6 -C 10芳基; 或R5和R6一起表示氧。

公开(公告)号：WO2006018405A1

公开(公告)日：2006-02-23

申请号：PCT/EP2005/053894

申请日：2005-08-08

Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. ,  TANABE, Junichi ,  KUNIMOTO, Kazuhiko ,  KURA, Hisatoshi ,  OKA, Hidetaka ,  OHWA, Masaki

Inventor： TANABE, Junichi ,  KUNIMOTO, Kazuhiko ,  KURA, Hisatoshi ,  OKA, Hidetaka ,  OHWA, Masaki

IPC: C07D209/86

CPC classification number: G03F7/031 ,  B33Y70/00 ,  C07D209/86 ,  C07D413/10

Abstract: Compounds of the formula (I), wherein R 1 , R 2 and R 10 independently of one another are C 1 -C 20 alkyl, phenyl, C 1 -C 12 alkylphenyl or phenyl-C 1 -C 6 alkyl; R 3 and R 4 independently of one another are hydrogen, C 1 -C 20 alkyl, NR 6 R 7 or SR 8 , provided that at least one of R 3 or R 4 is NR 6 R 7 or SR 8 ; R 5 is hydrogen or C 1 -C 20 alkyl; R 6 and R 7 independently of one another are C 1 -C 20 alkyl, or R 6 and R 7 together with the N-atom to which they are attached form a 5 or 6 membered ring, which optionally is interrupted by O, S or NR 9 and which optionally additionally is substituted by one or more C 1 -C 4 alkyl; R 8 is phenyl, biphenylyl, naphthyl, anthryl or phenanthryl, all of which optionally are substituted by one or more C 1 -C 4 alkyl; and R 9 is hydrogen, C 1 -C 20 alkyl, C 2 -C 4 hydroxyalkyl or phenyl; exhibit an unexpectedly good performance in photopolymerization reactions.

Abstract translation: 式（I）的化合物，其中R <

公开(公告)号：WO2002100903A1

公开(公告)日：2002-12-19

申请号：PCT/EP2002/006107

申请日：2002-06-04

Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. ,  KUNIMOTO, Kazuhiko ,  TANABE, Junichi ,  KURA, Hisatoshi ,  OKA, Hidetaka ,  OHWA, Masaki

Inventor： KUNIMOTO, Kazuhiko ,  TANABE, Junichi ,  KURA, Hisatoshi ,  OKA, Hidetaka ,  OHWA, Masaki

IPC: C08F2/50

CPC classification number: C08F2/50 ,  B33Y70/00 ,  C07C251/66 ,  G03F7/031

Abstract: Compounds of the formulae I, II, and III wherein R 1 is for example hydrogen, C 3 -C 8 cycloalkyl, C 1 -C 12 alkyl, phenyl unsubstituted or substituted; R 2 and R 2 ' for example are hydrogen, C 1 -C 20 alkyl, C 3 -C 8 cycloalkyl or phenyl, unsubstituted or substituted, or are (I) (I) or (I); Ar 1 is for example phenyl, optionally substituted by e.g. (CO)R 7 , (I)(D), (I)(E) and/or(I)(F); Ar 2 is for example phenylene, optionally substituted e.g. by (CO)R 7 , (D), (E)or (F); Ar 3 is for example phenyl; M 1 ,M 2 and M 3 are, for example, C 1 -C 20 alkylene; M 4 is for example direct bond, -O-, -S-, -Y-(C 1 -C 10 alkylene)-Y'-, optionally substituted;Y and Y' are for example a direct bond or O; R 7 is for example hydrogen, C 1 -C 20 alkyl or phenyl, optionally substituted; R 8 , R 9 , R 8 'and R 9 ' are for example hydrogen or C 1 -C 12 alkyl, exhibit an unexpectedly good performance in photopolymerization reactions.

Abstract translation: 式I，II和III的化合物，其中R 1是例如氢，C 3 -C 8环烷基，C 1 -C 12烷基，未取代或取代的苯基; R 2和R 2'例如是氢，C 1 -C 20烷基，C 3 -C 8环烷基或未取代或取代的苯基，或者是（I）（I）或（I）; Ar 1是例如苯基，任选地被例如苯基取代。 （CO）R7，（I）（D），（I）（E）和/或（I）（F）; Ar 2是例如亚苯基，任选被取代的例如亚苯基。 （CO）R7，（D），（E）或（F）; Ar 3例如是苯基; M1，M2和M3是例如C1-C20亚烷基; M4例如直接键合，-O - ， - S-，-Y-（C 1 -C 10亚烷基）-Y'-，任意取代; Y和Y'例如是直接键或O; R 7为例如氢，C 1 -C 20烷基或苯基，任选取代; R 8，R 9，R 8'和R 9'例如为氢或C 1 -C 12烷基，在光聚合反应中表现出出乎意料的良好性能。

公开(公告)号：WO2009109499A1

公开(公告)日：2009-09-11

申请号：PCT/EP2009/052243

申请日：2009-02-26

Applicant: BASF SE ,  KUNIMOTO, Kazuhiko ,  YAMAMOTO, Hiroshi ,  NAKAMICHI, Shinji ,  TAKAHASHI, Ryuichi ,  TANABE, Junichi

Inventor： KUNIMOTO, Kazuhiko ,  YAMAMOTO, Hiroshi ,  NAKAMICHI, Shinji ,  TAKAHASHI, Ryuichi ,  TANABE, Junichi

IPC: H01L51/00 ,  H01G9/20

CPC classification number: H01G9/2059 ,  H01G9/2031 ,  H01L51/0059 ,  H01L51/0064 ,  H01L51/0067 ,  Y02E10/542 ,  Y02E10/549

Abstract: The present invention pertains to an electrode layer comprising a porous film made of oxide semiconductor fine particles sensitized with certain methin dyes. Moreover the present invention pertains to a photoelectric conversion device comprising said electrode layer, a dye sensitized solar cell comprising said photoelectric conversion device and to novel methin dyes.

Abstract translation: 本发明涉及一种电极层，其包含由某些次甲基染料致敏的氧化物半导体微粒制成的多孔膜。 此外，本发明涉及包括所述电极层的光电转换装置，包含所述光电转换装置的染料敏化太阳能电池和新颖的次要染料。

公开(公告)号：WO2003022895A1

公开(公告)日：2003-03-20

申请号：PCT/EP2002/009782

申请日：2002-09-02

Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. ,  NESVADBA, Peter ,  KUNIMOTO, Kazuhiko

Inventor： NESVADBA, Peter ,  KUNIMOTO, Kazuhiko

IPC: C08F12/24

CPC classification number: C08F12/22 ,  C08F8/04

Abstract: The instant invention relates to a process for the preparation of hydroxy-vinyl-aromatic polymers in particular 4-hydroxystyrene polymers or copolymers by anionic or controlled radical polymerization of the respective monomer, wherein the hydroxy functionality is blocked with a protective group which is subsequently removed in a hydrogenation process. The resulting (co)polymers have a narrow polydispersity and are useful for manufacturing photoresists.

Abstract translation: 本发明涉及通过相应单体的阴离子或受控自由基聚合制备羟基乙烯基芳族聚合物，特别是4-羟基苯乙烯聚合物或共聚物的方法，其中羟基官能团被保护基团封闭，随后被除去 在加氢过程中。 所得（共）聚合物具有窄的多分散性，并且可用于制造光致抗蚀剂。

公开(公告)号：WO2005081239A1

公开(公告)日：2005-09-01

申请号：PCT/EP2005/050670

申请日：2005-02-16

Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. ,  TAKAHASHI, Ryuichi ,  KUNIMOTO, Kazuhiko ,  SUTTER, Peter ,  LEHMANN, Urs

Inventor： TAKAHASHI, Ryuichi ,  KUNIMOTO, Kazuhiko ,  SUTTER, Peter ,  LEHMANN, Urs

IPC: G11B7/24

CPC classification number: G11B7/246 ,  C07D277/46 ,  C09B23/04 ,  C09B55/009 ,  C09B57/10 ,  G11B7/2467 ,  G11B7/2472 ,  G11B7/2475 ,  G11B7/2478 ,  G11B7/2492 ,  G11B7/2533 ,  G11B7/2534 ,  G11B7/2535 ,  G11B7/259 ,  G11B2007/24612

Abstract: The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer comprising a compound of formula (I) or a tautomer thereof, wherein G 1 , G 2 and G 3 are each independently of the other A 1 , A 2 and A 3 are each independently of the other N(R 14 ),O, S or Se and A 4 is C(C 1 -C 5 aIkyl)2, C(C 4 -C 5 alkylene), N(R 14 ), O, S, Se, N=C(R 15 ) or CH=C(R 16 ); M 1 is an at least trivalent metal of groups 3 to 15 most preferred Co(III) or Cr(III); Q 1 , Q 2 and Q 3 are each independently of the other C(R 17 ) , N or P. Recording and playback are effected especially at a wavelength of from 350 to 500 nm, for example using a blue laser.

Abstract translation: 本发明涉及一种光记录介质，其包括基板，反射层和包含式（I）化合物或其互变异构体的记录层，其中G1，G2和G3各自独立地为A1，A2和A3分别为 各自独立地为N（R14），O，S或Se，A4为C（C1-C5烷基）2，C（C4-C5亚烷基），N（R14），O，S，Se，N = C（R15） 或CH = C（R 16）; M1是组3至15最优选Co（III）或Cr（III）的至少三价金属; Q1，Q2和Q3各自独立于另一个C（R17），N或P.例如使用蓝色激光器，特别是在350至500nm的波长下进行记录和回放。