PROCESS FOR PREPARING POROUS METAL-ORGANIC FRAMEWORK COMPOSED OF ZINC METHYLIMIDAZOLATE
    3.
    发明申请
    PROCESS FOR PREPARING POROUS METAL-ORGANIC FRAMEWORK COMPOSED OF ZINC METHYLIMIDAZOLATE 审中-公开
    制备金属有机骨架的方法

    公开(公告)号:WO2013005160A1

    公开(公告)日:2013-01-10

    申请号:PCT/IB2012/053368

    申请日:2012-07-03

    IPC分类号: C07D233/58 C07F3/06 B01J31/18

    摘要: Disclosed is a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is a zinc ion and the at least one at least bidentate organic compound is based on 2-methylimidazole, which comprises the steps (a) addition of a first water-based solution comprising zinc ions to a second water-based solution comprising 2-methylimidazole, with a suspension being formed after addition of the second solution; (b) addition of a third solution comprising a strong base to the suspension formed in step (a).

    摘要翻译: 公开了一种制备多孔金属 - 有机骨架的方法,所述多孔金属 - 有机骨架包含至少一种与至少一种金属离子配位的至少二齿有机化合物,其中所述至少一种金属离子是锌离子,并且所述至少一种至少二齿有机化合物 是基于2-甲基咪唑,其包括以下步骤:(a)在包含2-甲基咪唑的第二水性溶液中加入包含锌离子的第一水性溶液,在加入第二溶液后形成悬浮液; (b)向步骤(a)中形成的悬浮液中加入包含强碱的第三溶液。

    PROCESS FOR PREPARING POROUS METAL-ORGANIC FRAMEWORKS BASED ON ALUMINUM FUMARATE
    5.
    发明申请
    PROCESS FOR PREPARING POROUS METAL-ORGANIC FRAMEWORKS BASED ON ALUMINUM FUMARATE 审中-公开
    基于铝酸铝制备多孔金属有机框架的方法

    公开(公告)号:WO2012042410A1

    公开(公告)日:2012-04-05

    申请号:PCT/IB2011/053892

    申请日:2011-09-06

    IPC分类号: C07F5/06 B01J20/22

    CPC分类号: C07F5/069

    摘要: The present invention relates to a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is based on an aluminum ion and the at least one at least bidentate organic compound is based on fumaric acid, by reacting at least one aluminum compound with at least fumaric acid in an alkaline aqueous medium, optionally in the presence of at least one base, at a temperature in the range from 20°C to 100°C at an absolute pressure of not more than 2 bar for from 0.2 to 4 hours.

    摘要翻译: 本发明涉及一种制备多孔金属 - 有机骨架的方法,其包含与至少一种金属离子配位的至少一种至少二齿的有机化合物,其中所述至少一种金属离子基于铝离子,并且所述至少一种 至少二齿有机化合物是基于富马酸,在至少一种碱的存在下,在至少一种碱的存在下,使至少一种铝化合物与至少富马酸在碱性水性介质中反应,温度范围为20℃至 100℃,绝对压力不大于2巴,时间为0.2-4小时。