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    2,7-ARYL-9-SUBSTITUTED FLUORENES AND 9-SUBSTITUTED FLUORENE OLIGOMERS AND POLYMERS
    2.
    发明申请
    2,7-ARYL-9-SUBSTITUTED FLUORENES AND 9-SUBSTITUTED FLUORENE OLIGOMERS AND POLYMERS 审中-公开
    2,7-ARYL-9取代的荧光素和9取代的荧光低聚物和聚合物

    公开(公告)号：WO1997005184A1

    公开(公告)日：1997-02-13

    申请号：PCT/US1996012290

    申请日：1996-07-26

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  WOO, Edmund, P. ,  INBASEKARAN, Michael ,  SHIANG, William, R. ,  ROOF, Gordon, R.

    IPC: C08G61/10

    CPC classification number: H01L51/0043 ,  C07C17/2637 ,  C07C17/266 ,  C07C25/22 ,  C07C25/24 ,  C07C211/48 ,  C07C2602/44 ,  C07C2603/18 ,  C08G61/00 ,  C08G61/02 ,  C08G61/10 ,  C09B69/105 ,  C09B69/109 ,  C09K11/06 ,  C09K2211/1408 ,  C09K2211/1416 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0038 ,  H01L51/0039 ,  H01L51/0042 ,  H01L51/0052 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/007 ,  H01L51/0081 ,  H01L51/42 ,  H01L51/5012 ,  H01L2251/308 ,  Y10S428/917

    Abstract: The invention relates to 2,7-substituted-9-substituted fluorenes and 9-substituted fluorene oligomers and polymers. The fluorenes, oligomers and polymers are substituted at the 9-position with two hydrocarbyl moieties which may optionally contain one or more of sulfur, nitrogen, oxygen, phosphorous or silicon heteroatoms; a C5-20 ring structure formed with the 9-carbon on the fluorene ring or a C4-20 ring structure formed with the 9-carbon containing one or more heteroatoms of sulfur, nitrogen or oxygen; or a hydrocarbylidene moiety. In one embodiment, the fluorenes are substituted at the 2- and 7-positions with aryl moieties which may further be substituted with moieties which are capable of cross-linking or chain extension or a trialkylsiloxy moiety. The fluorene polymers and oligomers may be substituted at the 2- and 7'-positions. The monomer units of the fluorene oligomers and polymers are bound to one another at the 2- and 7'-positions. The 2,7'-aryl-9-substituted fluorene oligomers and polymers may be further reacted with one another to form higher molecular weight polymers by causing the optional moieties on the terminal 2,7'-aryl moieties, which are capable of cross-linking or chain extension, to undergo chain extension or cross-linking. Also disclosed are processes for preparing the disclosed compounds.

    Abstract translation: 本发明涉及2,7-取代的9-取代的芴和9-取代的芴低聚物和聚合物。 芴，低聚物和聚合物在9位被两个烃基部分取代，该烃基部分可任选地含有一个或多个硫，氮，氧，磷或硅杂原子; 由芴环上的9-碳形成的C5-20环结构或由含有一个或多个硫，氮或氧杂原子的9-碳形成的C 4-20环结构; 或亚烃基部分。 在一个实施方案中，芴在2-和7-位被芳基部分取代，芳基部分可进一步被能够交联或延伸的部分或三烷基甲硅烷氧基部分取代。 芴聚合物和低聚物可以在2-和7-位取代。 芴低聚物和聚合物的单体单元在2和7'位置彼此结合。 2,7'-芳基-9-取代的芴低聚物和聚合物可以进一步彼此反应以通过在端基2,7'-芳基部分上引入任选的部分来形成较高分子量的聚合物， 连接或链延伸，进行链延长或交联。 还公开了制备所公开的化合物的方法。

    HETEROCYCLIC COMPOUNDS, THEIR PREPARATION AND USE
    3.
    发明申请
    HETEROCYCLIC COMPOUNDS, THEIR PREPARATION AND USE 审中-公开
    杂环化合物，其制备和使用

    公开(公告)号：WO1996015099A1

    公开(公告)日：1996-05-23

    申请号：PCT/DK1994000421

    申请日：1994-11-09

    Applicant: NOVO NORDISK A/S ,  PELLICCIARI, Roberto ,  LUNEIA, Roberto ,  LOMBARDI, Grazia ,  MORONI, Flavio

    Inventor： NOVO NORDISK A/S

    IPC: C07C229/46

    CPC classification number: C07D257/04 ,  C07C17/2637 ,  C07C45/30 ,  C07C45/46 ,  C07C61/39 ,  C07C63/49 ,  C07C229/50 ,  C07C2602/08 ,  C07C2602/10 ,  C07D209/42 ,  C07D307/84 ,  C07D333/68 ,  C07C22/04 ,  C07C47/546 ,  C07C49/84 ,  C07C49/792

    Abstract: The present invention relates to therapeutically active heterocyclic compounds of formula (I) wherein n is 0, 1 or 2; and X is -O-, -S, -N(R )- or -CH2-; and R is H, NH2, NHR or OH; and R and R independently are H, COOH, COOR , CONH2, CONHR , CON(R )2, CONHSO2R or tetrazole; and R is H, OH, NH2, NHR , CF3, C1-8-alkyl, C2-8-alkenyl, C2-8-alkynyl, C3-6-cycloalkyl, phenyl or C1-4-alkoxy; and R is H, C1-8-alkyl, C2-8-alkenyl, C2-8-alkynyl, phenyl or C3-6-cycloalkyl; and ring A can be partly or completely saturated or aromatic, or a salt thereof with a pharmaceutically acceptable acid or base, a method of preparing the same and to pharmaceutical compositions comprising the compounds. The novel compounds are useful in treating diseases in the central nervous system related to the metabotropic glutamate receptor system.

    Abstract translation: 本发明涉及式（I）的治疗活性杂环化合物，其中n为0,1或2; 并且X是-O - ， - S，-N（R 5） - 或-CH 2 - ; 并且R 1是H，NH 2，NHR 5或OH; R 2和R 3独立地是H，COOH，COOR 5，CONH 2，CONHR 5，CON（R 5）2，CONHSO 2 R 5或四唑; 和R 4是H，OH，NH 2，NHR 5，CF 3，C 1-8烷基，C 2-8 - 烯基，C 2-8 - 炔基，C 3-6 - 环烷基，苯基或C 1-4 - 烷氧基 ; R 5为H，C 1-8 - 烷基，C 2-8 - 烯基，C 2-8 - 炔基，苯基或C 3-6 - 环烷基; 并且环A可以是部分或完全饱和的或芳族的，或其与药学上可接受的酸或碱的盐，其制备方法和包含该化合物的药物组合物。 该新化合物可用于治疗与代谢型谷氨酸受体系统相关的中枢神经系统疾病。

    PROCESS AND INTERMEDIATE COMPOUNDS FOR THE PREPARATION OF PESTICIDAL FLUOROOLEFIN COMPOUNDS
    6.
    发明申请
    PROCESS AND INTERMEDIATE COMPOUNDS FOR THE PREPARATION OF PESTICIDAL FLUOROOLEFIN COMPOUNDS 审中-公开
    用于制备杀虫剂氟化物化合物的方法和中间体化合物

    公开(公告)号：WO0222538A3

    公开(公告)日：2003-08-21

    申请号：PCT/EP0110463

    申请日：2001-09-11

    Applicant: BASF AG

    Inventor： WOOD WILLIAM WAKEFIELD

    IPC: B01J31/24 ,  C07B61/00 ,  C07C17/26 ,  C07C17/263 ,  C07C22/08 ,  C07C25/24 ,  C07C41/30 ,  C07C43/29

    CPC classification number: C07C17/263 ,  C07C17/2637 ,  C07C22/08 ,  C07C41/30 ,  C07C43/29 ,  C07C2601/02

    Abstract: A two-step process for the preparation of fluoroolefin compounds of formula (I) wherein R is hydrogen or alkyl, and R is alkyl or cyclopropyl, or R and R are taken together with the carbon atom to which they are attached to form a cyclopropyl group; Ar is phenyl or naphthyl both of which are optionally substituted; Ar is phenoxyphenyl, biphenyl, phenyl, benzylphenyl, or benzoylphenyl, all of which may be optionally substituted, comprising reacting fluorobromoolefin compounds of formula (II) with organozinc compounds of formula (III) (BrZnCH2Ar ) or (IV) (Zn(CH2Ar )2) in the presence of a palladium catalyst and a solvent, which compounds of formula (II) are obtained by reacting aldehyde compounds of formula (V) with (a) fluorotribromomethane, (b) a tri(substituted)phosphine or a hexaalkylphosphoramide or a mixture thereof, and (c) zinc, in the presence of a solvent, compounds of formula (II).

    Abstract translation: 制备式（I）的氟烯烃化合物的两步法，其中R是氢或烷基，R 1是烷基或环丙基，或R和R 1与它们所在的碳原子一起 连接形成环丙基; Ar是任选被取代的苯基或萘基; Ar 1是苯氧基苯基，联苯基，苯基，苄基苯基或苯甲酰基苯基，它们都可以任选被取代，包括使式（II）的氟代溴代烯烃化合物与式（III）的有机锌化合物（BrZnCH2Ar1）或（IV ）（Zn（CH 2 Ar 1）2）在钯催化剂和溶剂的存在下，式（II）化合物通过使式（V）的醛化合物与（a）氟代溴甲烷反应获得，（b） 三（取代）膦或六烷基磷酰胺或其混合物，和（c）锌在溶剂存在下，式（II）化合物。

    PROCESS AND INTERMEDIATE COMPOUNDS FOR THE PREPARATION OF PESTICIDAL FLUOROOLEFIN COMPOUNDS
    7.
    发明申请
    PROCESS AND INTERMEDIATE COMPOUNDS FOR THE PREPARATION OF PESTICIDAL FLUOROOLEFIN COMPOUNDS 审中-公开
    用于制备杀虫剂氟化物化合物的方法和中间体化合物

    公开(公告)号：WO02022538A2

    公开(公告)日：2002-03-21

    申请号：PCT/EP2001/010463

    申请日：2001-09-11

    IPC: B01J31/24 ,  C07B61/00 ,  C07C17/26 ,  C07C17/263 ,  C07C22/08 ,  C07C25/24 ,  C07C41/30 ,  C07C43/29

    CPC classification number: C07C17/263 ,  C07C17/2637 ,  C07C22/08 ,  C07C41/30 ,  C07C43/29 ,  C07C2601/02

    Abstract: A two-step process for the preparation of fluoroolefin compounds of formula (I) wherein R is hydrogen or alkyl, and R is alkyl or cyclopropyl, or R and R are taken together with the carbon atom to which they are attached to form a cyclopropyl group; Ar is phenyl or naphthyl both of which are optionally substituted; Ar is phenoxyphenyl, biphenyl, phenyl, benzylphenyl, or benzoylphenyl, all of which may be optionally substituted, comprising reacting fluorobromoolefin compounds of formula (II) with organozinc compounds of formula (III) (BrZnCH2Ar ) or (IV) (Zn(CH2Ar )2) in the presence of a palladium catalyst and a solvent, which compounds of formula (II) are obtained by reacting aldehyde compounds of formula (V) with (a) fluorotribromomethane, (b) a tri(substituted)phosphine or a hexaalkylphosphoramide or a mixture thereof, and (c) zinc, in the presence of a solvent, compounds of formula (II).

    Abstract translation: 制备式（I）的氟烯烃化合物的两步法，其中R是氢或烷基，R 1是烷基或环丙基，或R和R 1与它们所在的碳原子一起 连接形成环丙基; Ar是任选被取代的苯基或萘基; Ar 1是苯氧基苯基，联苯基，苯基，苄基苯基或苯甲酰基苯基，它们都可以任选被取代，包括使式（II）的氟代溴代烯烃化合物与式（III）的有机锌化合物（BrZnCH2Ar1）或（IV ）（Zn（CH 2 Ar 1）2）在钯催化剂和溶剂的存在下，式（II）化合物通过使式（V）的醛化合物与（a）氟代溴甲烷反应获得，（b） 三（取代）膦或六烷基磷酰胺或其混合物，和（c）锌在溶剂存在下，式（II）化合物。

    POLYMERS OF VINYL(PERFLUOROCYCLOPROPANE)
    8.
    发明申请
    POLYMERS OF VINYL(PERFLUOROCYCLOPROPANE) 审中-公开
    乙烯聚合物（全氟聚醚）

    公开(公告)号：WO1996010605A2

    公开(公告)日：1996-04-11

    申请号：PCT/US1995011408

    申请日：1995-09-19

    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY

    Inventor： E.I. DU PONT DE NEMOURS AND COMPANY ,  YANG, Zhen-Yu

    IPC: C08L00/00

    CPC classification number: C07C17/23 ,  C07C17/2637 ,  C07C23/04 ,  C08F12/20 ,  C08F14/185

    Abstract: Disclosed herein are polymers made by free radically polymerizing the novel compound vinyl(perfluorocyclopropane), and optionally other monomers to form copolymers. The repeat unit formed by vinyl(perfluorocyclopropane) contains an olefinic bond, making it particularly useful as a grafting and/or crosslinking site.

    Abstract translation: 本文公开的是通过自由基聚合新型化合物乙烯基（全氟环丙烷）和任选的其它单体以形成共聚物而制备的聚合物。 由乙烯基（全氟环丙烷）形成的重复单元含有烯键，使其特别可用作接枝和/或交联位点。

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