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    METHODS OF PRECIPITATING POLYMER AND DEACTIVATED ORGANOMETALLIC CATALYST IN AN OLEFIN OLIGOMERIZATION REACTION
    2.
    发明申请
    METHODS OF PRECIPITATING POLYMER AND DEACTIVATED ORGANOMETALLIC CATALYST IN AN OLEFIN OLIGOMERIZATION REACTION 审中-公开
    烯烃低聚反应中聚合物和去活化有机催化剂的制备方法

    公开(公告)号：WO2016105226A1

    公开(公告)日：2016-06-30

    申请号：PCT/RU2014/000972

    申请日：2014-12-23

    申请人： PUBLIC JOINT STOCK COMPANY "SIBUR HOLDING"

    发明人： ZILBERSHTEIN, Timur Mikhailovich

    IPC分类号： C07C7/12 ,  C07C7/13 ,  C08F6/02

    CPC分类号： C07C7/12 ,  B01J31/143 ,  B01J31/181 ,  B01J2231/20 ,  B01J2531/62 ,  C07C2/30 ,  C07C2/32 ,  C07C2531/12 ,  C07C2531/14 ,  C07C2531/18 ,  C07C11/02 ,  C07C11/107

    摘要： A method of precipitating polymer and deactivated organometallic catalyst in an olefin oligomerization reaction is provided. The method includes providing an effluent stream from an olefin oligomerization reaction. The effluent stream can include a polymer and an organometallic catalyst. The method can further include introducing sorbent particles into the effluent stream. The sorbent particles can include a deactivating agent. The deactivating agent can be water, an alcohol, an amine, an amino alcohol, or a combination thereof. At least about 10% of the sorbent particles can have a particle size in a range from 10 μm and 60 μm. The method can further include cooling the effluent stream, thereby precipitating polymer and deactivated organometallic catalyst from the effluent stream to provide a precipitate that includes sorbent, polymer, and deactivated catalyst.

    摘要翻译： 提供了在烯烃低聚反应中沉淀聚合物和失活的有机金属催化剂的方法。 该方法包括提供来自烯烃低聚反应的流出物流。 流出物流可以包括聚合物和有机金属催化剂。 该方法还可以包括将吸附剂颗粒引入流出物流中。 吸附剂颗粒可以包括钝化剂。 去活化剂可以是水，醇，胺，氨基醇或其组合。 至少约10％的吸附剂颗粒可以具有在10μm和60μm范围内的粒度。 该方法还可以包括冷却流出物流，从而从流出物流中沉淀聚合物和失活的有机金属催化剂，以提供包括吸附剂，聚合物和失活催化剂的沉淀物。

    OLIGOMERISATION OF OLEFINIC COMPOUNDS WITH REDUCED POLYMER FORMATION
    5.
    发明申请
    OLIGOMERISATION OF OLEFINIC COMPOUNDS WITH REDUCED POLYMER FORMATION 审中-公开
    具有降低聚合物形成的烯烃化合物的低级化

    公开(公告)号：WO2011048527A1

    公开(公告)日：2011-04-28

    申请号：PCT/IB2010/054631

    申请日：2010-10-13

    申请人： SASOL TECHNOLOGY (PTY) LIMITED ,  HANTON, Martin John ,  SMITH, David Matthew ,  GABRIELLI, William Fullard ,  KELLY, Mark William

    发明人： HANTON, Martin John ,  SMITH, David Matthew ,  GABRIELLI, William Fullard ,  KELLY, Mark William

    IPC分类号： C07C2/32 ,  C07C2/36

    CPC分类号： C07C2/36 ,  C07C2/32 ,  C07C2531/12 ,  C07C2531/14 ,  C07C2531/24 ,  C07C11/02

    摘要： The invention relaters to a process for producing an oligomeric product by oligomerisation of at least one olefinic compound, the process including a) providing an activated oligomerisation catalyst by combining, in any order, ι) a source of chromium, ιι) a ligating compound of the formula I (R 1 ) m X 1 (Y) X 2 (R 2 ) n ......I wherein X 1 and X 2 are independently an atom selected from the group consisting of nitrogen, phosphorus, arsenic, antimony, bismuth, oxygen, sulphur and selenium or said atom oxidized by S, Se, N or O where the valence of X 1 and/or X 2 allows for such oxidation, Y is a linking group between X 1 and X 2 , m and n are independently 0, 1 or a larger integer, and R 1 and R 2 are independently hydrogen, a hydrocarbyl group, an organoheteryl group or a heterohydrocarbyl group, and R1 being the same or different when m>1, and R 2 being the same or different when n>1, iii) a catalyst activator or combination of catalyst activators, b) providing a zinc compound, and c) contacting the at least one olefinic compound with a composition containing the activated oligomerisation catalyst and the zinc compound, the zinc compound being present in a sufficient quantity such that the ratio of the molar amount of zinc in the zinc compound to the molar amount of chromium in the source of chromium is between 1 and 10000 The invention also provides for a process for activating an oligomerisation catalyst to be used to produce an oligomeric product from at least one olefinic compound, as described above

    摘要翻译： 本发明涉及通过至少一种烯烃化合物的低聚产生低聚产物的方法，该方法包括：a）通过以任何顺序，以任何顺序组合α）铬源，α）连接化合物提供活化的低聚催化剂 的式I（R1）m X1（Y）X2（R2）n ...... I其中X1和X2独立地是选自氮，磷，砷，锑，铋，氧， 硫和硒或由S，Se，N或O氧化的所述原子，其中X1和/或X2的化合价允许这种氧化，Y是X1和X2之间的连接基团，m和n独立地为0,1或更大 R 1和R 2独立地为氢，烃基，有机杂原子或杂烃基，当m≥1时，R 1相同或不同，并且当n> 1时，R 2相同或不同，iii）催化剂 活化剂或催化剂活化剂的组合，b）提供锌化合物，和c） 至少一种含有活化低聚催化剂和锌化合物的组合物的烯烃化合物，锌化合物以足够的量存在，使得锌化合物中的锌的摩尔量与源的锌的摩尔量的比例 铬在1和10000之间本发明还提供了用于活化低聚催化剂以用于从至少一种烯属化合物制备低聚产物的方法，如上所述

    A SUPPORTED METAL COMPOUND, PREPARATION OF THE COMPOUND AND USE OF THE COMPOUND AS A CATALYST
    8.
    发明申请
    A SUPPORTED METAL COMPOUND, PREPARATION OF THE COMPOUND AND USE OF THE COMPOUND AS A CATALYST 审中-公开
    支持的金属化合物，化合物的制备和作为催化剂的化合物的使用

    公开(公告)号：WO2003061823A1

    公开(公告)日：2003-07-31

    申请号：PCT/GB2003/000173

    申请日：2003-01-17

    申请人： BP CHEMICALS LIMITED ,  BASSET, Jean-Marie ,  COPERET, Christophe ,  MAUNDERS, Barry, Martin ,  RATABOUL, Franck ,  SAGGIO, Guillaume ,  SOULIVONG, Daravong ,  TAOUFIK, Mostapha ,  THIVOLLE-CAZAT, Jean

    发明人： BASSET, Jean-Marie ,  COPERET, Christophe ,  MAUNDERS, Barry, Martin ,  RATABOUL, Franck ,  SAGGIO, Guillaume ,  SOULIVONG, Daravong ,  TAOUFIK, Mostapha ,  THIVOLLE-CAZAT, Jean

    IPC分类号： B01J31/12

    CPC分类号： C07C6/10 ,  B01J31/121 ,  B01J37/0203 ,  B01J37/16 ,  B01J2231/12 ,  B01J2231/20 ,  B01J2231/52 ,  C07C2/08 ,  C07C5/2206 ,  C07C2531/12 ,  C08F10/00 ,  C08F4/025

    摘要： The present invention relates to a supported metal compound comprising a solid support to which are grafted at least two types of metal atom, Me, one in a form (A) of a metal compound where the metal atom is bonded to at least one hydrogen atom and/or to at least one hydrocarbon, and the other in a form (B) of a metal compound where the metal atom is bonded solely to the support and optionally to at least one other element which is neither a hydrogen atom nor a hydrocarbon radical. The compound can be prepared (a) by grafting an organometallic precursor (P) comprising the metal Me, bonded to at least one hydrocarbon ligand, to the solid support, and (b) by treating the solid product resulting from step (a) with hydrogen or a reducing agent, at a temperature greater than the temperature, TI, at which the supported metal compound is formed solely in the form (A), and at a temperature lower than the temperature, T2, at which the supported metal compound is formed solely in the form (B). The compound can be used in particular as a catalyst in a process employing hydrocarbon splitting and recombination reactions, e.g. in a hydrocarbon metathesis reaction, with a greatly increased catalytic activity, in comparison with a supported metal compound which is identical but which would include only the form (A), the form (B) being inactive in this type of reaction.

    摘要翻译： 本发明涉及一种载体金属化合物，其包括固体载体，其接枝至少两种类型的金属原子Me，金属化合物的A形式，其中金属原子键合至至少一个氢原子和/ 或至少一种烃，另一种为金属化合物的形式B，其中金属原子仅与载体键合，并且任选地与至少一种不是氢原子或烃基的其它元素结合。 该化合物可以通过将包含与至少一个烃配体结合的金属Me的有机金属前体P接枝到固体载体上来制备，b通过用氢或还原剂处理由步骤a产生的固体产物， 温度高于仅以A型形成负载型金属化合物的温度TI，且温度低于仅以B型形成负载金属化合物的温度T2的温度。化合物可以 特别是在使用烃分解和重组反应的方法中用作催化剂，例如 在烃复分解反应中，与相同但仅包括A型的负载金属化合物相比，催化活性大大增加，B型在这种反应中是无活性的。

    PROCESS FOR THE PRODUCTION OF HIGH CETANE VALUE CLEAN FUELS
    9.
    发明申请
    PROCESS FOR THE PRODUCTION OF HIGH CETANE VALUE CLEAN FUELS 审中-公开
    生产高新西兰价值清洁燃料的工艺

    公开(公告)号：WO1993006069A1

    公开(公告)日：1993-04-01

    申请号：PCT/US1992008027

    申请日：1992-09-21

    申请人： MOBIL OIL CORPORATION

    发明人： MOBIL OIL CORPORATION ,  CHEN, Catherine, Shuihua, Hsia ,  HOSKIN, Dennis, Harold ,  SCHRAMM, Suzanne, Elaine

    IPC分类号： C07C02/74

    CPC分类号： C07C9/22 ,  C07C6/04 ,  C07C2521/08 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/36 ,  C07C2529/40 ,  C07C2529/70 ,  C07C2531/12 ,  C07C2531/26 ,  C07C2531/34 ,  C10G50/02 ,  C10G69/126

    摘要： The 177 DEG -343 DEG C (350 DEG -650 DEG F) portion of the product from the oligomerization of light olefins with surface-deactivated shape selective medium pore zeolite catalyst comprises olefinic hydrocarbons having unique and desirable structures as precursors for high cetane value clean fuels. These oligomers are near linear in structure and contain no aromatics. Following hydrogenation they produce cetane values between 50 and 75. When the near linear olefinic hydrocarbons from surface-deactivated zeolite catalyzed oligomerization of light olefins are subjected to ethene metathesis to alpha olefins and oligomerization, the overall process reaction product comprises a mixture of a 343 DEG C + (650 DEG F +) portion comprising high VI lubricant and a 177 DEG -343 DEG C (350 DEG -650 DEG F) portion comprising high cetane clean fuels precursor. Hydrogenation of the 177 DEG -343 DEG C (350 DEG -650 DEG F) portion provides an aromatics-free fuel with a cetane value between 50-70 containing less that 0.5 weight % naphthenes.

    摘要翻译： 来自具有表面去活化形状选择性中孔沸石催化剂的轻质烯烃低聚的产物的177°-343℃（350-650°F）包括具有独特且理想的结构的烯烃，作为高十六烷值清洁的前体 燃料。 这些低聚物在结构上接近线性并且不含芳族化合物。 氢化后，它们产生50至75之间的十六烷值。当来自表面失活的沸石催化的轻质烯烃低聚的近线性烯烃经受乙烯复分解为α-烯烃和低聚时，整个工艺反应产物包含343℃ 包含高VI润滑剂的C +（650°F +）部分和包含高十六烷清洁燃料前体的177-343℃（350-650°F）部分。 177°-343℃（350°-650°F）部分的氢化提供无芳烃的燃料，十五烷值在50-70之间，含有少于0.5重量％的环烷烃。

    PROCESS FOR OLIGOMERIZING C3 AND HIGHER OLEFINS USING ZIRCONIUM ADDUCTS AS CATALYSTS
    10.
    发明申请
    PROCESS FOR OLIGOMERIZING C3 AND HIGHER OLEFINS USING ZIRCONIUM ADDUCTS AS CATALYSTS 审中-公开
    使用ZIRCONIUM ADDUCTS作为催化剂低级化C3和高烯烃的方法

    公开(公告)号：WO1992016477A1

    公开(公告)日：1992-10-01

    申请号：PCT/US1992001821

    申请日：1992-03-04

    申请人： EXXON CHEMICAL PATENTS INC.

    发明人： EXXON CHEMICAL PATENTS INC. ,  YOUNG, David, Alexander ,  JONES, Larry, Olivier ,  CAMPIONE, Troy, John

    IPC分类号： C07C02/30

    CPC分类号： C07C2/30 ,  B01J31/122 ,  B01J31/38 ,  B01J2231/20 ,  C07C2527/135 ,  C07C2531/02 ,  C07C2531/04 ,  C07C2531/12 ,  C07C2531/14 ,  C07C2531/38

    摘要： C3 and higher olefins are oligomerized using a two component catalyst system comprising (a) a soluble adduct of zirconium tetrahalide, the halogen being Br or Cl, with an organic compound selected from the group of esters, ketones, ethers, amines, nitriles, anhydrides, acid chlorides, amides or aldehydes, the organic compound having up to about 30 carbon atoms and (b) an alkyl metal selected from the group R2AlX, RAlX2, R3Al2X3, R3Al and R2Zn where R is C1-C20 alkyl and X is Cl or Br. ZrCl4 adducts with organic acetates are the preferred embodiments. Dimers, trimers and tetramers are selectively prepared in the process.

    摘要翻译： C3和更高级烯烃使用双组分催化剂体系低聚，其包含（a）四卤化锆的可溶性加合物，卤素为Br或Cl，与选自酯，酮，醚，胺，腈，酸酐的有机化合物 ，酰氯，酰胺或醛，有机化合物具有至多约30个碳原子，和（b）选自R2AlX，RA1X2，R3Al2X3，R3Al和R2Zn的烷基金属，其中R是C1-C20烷基，X是Cl或 BR。 ZrCl 4与有机乙酸酯的加合物是优选的实施方案。 在该过程中选择性地制备二聚体，三聚体和四聚体。