Abstract:
The invention includes methods and materials for forming and manipulating aromatic-based polymers and copolymers using biomass compounds as starting materials. Embodiments of the invention can be used in processes designed to replace those used in the petrochemical industry. Typical embodiments of the invention include methods and materials for forming and/or modifying compounds including dicarboxylic acid ester dimers, benzoxazines and dicarboxylic acid ether dimers. Embodiments of the invention further provide methods and materials for utilizing these compounds to form commercially desirable polymers having structures and physical properties akin to those found in polymers formed from petroleum products.
Abstract:
A mefa-substituted trifunctional benzoxazine monomer and compositions containing the same, wherein the trifunctional benzoxazine monomer is represented by the following structure.
Abstract:
Polytetrahydrobenzoxazine und Bistetrahydrobenzoxazine, erhältlich durch (A) Umsetzung mindestens eines Diamins der Formel H 2 N-A-NH 2 mit einem C 1 - bis C 12 -Aldehyd und einem C 1 - bis C 8 -Alkanol bei 20 bis 80°C unter Abspaltung und Entfernung von Wasser, (B) Umsetzung des Kondensationsproduktes aus (A) mit einem Phenol, welches einen langkettigen Substituenten trägt, bei 30 bis 120°C und gegebenenfalls (C) Erhitzen des Umsetzungsproduktes aus (B) auf 125 bis 280°C. Die erhaltenen Polytetrahydrobenzoxazine und Bistetrahydrobenzoxazine eignen sich als Kraftstoff- oder Schmierstoffadditive, insbesondere als Detergensadditive für Dieselkraftstoffe.
Abstract:
Verwendung von mehrkernigen phenolischen Verbindungen mit bis zu 20 Benzolkernen pro Molekül, welche durch Umsetzung eines Tetrahydrobenzoxazins I wobei R 1 einen Hydrocarbylrest bezeichnet und R 2 , R3, R 4 und R 5 unabhängig voneinander für Wasserstoffatome, Hydroxylgruppen oder Hydrocarbylreste stehen, mit einem oder mehreren der gleichen oder verschiedener Phenole II wobei R 7 , R 8 , R 9 und R 10 unabhängig voneinander für Wasserstoffatome, Hydroxylgruppen oder Hydrocarbylreste stehen, und/oder mit einem oder mehreren der gleichen oder verschiedener Tetrahydrobenzoxazine I erhältlich sind, mit der Maßgabe, dass mindestens einer der Substituenten 13 bis 3000 Kohlenstoffatome aufweist und die übrigen Substituenten, wenn sie für Hydrocarbylreste stehen, jeweils 1 bis 20 Kohlenstoffatome aufweisen, als Stabilisatoren zur Stabilisierung von unbelebtem organischen Material gegen die Einwirkung von Licht, Sauerstoff und Wärme.
Abstract:
Compounds are disclosed that have a formula represented by the following: The compounds may be prepared as pharmaceutical compositions, and may be used for the prevention and treatment of a variety of conditions in mammals including humans, including by way of non-limiting example, pain, inflammation, traumatic injury, and others.
Abstract:
The present invention relates to monofunctional benzoxazines having non-benzoxazine functional groups thereon. Polymers of benzoxazine can be formed from the monomers through functional group polymerization as well as benzoxazine polymerization utilizing the same or different mechanisms. The functionalized benzoxazine materials are high performance polymers having glass transition temperature about 200° C and which exhibit other desirable properties such as increase of char yield without a significant increase in viscosity of the monomer. Furthermore, the functionalized benzoxazine monomers can be copolymerized with other monomers such as epoxy. The benzoxazine copolymers exhibit toughness, processability, and excellent thermal properties.
Abstract:
Benzoxazine monomers, oligomers and polymers are desirably modified by adding pendant functional groups to either the amine or phenolic reactants. These pendant functional groups can be activated at temperatures generally from about 25 DEG C to about 300 DEG C to form chemical bonds between said benzoxazine monomers, oligomers and polymers. The additional chemical bonds increase the thermal stability of benzoxazine polymers such that they can withstand higher use temperature, act as more effective flame barriers, or result in higher amounts of char if used as a precursor to high temperature (600-1000 DEG C reaction condition) chars.
Abstract:
A curable resin composition containing a blend of multifunctional benzoxazines, and composite materials derived therefrom. The benzoxazine blend contains the combination of (A) a difunctional benzoxazine component and (B) a multifunctional benzoxazine component with functionality of greater than 2. Cured matrix resins and cured composite materials containing such benzoxazine blend exhibit a significant retardation in the rate of organic solvent uptake as compared to the same cured matrix resins and composite materials without component (B).
Abstract:
Disclosed herein are monofunctional benzoxazine compounds having at least one electron-withdrawing group. The monofunctional benzoxazine compounds may be combined with one or more multifunctional benzoxazine compounds to form a unique benzoxazine blend. This benzoxazine blend may be combined with additional components such as catalysts and toughening agents to form a curable resin composition suitable for forming resinous films or composite materials. The presence of monofunctional benzoxazine improves the processability of the benzoxazine-based resin composition by reducing the viscosity of the resin composition, and results in improved tack and drape in the films and composite materials formed from the composition without the loss of modulus in the cured resin.