BIOMASS-DERIVED POLYMERS AND COPOLYMERS INCORPORATING MONOLIGNOLS AND THEIR DERIVATIVES
    1.
    发明申请
    BIOMASS-DERIVED POLYMERS AND COPOLYMERS INCORPORATING MONOLIGNOLS AND THEIR DERIVATIVES 审中-公开
    生物材料衍生的聚合物和共聚物,包括单体和它们的衍生物

    公开(公告)号:WO2017066699A1

    公开(公告)日:2017-04-20

    申请号:PCT/US2016/057212

    申请日:2016-10-14

    Abstract: The invention includes methods and materials for forming and manipulating aromatic-based polymers and copolymers using biomass compounds as starting materials. Embodiments of the invention can be used in processes designed to replace those used in the petrochemical industry. Typical embodiments of the invention include methods and materials for forming and/or modifying compounds including dicarboxylic acid ester dimers, benzoxazines and dicarboxylic acid ether dimers. Embodiments of the invention further provide methods and materials for utilizing these compounds to form commercially desirable polymers having structures and physical properties akin to those found in polymers formed from petroleum products.

    Abstract translation: 本发明包括用于形成和操作使用生物质化合物作为起始材料的芳族基聚合物和共聚物的方法和材料。 本发明的实施方案可以用于被设计来代替在石化工业中使用的那些的工艺中。 本发明的典型实施方案包括用于形成和/或改性包括二羧酸酯二聚体,苯并恶嗪和二羧酸醚二聚体的化合物的方法和材料。 本发明的实施方案进一步提供了利用这些化合物形成具有类似于由石油产品形成的聚合物中发现的结构和物理性质的商业上期望的聚合物的方法和材料。

    FUNCTIONALIZED BENZOXAZINES, POLYMERS AND COPOLYMERS THEREOF
    6.
    发明申请
    FUNCTIONALIZED BENZOXAZINES, POLYMERS AND COPOLYMERS THEREOF 审中-公开
    功能性苯并吖庚因,聚合物及其共聚物

    公开(公告)号:WO2004101509A3

    公开(公告)日:2005-06-30

    申请号:PCT/US2004012041

    申请日:2004-04-19

    Inventor: ISHIDA HATSUO

    CPC classification number: C07D413/10 C07D265/16 H05K1/0346

    Abstract: The present invention relates to monofunctional benzoxazines having non-benzoxazine functional groups thereon. Polymers of benzoxazine can be formed from the monomers through functional group polymerization as well as benzoxazine polymerization utilizing the same or different mechanisms. The functionalized benzoxazine materials are high performance polymers having glass transition temperature about 200° C and which exhibit other desirable properties such as increase of char yield without a significant increase in viscosity of the monomer. Furthermore, the functionalized benzoxazine monomers can be copolymerized with other monomers such as epoxy. The benzoxazine copolymers exhibit toughness, processability, and excellent thermal properties.

    Abstract translation: 本发明涉及其上具有非苯并恶嗪官能团的单官能苯并恶嗪。 苯并恶嗪的聚合物可以通过官能团聚合由单体形成,也可以使用相同或不同的机理形成苯并恶嗪聚合。 官能化的苯并恶嗪材料是玻璃化转变温度约为200℃的高性能聚合物,并且其表现出其它所需的性能,例如增加焦炭产率而不显着增加单体的粘度。 此外,官能化的苯并恶嗪单体可以与其它单体如环氧树脂共聚。 苯并恶嗪共聚物具有韧性,加工性和优异的热性能。

    HIGH CHAR YIELD BENZOXAZINES
    7.
    发明申请
    HIGH CHAR YIELD BENZOXAZINES 审中-公开
    高铬合金苯甲酸酯

    公开(公告)号:WO99018092A1

    公开(公告)日:1999-04-15

    申请号:PCT/US1998/019799

    申请日:1998-09-22

    CPC classification number: C07D265/16

    Abstract: Benzoxazine monomers, oligomers and polymers are desirably modified by adding pendant functional groups to either the amine or phenolic reactants. These pendant functional groups can be activated at temperatures generally from about 25 DEG C to about 300 DEG C to form chemical bonds between said benzoxazine monomers, oligomers and polymers. The additional chemical bonds increase the thermal stability of benzoxazine polymers such that they can withstand higher use temperature, act as more effective flame barriers, or result in higher amounts of char if used as a precursor to high temperature (600-1000 DEG C reaction condition) chars.

    Abstract translation: 希望通过向胺或酚类反应物中加入侧链官能团来修饰苯并恶嗪单体,低聚物和聚合物。 这些侧基官能团可以在通常约25℃至约300℃的温度下活化,以形成所述苯并恶嗪单体,低聚物和聚合物之间的化学键。 额外的化学键增加了苯并恶嗪聚合物的热稳定性,使得它们可以承受更高的使用温度,作为更有效的阻燃剂,或者如果用作高温的前体(600-1000℃的反应条件) )字符

    MULTIFUNCTIONAL BENZOXAZINES AND COMPOSITE MATERIALS INCORPORATING THE SAME
    8.
    发明申请
    MULTIFUNCTIONAL BENZOXAZINES AND COMPOSITE MATERIALS INCORPORATING THE SAME 审中-公开
    多官能苯并ES嗪及其合成材料

    公开(公告)号:WO2015094635A1

    公开(公告)日:2015-06-25

    申请号:PCT/US2014/068068

    申请日:2014-12-02

    Abstract: A curable resin composition containing a blend of multifunctional benzoxazines, and composite materials derived therefrom. The benzoxazine blend contains the combination of (A) a difunctional benzoxazine component and (B) a multifunctional benzoxazine component with functionality of greater than 2. Cured matrix resins and cured composite materials containing such benzoxazine blend exhibit a significant retardation in the rate of organic solvent uptake as compared to the same cured matrix resins and composite materials without component (B).

    Abstract translation: 含有多官能苯并恶嗪的共混物的固化性树脂组合物和由其衍生的复合材料。 苯并恶嗪混合物包含(A)双官能苯并恶嗪组分和(B)官能度大于2的多官能苯并嗪组分的组合。固化的基质树脂和含有这种苯并恶嗪混合物的固化的复合材料显示有机溶剂的速率显着延迟 与没有组分(B)的相同的固化基质树脂和复合材料相比,吸收。

    BENZOXAZINES AND COMPOSITIONS CONTAINING THE SAME
    9.
    发明申请
    BENZOXAZINES AND COMPOSITIONS CONTAINING THE SAME 审中-公开
    苯并吖嗪及其组合物

    公开(公告)号:WO2013148408A1

    公开(公告)日:2013-10-03

    申请号:PCT/US2013/032897

    申请日:2013-03-19

    Abstract: Disclosed herein are monofunctional benzoxazine compounds having at least one electron-withdrawing group. The monofunctional benzoxazine compounds may be combined with one or more multifunctional benzoxazine compounds to form a unique benzoxazine blend. This benzoxazine blend may be combined with additional components such as catalysts and toughening agents to form a curable resin composition suitable for forming resinous films or composite materials. The presence of monofunctional benzoxazine improves the processability of the benzoxazine-based resin composition by reducing the viscosity of the resin composition, and results in improved tack and drape in the films and composite materials formed from the composition without the loss of modulus in the cured resin.

    Abstract translation: 本文公开了具有至少一个吸电子基团的单官能苯并恶嗪化合物。 单官能苯并恶嗪化合物可以与一种或多种多官能苯并恶嗪化合物组合以形成独特的苯并恶嗪混合物。 该苯并恶嗪共混物可以与另外的组分如催化剂和增韧剂组合以形成适于形成树脂膜或复合材料的可固化树脂组合物。 单官能苯并恶嗪的存在通过降低树脂组合物的粘度来提高苯并恶嗪类树脂组合物的加工性,并且导致由组合物形成的膜和复合材料中的粘性和悬垂性改善,而固化树脂的模量没有损失 。

    含苯并环丁烯官能团的苯并噁嗪单体及其合成方法和应用

    公开(公告)号:WO2013033955A1

    公开(公告)日:2013-03-14

    申请号:PCT/CN2011/082499

    申请日:2011-11-21

    Inventor: 程元荣 肖斐

    CPC classification number: C07D265/12 C07D265/14 C07D265/16 C08G73/06 C08G73/22

    Abstract: 提供一种含苯并环丁烯官能团的苯并噁嗪单体及其合成方法和应用。所述含苯并环丁烯单体的苯并噁嗪单体可由两种路线合成。其一是采用含氨基的苯并环丁烯和酚类化合物以及甲酸(或者多聚甲酸)为原料,通过洗涤、萃取等方法提纯分离,得到目标单体。其二是以4-羟基苯并环丁烯和含伯胺类化合物以及甲酸(或者多聚甲酸)为原料,通过洗涤、萃取等方法提纯分离,得到目标单体。该苯并噁嗪单体在一定温度下具有较低的粘度,可以通过加热或者催化剂催化的方法进行固化。固化后得到的树脂具有优良的热稳定性、机械性能、以及极低的吸湿性,可以用作电子封装材料、耐高温阻燃材料、高性能复合材料、航空材料等。

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