CYCLIC THERMOCHEMICAL DISSOCIATION OF CARBON DIOXIDE AND WATER.
    3.
    发明申请
    CYCLIC THERMOCHEMICAL DISSOCIATION OF CARBON DIOXIDE AND WATER. 审中-公开
    二氧化碳和水的循环热化学分解。

    公开(公告)号:WO2012131703A3

    公开(公告)日:2012-12-27

    申请号:PCT/IN2012000170

    申请日:2012-03-13

    摘要: The invention comprises a process of cyclic thermochemical dissociation of oxides catalysed by a metal compound of general structural formula MX, wherein M is a metal; X is none or oxygen or halogen, the said oxygen or halogen present in moles equivalent to M; comprising at least a step of recovering anhydrous metal halide from a process stream and recycling the metal halide or thermally decomposing the same to metal and halogen for recycling. The oxide selected for dissociation may be carbon-dioxide or water. After dissociation of oxides, the products of the reaction undergo a series of reactions comprising a reaction with a halogen, formation of metal halides and oxyhalides as intermediates, thermal decomposition of metal oxyhalides to recover metal oxides and Iodine for recycle, recovery of metal halides for recycle and thermal decomposition of metal halides to metal and halogen for recycle in the said cyclic process.

    摘要翻译: 本发明包括由通式结构式MX的金属化合物催化的氧化物的环状热化学解离过程,其中M是金属; X为无或氧或卤素,所述氧或卤素以摩尔当量M存在; 包括至少从工艺流中回收无水金属卤化物并循环金属卤化物或将其热分解成金属和卤素进行回收的步骤。 选择用于解离的氧化物可以是二氧化碳或水。 在氧化物解离后,反应产物经过一系列反应,包括与卤素的反应,金属卤化物和卤氧化物的形成作为中间体,金属卤氧化物的热分解以回收金属氧化物和碘进行再循环,回收金属卤化物 在所述循环过程中金属卤化物再循环和热分解成金属和卤素用于再循环。

    PROCESS, METHOD, AND SYSTEM FOR REMOVING HEAVY METALS FROM FLUIDS
    8.
    发明申请
    PROCESS, METHOD, AND SYSTEM FOR REMOVING HEAVY METALS FROM FLUIDS 审中-公开
    用于从流体中除去重金属的方法,方法和系统

    公开(公告)号:WO2012036986A2

    公开(公告)日:2012-03-22

    申请号:PCT/US2011051033

    申请日:2011-09-09

    摘要: Trace element levels of heavy metals such as mercury in crude oil are reduced by contacting the crude oil with an iodine source, generating a water soluble heavy metal complex for subsequent removal from the crude oil. In one embodiment, the iodine source is generated in-situ in an oxidation-reduction reaction, by adding the crude oil to an iodine species having a charge and a reductant or an oxidant depending on the charge of the iodine species. In one embodiment with an iodine species having a positive charge and a reducing reagent, a complexing agent is also added to the crude oil to extract the heavy metal complex into the water phase to form water soluble heavy metal complexes which can be separated from the crude oil, for a treated crude oil having reduced levels of heavy metals.

    摘要翻译: 原油中的重金属如汞的痕量元素含量通过使原油与碘源接触而减少,从而产生水溶性重金属络合物以随后从原油中除去。 在一个实施方案中,通过将原油加入具有电荷和还原剂或氧化剂的碘物质,取决于碘物质的电荷,在氧化还原反应中原位生成碘源。 在具有正电荷和还原剂的碘物质的一个实施方案中,络合剂也被加入到原油中以将重金属络合物萃取到水相中以形成水溶性重金属络合物,其可以从原油 对于具有降低的重金属含量的经处理的原油来说。

    METHOD AND KIT FOR QUICK AND LOW-COST DETECTION OF IODIDE IONS IN AQUEOUS SOLUTIONS

    公开(公告)号:WO2019239168A1

    公开(公告)日:2019-12-19

    申请号:PCT/HU2019/000020

    申请日:2019-06-12

    申请人: IOI AURANAE KFT.

    发明人: KÖNTÖS, Zoltan

    摘要: The invention relates to a method and kit for quick and low-cost determination of the iodide ion content, which can be used not only to detect the possible iodine deficient conditions but also to estimate the iodide ion concentration of aqueous solutions. The present invention relates to a method for the determination of iodide ions in an aqueous solution, comprising the steps of: a) providing a liquid sample for which iodide ion concentration has to be determined, b) adding at least one drop of aqueous solution of metal ion to the liquid sample of step a) wherein the metal ions selectively precipitate with iodide ion under normal conditions; c) shaking the liquid sample of step b) and waiting for 1 to 5 minutes, preferably 3 minutes; d) repeating steps b) and c) until the precipitation is clearly visible to the naked eye in the test solution; e) recording and summing up the number of drops; and f) determining the amount of iodide ions based on the number of drops. The present invention further relates to a kit for determination of iodide ions in an aqueous solution. The kit according to the invention comprises a sample vessel, a vessel equipped with a dropper wherein the said vessel contains a metal salt solution which selectively precipitates with iodide ion content under normal conditions and an instruction for describing the method of determining the iodide ions in aqueous solution.