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    VERFAHREN ZUR HERSTELLUNG VON ACYLGLYCINATEN MITTELS DIREKTOXIDATION
    2.
    发明申请
    VERFAHREN ZUR HERSTELLUNG VON ACYLGLYCINATEN MITTELS DIREKTOXIDATION 审中-公开
    用于生产酰基甘氨酸盐直接氧化法

    公开(公告)号：WO2008019807A1

    公开(公告)日：2008-02-21

    申请号：PCT/EP2007/007128

    申请日：2007-08-13

    Applicant: CLARIANT INTERNATIONAL LTD ,  KLUG, Peter ,  STANKOWIAK, Achim ,  FRANKE, Oliver ,  SCHERL, Franz-Xaver ,  PRÜSSE, Ulf ,  THIELECKE, Nadine ,  VORLOP, Klaus-Dieter

    Inventor： KLUG, Peter ,  STANKOWIAK, Achim ,  FRANKE, Oliver ,  SCHERL, Franz-Xaver ,  PRÜSSE, Ulf ,  THIELECKE, Nadine ,  VORLOP, Klaus-Dieter

    IPC: C07B41/10 ,  C07C231/02 ,  C07C233/30

    CPC classification number: C07C231/14 ,  C07C233/47 ,  C07C233/49

    Abstract: Es wird ein Verfahren zur Herstellung von Acylglycinatsalzen der Formel (II) beschrieben, worin R 1 einen gesättigten linearen oder verzweigten Alkylrest mit 1 bis 21 Kohlenstoffatomen oder einen ein- oder mehrfach ungesättigten linearen oder verzweigten Alkenylrest mit 2 bis 21 Kohlenstoffatomen und B ein Kation, das von einer Base abgeleitet ist, bedeutet, und/oder der entsprechenden protonierten Acylglycinsäuren, dadurch gekennzeichnet, dass ein oder mehrere Fettsäuremonoethanolamide der Formel (I) worin R 1 die oben angegebene Bedeutung besitzt, mit Sauerstoff in Gegenwart eines Nebengruppenmetallkatalysators im alkalischen Medium zu einem oder mehreren Acylglycinatsalzen der Formel (II) oxidiert werden und im Fall der Herstellung der protonierten Acylglycinsäuren das oder die Acylglycinatsalze der Formel (II) zusätzlich mit einer Säure umgesetzt werden.

    Abstract translation: 中描述了一种方法用于式（II）的酰基甘氨酸盐盐的制备，其中R 1 是饱和的直链或支链烷基具有1至21个碳原子或单 - 或多不饱和的直链或支链烯基基团具有2至 21个碳原子，B表示从碱衍生的阳离子，和/或相应的质子化的acylglycine酸，其特征在于在式（I）的一个或多个脂肪酸单乙醇酰胺，其中R 1 ，上面提到的 意，被氧化成式（II）的一个或多个酰基甘氨酸盐的盐和在的质子化acylglycine酸的，或式的Acylglycinatsalze（II）可进一步与一种酸与氧气在过渡金属催化剂的存在下在碱性介质中反应制备的情况下。

    METHOD FOR CATALYTICALLY PRODUCING ORGANIC SUBSTANCES BY PARTIAL OXIDATION
    3.
    发明申请
    METHOD FOR CATALYTICALLY PRODUCING ORGANIC SUBSTANCES BY PARTIAL OXIDATION 审中-公开
    方法制造中的催化有机材料部分氧化

    公开(公告)号：WO02012158A3

    公开(公告)日：2002-06-27

    申请号：PCT/EP2001/008002

    申请日：2001-07-11

    IPC: C07D307/89 ,  C07B41/06 ,  C07B41/10 ,  C07B61/00 ,  C07C46/08 ,  C07C50/18 ,  C07C51/215 ,  C07C51/25 ,  C07C51/265 ,  C07C51/31 ,  C07C53/08 ,  C07C57/05 ,  C07C57/055 ,  C07C63/16 ,  C07C63/26 ,  B01J8/04 ,  B01J8/18 ,  B01J8/02

    CPC classification number: C07C51/265 ,  C07C51/252 ,  C07C57/04 ,  C07C63/16 ,  C07C63/26

    Abstract: The invention relates to a method for catalytically producing organic substances by partial oxidation which is carried out in the gaseous phase in the presence of molecular oxygen at temperatures in the range of from 200 to 500 DEG C in at least one reactor that is configured as a cooled tubular reactor and that contains a catalyst. A coolant flows through the cooling pipes of the reactor and a gaseous mixed product is removed from the reactor. 40 to 100 % by weight of the total amount of the catalyst of the cooled tubular reactor are disposed on the exterior face of the cooling pipes in the form of a coating. The feedstock mixture containing the feedstock and the molecular oxygen is contacted with the catalytic layers. Preferably, at least half of the cooling pipes are designed as ribbed pipes with ribs projecting from the exterior of the pipe, and the ribs are at least partially coated with the catalyst.

    Abstract translation: 该方法是在气相中分子氧的在至少一个反应器中存在的温度下在200至500℃的范围内，其被构造为冷却管式反应器和含有催化剂进行。 将反应器的冷却管通过冷却液体，并从气态产物混合物中取出的反应器流动。 40〜100重量冷却管反应器中的冷却管被布置为在外侧的涂层的催化剂的总量，其中所述含有原料和分子氧进料混合物接触到催化剂层接触的％。 优选地，至少一半的冷却管被构造为翅片管与突出在外侧肋，其中所述肋至少部分地与催化剂涂覆。

    METHOD FOR CATALYTICALLY PRODUCING ORGANIC SUBSTANCES BY PARTIAL OXIDATION
    4.
    发明申请
    METHOD FOR CATALYTICALLY PRODUCING ORGANIC SUBSTANCES BY PARTIAL OXIDATION 审中-公开
    部分氧化催化生产有机物的方法

    公开(公告)号：WO0212158A2

    公开(公告)日：2002-02-14

    申请号：PCT/EP0108002

    申请日：2001-07-11

    Applicant: MG TECHOLOGIES AG ,  FRANZ VOLKEV ,  DOMES HELMUETH

    Inventor： FRANZ VOLKEV ,  DOMES HELMUETH

    IPC: C07D307/89 ,  C07B41/06 ,  C07B41/10 ,  C07B61/00 ,  C07C46/08 ,  C07C50/18 ,  C07C51/215 ,  C07C51/25 ,  C07C51/265 ,  C07C51/31 ,  C07C53/08 ,  C07C57/05 ,  C07C57/055 ,  B01J8/04 ,  B01J8/18 ,  C07C63/16 ,  C07C63/26

    CPC classification number: C07C51/265 ,  C07C51/252 ,  C07C57/04 ,  C07C63/16 ,  C07C63/26

    Abstract: The invention relates to a method for catalytically producing organic substances by partial oxidation which is carried out in the gaseous phase in the presence of molecular oxygen at temperatures in the range of from 200 to 500 DEG C in at least one reactor that is configured as a cooled tubular reactor and that contains a catalyst. A coolant flows through the cooling pipes of the reactor and a gaseous mixed product is removed from the reactor. 40 to 100 % by weight of the total amount of the catalyst of the cooled tubular reactor are disposed on the exterior face of the cooling pipes in the form of a coating. The feedstock mixture containing the feedstock and the molecular oxygen is contacted with the catalytic layers. Preferably, at least half of the cooling pipes are designed as ribbed pipes with ribs projecting from the exterior of the pipe, and the ribs are at least partially coated with the catalyst.

    Abstract translation: 该方法在分子氧存在下在气相中在200-500℃范围内的温度下在至少一个反应器中进行，该反应器被设计为冷却管反应器并且含有催化剂。 冷却流体流过反应器的冷却管，气体产物混合物从反应器中排出。 40〜100重量冷却管反应器中的冷却管被布置为在外侧的涂层的催化剂的总量，其中所述含有原料和分子氧进料混合物接触到催化剂层接触的％。 优选地，至少一半的冷却管被设计成具有在外侧突出的肋条的翅片管，其中翅片至少部分地涂覆有催化剂。

    PREPARING AN UNSATURATED CARBOXYLIC ACID SALT FROM AN ALKENE AND CARBON DIOXIDE USING A COVALENTLY IMMOBILIZED TRANSITION METAL COMPLEX
    5.
    发明申请
    PREPARING AN UNSATURATED CARBOXYLIC ACID SALT FROM AN ALKENE AND CARBON DIOXIDE USING A COVALENTLY IMMOBILIZED TRANSITION METAL COMPLEX 审中-公开
    使用共价固定的过渡金属络合物从碱和二氧化碳制备不饱和羧酸盐

    公开(公告)号：WO2015173295A1

    公开(公告)日：2015-11-19

    申请号：PCT/EP2015/060574

    申请日：2015-05-13

    Applicant: BASF SE

    Inventor： LIMBACH, Michael ,  FUTTER, Cornelia ,  SCHUNK, Stephan A. ,  LEJKOWSKI, Michael ,  GORDILLO, Alvaro ,  PRASETYO, Eko

    IPC: C07B41/08 ,  C07B41/10 ,  C07C51/15 ,  C07C57/04

    CPC classification number: C07C51/15 ,  C07C57/04

    Abstract: Process for preparing an α,β-ethylenically unsaturated carboxylic acid salt, comprising, reacting an alkene and carbon dioxide in the presence of a carboxylation catalyst and releasing the α,β-ethylenically unsaturated carboxylic acid salt with a base, wherein the carboxylation catalyst comprises a transition metal complex that is covalently immobilized on a solid support. The crude reaction product can be processed with little effort to obtain the carboxylic acid derivative at a purity level suitable for further processing into sanitary products.

    Abstract translation: 一种制备α，β-烯键式不饱和羧酸盐的方法，包括在羧化催化剂存在下使烯烃和二氧化碳反应并与碱释放α，β-烯属不饱和羧酸盐，其中羧化催化剂包括 共价固定在固体载体上的过渡金属络合物。 可以很少的努力处理粗反应产物，以获得适合于进一步加工成卫生产品的纯度水平的羧酸衍生物。

    PREPARATION OF α,β-ETHYLENICALLY UNSATURATED CARBOXYLIC SALTS BY CATALYTIC CARBOXYLATION OF ALKENES
    6.
    发明申请
    PREPARATION OF α,β-ETHYLENICALLY UNSATURATED CARBOXYLIC SALTS BY CATALYTIC CARBOXYLATION OF ALKENES 审中-公开
    通过催化羰基化制备α，β-乙烯基不饱和羧酸盐

    公开(公告)号：WO2013098772A1

    公开(公告)日：2013-07-04

    申请号：PCT/IB2012/057750

    申请日：2012-12-27

    Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED

    Inventor： LIMBACH, Michael ,  LINDNER, Ronald ,  LEJKOWSKI, Michael Ludwik ,  KAGEYAMA, Takeharu ,  BODIZS, Gabriella Eva ,  SCHUNK, Stephan ,  FUTTER, Cornelia ,  ROTHER, Jörg

    IPC: C07C51/15 ,  C07C51/41 ,  C07B41/08 ,  C07B41/10

    CPC classification number: C07B41/08 ,  C07B41/10 ,  C07C51/15 ,  C07C57/04

    Abstract: In a process for preparing an alkalimetalor alkaline earth metal salt of an α,β -ethylenically unsaturated carboxylic acid, a)a transition metal-alkene complex is reacted with CO 2 to give a metallalactone, b)the metallalactone is reacted with a base to give an adduct of the alkalimetal or alkaline earth metal salt of the α,β -ethylenically unsaturated carboxylic acid with the transition metal complex, and c)the adduct is reacted with an alkene to release the alkalimetalor alkaline earth metalsalt of the α,β -ethylenically unsaturated carboxylic acid and regenerate the transition metal-alkene complex. The baseis selected from alkalimetal or alkaline earth metal hydroxides and alkali metal or alkaline earth metal superbases.The alkene is, for example, ethene. The transition metal complex comprises, for example, nickel and a bidentate P,P, P,N, P,O or P,carbene ligand, such as 1,2-bis(di- tert -butylphosphino)ethane.

    Abstract translation: 在制备α，β-烯属不饱和羧酸的碱金属碱土金属盐的方法中，a）过渡金属 - 烯烃络合物与CO 2反应得到金属内酯，b）金属内酯与碱反应，得到 α，β-烯键式不饱和羧酸的碱金属或碱土金属盐与过渡金属络合物的加合物，和c）加合物与烯烃反应以释放α，β-烯属的碱金属盐碱金属盐 不饱和羧酸并再生过渡金属 - 烯烃络合物。 碱选自碱金属或碱土金属氢氧化物和碱金属或碱土金属超碱物。烯烃是例如乙烯。 过渡金属络合物包括例如镍和二齿P，P，P，N，P，O或P，卡宾配体，例如1,2-双（二叔丁基膦基）乙烷。

    IMPROVED CARBONYLATION PROCESS
    7.
    发明申请
    IMPROVED CARBONYLATION PROCESS 审中-公开
    改进的碳化过程

    公开(公告)号：WO2009123675A1

    公开(公告)日：2009-10-08

    申请号：PCT/US2009/001600

    申请日：2009-03-13

    Applicant: EASTMAN CHEMICAL COMPANY

    Inventor： ZOELLER, Joseph, Robert ,  MOORE, Mary, Kathleen

    IPC: C07B41/08 ,  C07B41/10 ,  C07B41/12 ,  C07C51/12 ,  C07C51/56 ,  C07C67/08 ,  C07C53/08 ,  C07C53/12 ,  C07C69/14

    CPC classification number: C07C67/36 ,  C07B41/00 ,  C07C51/12 ,  C07C51/56 ,  C07C67/37 ,  C07C53/08 ,  C07C53/12 ,  C07C69/14

    Abstract: Disclosed is an improved carbonylation process for the production of carboxylic acids, carboxylic acid esters, and/or carboxylic acid anhydrides wherein a carbonylation feedstock compound selected from one or more organic oxygenates such as alcohols, ethers, and esters is contacted with carbon monoxide in the presence of a carbonylation catalyst and one or more onium compounds. The carbonylation process differs from known carbonylation processes in that a halide compound, other than the onium salt, such as a hydrogen halide (typically, hydrogen iodide) and/or an alkyl halide (typically, methyl iodide), extraneous or exogenous to the carbonylation process is not fed or supplied to the process. The process can be improved by using a bidentate ligand comprising two functional groups selected from tertiary amines and tertiary phosphines, such as 2,2'-bipyridine and diphosphine derivatives.

    Abstract translation: 公开了用于生产羧酸，羧酸酯和/或羧酸酐的改进的羰基化方法，其中选自一种或多种有机含氧化合物如醇，醚和酯的羰基化原料化合物与一氧化碳在 存在羰基化催化剂和一种或多种鎓化合物。 羰基化方法与已知的羰基化方法不同之处在于除了卤化物（通常为碘化氢）和/或烷基卤（通常为甲基碘）之外的卤化物，对于羰基化是外来或外源的 过程没有进给或提供给过程。 通过使用包含选自叔胺和叔膦的两种官能团的二齿配体，例如2,2'-联吡啶和二膦衍生物，可以改进该方法。

    REACTIVE CHROMATOGRAPHY PROCESS FOR EQUILIBRIUM-LIMITED REACTIONS
    10.
    发明申请
    REACTIVE CHROMATOGRAPHY PROCESS FOR EQUILIBRIUM-LIMITED REACTIONS 审中-公开
    平衡有限反应的反应色谱法

    公开(公告)号：WO2014179706A3

    公开(公告)日：2014-12-31

    申请号：PCT/US2014036602

    申请日：2014-05-02

    Applicant: DOW GLOBAL TECHNOLOGIES LLC

    Inventor： FRANK TIMOTHY C ,  DONALDSON MEGAN E

    IPC: C07C67/03 ,  B01D15/38 ,  C07B41/10 ,  C07C69/14

    CPC classification number: C07B41/12 ,  B01D15/1821 ,  B01D15/1857 ,  B01D15/363 ,  B01D15/3857 ,  C07B41/02 ,  C07C29/1285 ,  C07C67/03 ,  Y02P20/127 ,  C07C69/14

    Abstract: The present disclosure provides for a process for an equilibrium limited reaction using reactive chromatography unit (RCU) in which a first organic donor reactant (FODR) and a second organic acceptor reactant (SOAR) react to form a product mixture of a first acceptor product (FAP) and a second donor co-product (SDCP). The equilibrium-limited reaction does not produce water. The RCU has separation media to separate the product mixture into a raffinate and an extract. The FODR is in a stoichiometric deficit relative to the SOAR for the equilibrium limited reaction, so that the SOAR acts as the eluent for both the raffinate and the extract, and so as not to produce an azeotrope of FODR and the SDCP in the extract.

    Abstract translation: 本公开提供使用反应性色谱单元（RCU）的平衡限制反应的方法，其中第一有机供体反应物（FODR）和第二有机受体反应物（SOAR）反应以形成第一受体产物（ FAP）和第二供体共同产物（SDCP）。 平衡有限的反应不产生水。 RCU具有分离介质以将产物混合物分离成萃余液和提取物。 FODR相对于SOAR为平衡有限反应的化学计量缺口，使得SOAR作为萃余液和提取物的洗脱液，并且不产生FODR和提取物中的SDCP的共沸物。

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