繊維構造物の恒久・耐久撥水加工法
    1.
    发明申请
    繊維構造物の恒久・耐久撥水加工法 审中-公开
    将永久长寿命水再循环至纺织结构的方法

    公开(公告)号:WO2013136544A1

    公开(公告)日:2013-09-19

    申请号:PCT/JP2012/068116

    申请日:2012-07-17

    摘要:  本発明により、繊維改質剤として、(A)2,6-ジクロロ-4-ヒドロキシ-1,3,5-トリアジンナトリウム塩と、(B)ジアミノベンゼンスルホン酸アルカリ塩との反応混合物であって、(A)と(B)とのモル比が(A):(B)=1:1~1:3である反応混合物を繊維構造物に適用することを含む、繊維構造物の製造方法を提供する。本発明によれば、炭素数6以下のフッ素系撥水剤を用いた場合にも、現在要求されている100回以上の実用洗濯にも耐えられるほど、恒久的な耐久性のある撥水性繊維構造物を得ることができる。

    摘要翻译: 本发明提供一种纺织结构体的制造方法,其包括将(A)2,6-二氯-4-羟基-1,3,5-三嗪的钠盐与(B)碱金属盐 的(A)/(B)摩尔比为(A):(B)= 1:1〜1:3的二氨基苯磺酸,作为织物结构的纤维改性剂。 即使使用具有6个或更少碳原子的氟化学防水剂,也可以获得具有防水性的纺织结构,它具有足够的耐久性,能承受目前实际洗涤的100次或更多次的操作。

    A PROCESS FOR IMPROVING THE SUN PROTECTION FACTOR OF CELLULOSIC FIBRE MATERIAL
    3.
    发明申请
    A PROCESS FOR IMPROVING THE SUN PROTECTION FACTOR OF CELLULOSIC FIBRE MATERIAL 审中-公开
    提高纤维素纤维材料的太阳能保护因子的方法

    公开(公告)号:WO01049924A3

    公开(公告)日:2001-12-06

    申请号:PCT/EP2001/000052

    申请日:2001-01-04

    IPC分类号: D06L3/12 D06M13/358

    摘要: A process for improving the sun protection factor (SPF) of cellulosic fibre materials and blends thereof, which comprises contacting said materials with at least one compound of the formula (1), whereby R1 represents hydrogen or C1-C4alkyl; R2 represents hydrogen, c1-c4alkyl, C1-C4alkoxy, halogen or SO3M, M being hydrogen or an alkali or alkaline earth metal; X1 is chlorine, fluorine, NR3R4, OR3 or SR3, wherein R3 represents hydrogen, C1-C4alkyl or C1-C4alkoxy, which are unsubstituted or substituted by one or more SO3M, OSO3M, COOM or OH groups, C2-C4hydroxyalkoxy, C1-C4alkoxy-C1-C4alkoxy or phenyl, which is unsubstituted or substituted by one or more SO3M, COOM, OH, halogen or C1-C4alkyl groups and R4 represents hydrogen, C1-C4alkyl, C2-C4hydroxyalkoxy, C1-C4alkoxoxy-C1-C4alkoxy or phenyl, or R3 and R4, together with the nitrogen atom, form a pyrrolidine, piperidine or morpholine ring; X2 is chlorine, when X1 is chlorine, or X2 is fluorine, when X1 is, NR3R4, OR3 or SR3 and Z is a fibre reactive group, whereby the cellulosic fibre material may also be treated with a fluorescent whitening agent either before, during or after contact with the compound of formula (1).

    摘要翻译: 本发明涉及改进纤维素纤维材料和这些材料的混合物的防晒因子(SPF)的方法。 此方法包括这些材料与配方中的至少一种化合物接触(1)其中R1表示氢或C1-C4烷基; R2代表氢,C1-C4烷基,C1-C4烷氧基,卤素或SO3M,M是氢或碱金属或碱土金属; X 1表示氯,氟,NR 3 R 4,OR 3或SR 3,其中R 3代表氢,C1-C4烷基或C1-C4烷氧基未被取代或被一个或多个基团SO 3 M,OSO 3 M,COOM或OH取代,羟基C2-C4,烷氧基C1 C4烷氧基C1-C4烷基或苯基未被取代或被一个或多个-SO 3 M基团,COOM,OH,卤素或C1-C4烷基和R4是氢,C1-C4烷基,羟基 - C2-C4 alcoxoxy C1-C4烷氧基C1取代的 -C4或苯基,R3和R4与氮原子一起形成吡咯烷,哌啶或吗啉环; 当X1是氯时X2是二氢卟酚或当X1是NR3R4,OR3或SR3时X2是氟; Z是纤维状反应性基团。 根据本发明的纤维素纤维材料也可以与荧光增白剂之前,期间或与式(1)的化合物接触后处理。

    A PROCESS FOR IMPROVING THE SUN PROTECTION FACTOR OF CELLULOSIC FIBRE MATERIAL
    5.
    发明申请
    A PROCESS FOR IMPROVING THE SUN PROTECTION FACTOR OF CELLULOSIC FIBRE MATERIAL 审中-公开
    一种改进纤维素纤维材料的保护因子的方法

    公开(公告)号:WO0149924A2

    公开(公告)日:2001-07-12

    申请号:PCT/EP0100052

    申请日:2001-01-04

    IPC分类号: D06L3/12 D06M13/358 D06M13/00

    摘要: A process for improving the sun protection factor (SPF) of cellulosic fibre materials and blends thereof, which comprises contacting said materials with at least one compound of the formula (1), whereby R1 represents hydrogen or C1-C4alkyl; R2 represents hydrogen, c1-c4alkyl, C1-C4alkoxy, halogen or SO3M, M being hydrogen or an alkali or alkaline earth metal; X1 is chlorine, fluorine, NR3R4, OR3 or SR3, wherein R3 represents hydrogen, C1-C4alkyl or C1-C4alkoxy, which are unsubstituted or substituted by one or more SO3M, OSO3M, COOM or OH groups, C2-C4hydroxyalkoxy, C1-C4alkoxy-C1-C4alkoxy or phenyl, which is unsubstituted or substituted by one or more SO3M, COOM, OH, halogen or C1-C4alkyl groups and R4 represents hydrogen, C1-C4alkyl, C2-C4hydroxyalkoxy, C1-C4alkoxoxy-C1-C4alkoxy or phenyl, or R3 and R4, together with the nitrogen atom, form a pyrrolidine, piperidine or morpholine ring; X2 is chlorine, when X1 is chlorine, or X2 is fluorine, when X1 is, NR3R4, OR3 or SR3 and Z is a fibre reactive group, whereby the cellulosic fibre material may also be treated with a fluorescent whitening agent either before, during or after contact with the compound of formula (1).

    摘要翻译: 一种用于改善纤维素纤维材料及其共混物的防晒因子(SPF)的方法,其包括使所述材料与至少一种式(1)化合物接触,由此R1表示氢或C1-C4烷基; R 2表示氢,C 1 -C 4烷基,C 1 -C 4烷氧基,卤素或SO 3 M,M为氢或碱金属或碱土金属; X 1是氯,氟,NR 3 R 4,OR 3或SR 3,其中R 3表示氢,C 1 -C 4烷基或C 1 -C 4烷氧基,其未被取代或被一个或多个SO 3 M,OSO 3 M,COOM或OH基团取代,C 2 -C 4羟基烷氧基,C 1 -C 4烷氧基 C 1 -C 4烷氧基或苯基,其未被取代或被一个或多个SO 3 M,COOM,OH,卤素或C 1 -C 4烷基取代,R 4表示氢,C 1 -C 4烷基,C 2 -C 4羟基烷氧基,C 1 -C 4烷氧基氧基-C 1 -C 4烷氧基或苯基 或R3和R4与氮原子一起形成吡咯烷,哌啶或吗啉环; X 1为氯时,X 1为氯时,X 2为氟,X 1为NR 3 R 4,OR 3或SR 3,Z为纤维反应性基团时,纤维素纤维材料也可以在荧光增白剂前, 与式(1)化合物接触后。

    PROCESS FOR TREATING CELLULOSIC FIBRES
    10.
    发明申请
    PROCESS FOR TREATING CELLULOSIC FIBRES 审中-公开
    处理纤维素纤维的方法

    公开(公告)号:WO2008154671A1

    公开(公告)日:2008-12-24

    申请号:PCT/AT2008/000223

    申请日:2008-06-20

    摘要: The present invention relates to a process for treating cellulosic fibres and for compounds that are suitable to be used in said process. According to the process of the invention, the cellulosic fibres are contacted with a textile auxiliary agent of the general formula (I) wherein: n = 0 or 1; X = halogen, especially Cl or Br, alkoxyl, hydroxyl, optionally substituted alkyl or arylamino; Z = a vinyl group, or a group -CH 2 CH 2 -U, where U is a group displaceable by alkali, e.g. Cl, OSO 3 H or SSO 3 H; A and B can be the same or different and may be H, methyl, methoxyl or a sulphonic acid group; D = an optionally substituted alkyl, aralkyl or aryl group; Y = a primary or secondary amino group; R and R1 independently are H, methyl or ethyl, or a salt thereof, respectively.

    摘要翻译: 本发明涉及一种处理纤维素纤维的方法和适用于所述方法的化合物。 根据本发明的方法,纤维素纤维与通式(I)的织物助剂接触,其中:n = 0或1; X =卤素,特别是Cl或Br,烷氧基,羟基,任选取代的烷基或芳基氨基; Z =乙烯基或基团-CH 2 CH 2 -U,其中U是可被碱取代的基团,例如 Cl,OSO3H或SSO3H; A和B可以相同或不同,可以是H,甲基,甲氧基或磺酸基团; D =任选取代的烷基,芳烷基或芳基; Y =伯或仲氨基; R和R 1分别独立地是H,甲基或乙基,或其盐。