摘要:
Process for the preparation of formic acid by reacting carbon dioxide with hydrogen in a hydrogenation reactor in the presence of a catalyst comprising an element from the 8th, 9th or 10th group of the Periodic Table of the Elements, of a tertiary amine and of a polar solvent, with formation of formic acid-amine adducts, which are then cleaved thermally to give formic acid and tertiary amine.
摘要:
The invention relates to an aqueous polymer dispersion containing a polymer, which can be produced by a radically initiated emulsion polymerization from ethylenically unsaturated, radically polymerizable monomers, wherein the polymerization of the monomers is carried out in the presence of a specific molecular weight regulator composition. The molecular weight regulator composition contains at least one mercaptoalkylcarboxylic acid ester of a C2 to C4 carboxylic acid and at least one oligomeric compound of formula R 1 -X-(A-S-) n -A-Y-R 2 , where R 1 and R 2 denote H or CH 3 -(CH 2 ) 0-2 -C(=0)-, X and Y denote an oxygen atom or a sulfur atom, A denotes a divalent C 1 - to C 18 -alkylene group, and n denotes a number from 1 to 8. The invention further relates to a method for producing the aqueous polymer dispersion. The polymer dispersion can be used as a binder, adhesive, sizing agent for fibers, for producing coatings or for producing paper coating compounds.
摘要:
The invention relates to a method for producing 3-pentenenitrile, characterised by the following steps: (a) isomerisation of an educt stream containing 2-methyl-3-butenenitrile on at least one dissolved or dispersed isomerisation catalyst to form a stream (1), which contains the isomerisation catalyst(s), 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile; (b) distillation of the stream (1) to obtain a stream (2) as the overhead product, which contains 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile and a stream (3) as the bottom product, which contains the isomerisation catalyst(s); (c) distillation of the stream (2) to obtain a stream (4) as the overhead product, which is enriched with (Z)-2-methyl-2-butenenitrile in comparison to stream (2), (in relation to the sum of all pentenenitriles in stream (2)) and a stream (5) as the bottom product, which is enriched with 3-pentenenitrile and 2-methyl-3-butenenitrile in comparison to stream (2), (in relation to the sum of all pentenenitriles in stream (2); (d) distillation of stream (5) to obtain a stream (6) as the bottom product, which contains 3-pentenenitrile and a stream (7) as the head product, which contains 2-methyl-3-butenenitrile.
摘要:
The present invention provides a process for the epoxidation of propene which comprises reacting propene with hydrogen peroxide in the presence of methanol as solvent and a titanium zeolite catalyst, the process further comprising separating propylene oxide from the reaction mixture to obtain a mixture comprising methanol, water, at least one carboxylic acid and at least one carbonyl compound, wherein the at least one carboxylic acid is at least partially neutralized, said process optionally comprising a hydrogenation stage.
摘要:
The invention relates to a method for producing propylene oxide, at least comprising steps (i) and (ii): (i) providing a catalyst containing at least one porous oxidic material; (ii) reacting propene with a hydroperoxide in at least one nitrile serving as a solvent or in a solvent mixture containing at least one nitrile in the presence of the catalyst in accordance with (i). The invention is characterized in that at least one porous oxidic material is a zeolite having a radiographic correspondence to the MWW type.
摘要:
The invention relates to a method for the production of propylene oxide, comprising the following steps: (a) propene is reacted with hydrogen peroxide in a solvent in the presence of a suitable catalyst in order to obtain a mixture (G0) of propylene oxide, solvent, unreacted propene, unreacted hydrogen peroxide and oxygen, (b) the propylene oxide is separated from the mixture (G0) in such a way that a mixture (G1) of unreacted propene and oxygen is obtained, and (c) the mixture (G1) is used.