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21.发明公开VERWENDUNG VON TRIS(TRIFLUOROMETHYLSULFONYL)METHAN UND DESSEN ALKALI- UND ERDALKALIMETALLSALZEN ALS KATALYSATOREN BEI C-C VERKNÜPFENDEN SYNTHESEN UND DAS NEUE Mg-SALZ VON TRIS(TRIFLUOROMETHYLSULFONYL)METHAN 有权USE TRIS（三氟甲基磺酰基）甲烷和其碱和碱性AS FOR C-C连接的合成和TRIS THE NEW Mg盐（三氟甲基磺酰基）甲烷催化剂的
公开(公告)号：EP0998351A1
公开(公告)日：2000-05-10
申请号：EP98954341.8
申请日：1998-10-05
申请人： MERCK PATENT GmbH
发明人： BUCHHOLZ, Herwig , FRANZ, Klaus-Dieter , MAYR, Herbert , FUNKE, Marcus-Alexander , ZEHETNER, Andrea
IPC分类号： B01J31/02
CPC分类号： B01J31/122 , B01J31/0227 , B01J31/4015 , B01J2231/326 , B01J2231/4205 , C07C1/321 , C07C41/30 , C07C45/46 , C07C45/69 , C07C49/675 , C07C67/347 , C07C67/475 , C07C227/02 , C07C317/04 , Y02P20/584 , C07C15/50 , C07C15/44 , C07C49/784 , C07C49/76 , C07C49/84 , C07C49/543 , C07C69/753 , C07C69/738 , C07C43/215 , C07C43/2055
摘要： Compounds are used as catalysts according to general formula (1) M+x(C(SO2CF3)3)x whereby x is equal to 1 or 2; M represents one hydrogen or alkaline metal atom when x equals 1; and M represents one alkaline-earth metal atom when x equals 2. The invention also relates to a novel Mg compound of formula (1).
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公开(公告)号：EP0901453A1
公开(公告)日：1999-03-17
申请号：EP97923387.0
申请日：1997-05-14
申请人： Labwell AB
IPC分类号： B01J19 , C07B37 , C07B61 , C07C1 , C07C2 , C07C17 , C07C45 , C07C67 , C07C209 , C07C213 , C07C231 , C07C253 , C07D209 , C07D307 , C07D333
CPC分类号： C07D333/08 , B01J19/126 , C07B37/00 , C07C1/321 , C07C2/861 , C07C17/266 , C07C45/515 , C07C45/68 , C07C67/343 , C07C209/68 , C07C213/08 , C07C231/12 , C07C253/30 , C07D209/18 , C07D307/28 , C40B40/04 , C40B50/14 , C07C15/14 , C07C15/50 , C07C25/24 , C07C49/76 , C07C49/784
摘要： The present invention relates to a method for organic reactions. More specifically, a method for palladium, except Pd/C, catalyzed organic reactions comprising a heating step with microwave energy. One type of organic reactions concerned are coupling reactions, in which new carbon-carbon bonds are formed. Preferred reactions are the Heck, Stille and Suzuki reactions. The method provides high yields in very short reaction times.
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公开(公告)号：EP0849246A3
公开(公告)日：1998-09-23
申请号：EP97810972.6
申请日：1997-12-11
IPC分类号： C07C33/28 , C07C15/50 , C07C1/24 , C07C309/32
CPC分类号： C07C309/32 , C07C1/24 , C07C15/50 , C07C29/60 , C07C33/28 , C07C303/22 , C07C2531/025
摘要： The present invention provides compounds having the formula:
in which R is hydrogen or C 1 -C 4 alkyl, preferably hydrogen and Y is hydrogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy, CF 3 , halogen (F, Cl, Br or I) or SO 3 M in which M is H, Na, K, Ca, Mg, ammonium, mono-, di-, tri- or tetra-C 1 -C 4 alkylammonium, mono-, di- or tri-hydroxyalkylammonium or ammonium that is di- or tri-substituted with a mixture of C 1 -C 4 alkyl and C 1 -C 4 hydroxyalkyl groups; a process for their production by partial dehydration of compounds having the formula:
; and their use as intermediates in the production of asymmetric or symmetric fluorescent whitening agents.摘要翻译： 本发明提供了具有下式的化合物：其中R是氢或C1-C4烷基，优选氢，Y是氢，C1-C4烷基，C1-C4烷氧基，CF3，卤素（F，Cl，Br或I） M是H，Na，K，Ca，Mg，铵，单 - ，二 - ，三 - 或四-C1-C4烷基铵，单 - ，二 - 或三 - 羟烷基铵或铵 C1-C4烷基和C1-C4羟烷基的混合物; 通过使具有下式的化合物部分脱水来制备它们的方法： 以及它们作为生产不对称或对称荧光增白剂的中间体的用途。
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24.发明授权VERFAHREN ZUR HERSTELLUNG VON 3-ARYL-PROPINEN UND NEUE 3-ARYL-PROPINE 失效PROCESS FOR的3-芳基PROPINEN和新的3-芳基propynes的制备
公开(公告)号：EP0741681B1
公开(公告)日：1998-05-20
申请号：EP95906983.2
申请日：1995-01-20
申请人： BAYER AG
发明人： LAUE, Christian
IPC分类号： C07B37/04 , C07C41/30 , C07C43/215 , C07D307/33 , C07D309/12 , C07F7/18
CPC分类号： C07D307/33 , C07B37/04 , C07C2/861 , C07C41/30 , C07C69/734 , C07C2527/13 , C07C2531/04 , C07C2531/22 , C07F7/083 , C07F7/1892 , C07C15/50 , C07C43/23 , C07C43/215
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公开(公告)号：EP0641756B1
公开(公告)日：1997-07-02
申请号：EP94303125.2
申请日：1994-04-29
CPC分类号： C07C15/50 , C07C2/04 , C07C2531/025
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26.发明公开VERFAHREN ZUR HERSTELLUNG VON 3-ARYL-PROPINEN UND NEUE 3-ARYL-PROPINE 失效PROCESS FOR的3-芳基PROPINEN和新的3-芳基propynes的制备
公开(公告)号：EP0741681A1
公开(公告)日：1996-11-13
申请号：EP95906983.0
申请日：1995-01-20
申请人： BAYER AG
发明人： LAUE, Christian
IPC分类号： B01J31 , C07B37 , C07B61 , C07C2 , C07C11 , C07C33 , C07C41 , C07C43 , C07C67 , C07C69 , C07D307 , C07D309 , C07F7
CPC分类号： C07D307/33 , C07B37/04 , C07C2/861 , C07C41/30 , C07C69/734 , C07C2527/13 , C07C2531/04 , C07C2531/22 , C07F7/083 , C07F7/1892 , C07C15/50 , C07C43/23 , C07C43/215
摘要： The invention relates to a process for producing 3-aryl propines in which alkines are reacted with benzyl halides in the presence of a palladium compound and weak bases, and to some novel 3-aryl propines.
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27.发明授权Method for improving the electrical insulating characteristics of a fraction, electrical insulating substance, and electrical appliances containing the same 失效用于提高电绝缘材料的一小部分的电绝缘性能和一种方法，含有这些物质的电气装置
公开(公告)号：EP0281162B1
公开(公告)日：1996-06-12
申请号：EP88104568.6
申请日：1983-12-23
CPC分类号： H01G4/221 , C07C5/3332 , H01B3/22 , C07C15/50
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28.发明公开1,2-Di(4-isobutylphenyl) ethane and its preparation and use as intermediate 失效1,2-二（4-异丁基苯基）乙烷，其中Herstellung und ihre Verwendung als Zwischenprodukt。
公开(公告)号：EP0470651A1
公开(公告)日：1992-02-12
申请号：EP91117463.9
申请日：1988-05-06
CPC分类号： C07C57/30 , C07C2/861 , C07C4/00 , C07C5/03 , C07C6/04 , C07C15/18 , C07C15/52 , C07C25/18 , C07C51/14 , C07C2521/08 , C07C2521/12 , C07C2521/16 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2527/173 , C07C2529/04 , C07C2531/025 , C07C15/50 , C07C15/46
摘要： Novel compound 1,2-di(isobutylphenyl)ethane and method for preparing 4-isobutylstyrene and a-(4-isobutylphenyl)propionic acid from this compound. In the preparation of 4-isobutylstyrene from the former compound by cracking or disproportionation, the components in the resultant reaction mixture can be separated without difficulty, the formation of by-product isobutylbenzene can be avoided, and the remaining unreacted starting material can be reused for the same reaction without causing any adverse effect on the catalyst.
摘要翻译： 新型化合物1,2-二异丁基苯乙烷及其制备4-异丁基苯乙烯和α-（4-异丁基苯基）丙酸的方法。 在通过裂化或歧化从前一化合物制备4-异丁基苯乙烯时，可以难以分离所得反应混合物中的组分，可以避免副产物异丁苯的形成，并且剩余的未反应的起始原料可以重新用于 相同的反应而不会对催化剂造成任何不利影响。
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29.发明公开
公开(公告)号：EP0281162A3
公开(公告)日：1990-08-29
申请号：EP88104568.6
申请日：1983-12-23
CPC分类号： H01G4/221 , C07C5/3332 , H01B3/22 , C07C15/50
摘要： The electrical insulating characteristics of a hydrocarbon fraction which is obtained by reacting an aromatic hydrocarbon or hydrocarbons with an alkylating agent in the presence of alkylating catalyst to produce an alkylation product mainly consisting of mono- and polyalkylated aromatic hydrocarbons, diarylalkanes, heavier products and unreacted substances, then separating unreacted substances and mono- and polyalkylated aromatic hydrocarbons to obtain a separated fraction, and if required, refining said separated fraction, are improved by a process which comprises dehydrogenating said fraction at a temperature in the range of 350 to 650°C in the presence of a dehydrogenation catalyst to obtain a dehydrogenated reaction mixture containing at least 0.5 % by weight of an aromatic monoolefin or diolofin having two condensed or non-condensed aromatic nuclei.
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公开(公告)号：EP0290050A1
公开(公告)日：1988-11-09
申请号：EP88107351.4
申请日：1988-05-06
CPC分类号： C07C57/30 , C07C2/861 , C07C4/00 , C07C5/03 , C07C6/04 , C07C15/18 , C07C15/52 , C07C25/18 , C07C2521/08 , C07C2521/12 , C07C2521/16 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2527/173 , C07C2529/04 , C07C2531/025 , C07C15/50 , C07C15/46
摘要： A method for producing alkylstyrene which is characterized in that 1,2-di(substituted phenyl)ethane is brought into contact with an acid catalyst at 200°C to 650°C in the presence of an inert gas to crack it into alkylstyrene and alkylbenzene. The method of the invention has advantages in that the operation of reaction and separation of reaction mixture are quite easy, the lowering of catalytic activity is small, and unreacted starting material can be reused.
摘要翻译： 一种烷基苯乙烯的制造方法，其特征在于，在惰性气体存在下，使1,2-二（取代苯基）乙烷与酸催化剂在200〜650℃下接触，将其裂解成烷基苯乙烯和烷基苯 。 本发明的方法的优点在于反应混合物的反应和分离操作相当容易，催化活性降低，可以重复使用未反应的原料。
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