CLATHRATE COMPOUND, CURING CATALYST, COMPOSITION FOR FORMING CURED RESIN, AND CURED RESIN
    21.
    发明公开
    CLATHRATE COMPOUND, CURING CATALYST, COMPOSITION FOR FORMING CURED RESIN, AND CURED RESIN 有权
    包合物催化剂进行硬化,形成组合物的固化树脂和树脂固化

    公开(公告)号:EP2103600A1

    公开(公告)日:2009-09-23

    申请号:EP06842980.2

    申请日:2006-12-21

    Abstract: The present invention provides a curing catalyst (clathrate compound) for which the curing reaction is suppressed at low temperatures, allowing an improvement in the one-pot stability, but which can effectively cure a resin upon heat treatment. The clathrate compound comprises at least an isophthalic acid compound represented by a formula (I) [wherein R 1 represents a C1 to C6 alkyl group or the like] and an imidazole compound represented by a formula (II) [wherein R 2 represents a hydrogen atom or a C1 to C10 alkyl group or the like, and R 3 to R 5 each independently represents a hydrogen atom or a nitro group or the like].

    Abstract translation: 本发明提供一种固化反应在低温下抑制,允许在单液稳定性提高的固化催化剂(包合化合物),但可有效固化通过热处理的树脂。 笼形化合物至少包含在由式(I)所示的间苯二甲酸化合物[worin,R 1 darstellt一个C1至C6烷基或等]由式(II)表示并咪唑化合物的worin [R 2表示氢 原子或C1-C10烷基或类似物,且R 3至R 5各自独立地darstellt氢原子或硝基或等]。

    Diamine chain extenders in polyurethane-ureas and process of manufacture
    30.
    发明公开
    Diamine chain extenders in polyurethane-ureas and process of manufacture 失效
    二胺增链剂在聚氨酯脲和它们的制备方法。

    公开(公告)号:EP0677542A3

    公开(公告)日:1996-06-26

    申请号:EP95105209.1

    申请日:1995-04-06

    CPC classification number: C08G18/3243 C07C205/57 C07C229/60

    Abstract: Polyurethane-urea elastomers are made using as a chain extender 2-methyl-1,3-propanediol-bis-p-aminobenzoate which is the reduction product from hydrogenating 2-methyl-1,3-propanediol-bis-p-nitrobenzoate. The latter composition is preferably made by esterifying p-nitrobenzoic acid and 2-methyl-1,3-propanediol using a stoichiometric excess of the diol initially, adequate to render the reaction mixture processible, and after converting to a nonvolatile form sufficient diol to form diester with substantially all of the acid, removing free diol by distillation while continuing the esterification of unreacted acid and transesterification of monoester formed to diester. This process, which can be applied broadly to esterification of other nitroaromatic acids with other aliphatic diols, produces high yields of diester without needing extraneous solvent for processibility and with only water as a by-product. The 2-methyl-1,3-propanediol-bis-p-aminobenzoate exhibits reactivity and processing characteristics which make it a suitable drop-in replacement for MoCA in polyurethane-urea elastomer manufacture.

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