VERFAHREN ZUR HERSTELLUNG VON PORÖSEN METALLORGANISCHEN GERÜSTMATERIALIEN
    31.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON PORÖSEN METALLORGANISCHEN GERÜSTMATERIALIEN 有权
    用于生产多孔金属有机骨架

    公开(公告)号:EP2027307A2

    公开(公告)日:2009-02-25

    申请号:EP07729006.2

    申请日:2007-05-11

    Applicant: BASF SE

    CPC classification number: C25B3/12

    Abstract: The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode containing metal corresponding to the at least one metal ion in a reaction medium in the presence of at least a first organic compound, where the first organic compound is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons are replaced by heteroatoms selected from the group consisting of N, O and S, to form a reaction intermediate containing at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with an at least second organic compound which coordinates to the at least one metal ion, where the second organic compound is derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.

    VERFAHREN ZUR HERSTELLUNG METALLORGANISCHER GERÜSTMATERIALIEN MIT METALLEN DER IV. NEBENGRUPPE
    34.
    发明公开
    VERFAHREN ZUR HERSTELLUNG METALLORGANISCHER GERÜSTMATERIALIEN MIT METALLEN DER IV. NEBENGRUPPE 审中-公开
    制造有机金属骨架材料与IV。侧基金属的方法

    公开(公告)号:EP2010547A1

    公开(公告)日:2009-01-07

    申请号:EP07728243.2

    申请日:2007-04-18

    Applicant: BASF SE

    CPC classification number: C07F7/006 C07C51/412 C07C63/28

    Abstract: The invention relates to methods for producing a porous metal-organic framework material which contains at least one at least bidentate compound that is coordinately bound to at least one metal ion. Said method comprises the step of reacting at least one metal compound with at least one at least bidentate organic compound which is capable of coordinately binding to the metal. The metal ion of the at least one metal compound is selected from the group of metals including titanium, zirconium, and hafnium. The at least bidentate compound is derived from a di-, tri- or tetracarboxylic acid and the metal compound is an inorganic salt.

    PROCESS FOR THE SEPARATION OF UNBRANCHED HYDROCARBONS FROM THEIR BRANCHED ISOMERS
    38.
    发明授权
    PROCESS FOR THE SEPARATION OF UNBRANCHED HYDROCARBONS FROM THEIR BRANCHED ISOMERS 有权
    方法用于分离的支链烃不会从支化异构

    公开(公告)号:EP2176201B1

    公开(公告)日:2014-06-04

    申请号:EP08774533.7

    申请日:2008-06-30

    Applicant: BASF SE

    Abstract: The present invention relates to a process for the separation of at least one unbranched C4-C2O hydrocarbon from a fluid mixture containing the unbranched hydrocarbon and at least one branched isomer of the unbranched hydrocarbon, which comprises the step of-contacting the fluid mixture with an adsorbent comprising a porous metal organic framework material, which material comprises at least one at least bidentate organic compound coordinately bound to at least one metal ion, to get the unbranched hydrocarbon adsorbed, wherein the at least one at least bidentate organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived from at least one heterocycle selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens and is unsubstituted or bears one or more substituents selected independently from the group consisting of halogen, Ci-6-alkyl, phenyl, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl, where the substituents Ci_6-alkyl and phenyl are unsubstituted or bear one or more substituents selected independently from the group consisting of halogen, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl. The present invention also relates to the use of said porous metal-organic framework material in a process for the separation of unbranched hydrocarbons from their branched isomers.

    KATALYSATOR ZUR OXIDATION VON SO2 ZU SO3
    39.
    发明公开
    KATALYSATOR ZUR OXIDATION VON SO2 ZU SO3 审中-公开
    KATALYSATOR ZUR氧化VON SO2 ZU SO3

    公开(公告)号:EP2558198A1

    公开(公告)日:2013-02-20

    申请号:EP11768541.2

    申请日:2011-04-12

    Applicant: BASF SE

    Abstract: A catalyst for the oxidation of SO
    2 to SO
    3 , a process for producing it and its use in a process for the oxidation of SO
    2 to SO
    3 are provided. The catalyst comprises an active substance comprising vanadium, alkali metal compounds and sulfate applied to a support comprising naturally occurring diatomaceous earths, wherein the support comprises at least two different naturally occurring uncalcined diatomaceous earths which differ in terms of the structure type of the siliceous algae from which they are derived.

    Abstract translation: 提供了用于将SO 2氧化成SO 3的催化剂,其制备方法及其在将SO 2氧化成SO 3的方法中的用途。 所述催化剂包含含有钒,碱金属化合物和硫酸盐的活性物质,所述活性物质施加到包含天然存在的硅藻土的载体上,其中所述载体包含至少两种不同的天然存在的未煅烧硅藻土,所述硅藻土的硅酸盐结构类型不同 它们来源于它们。

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