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    ORGANIC NITRILE DERIVATIVES AND THEIR USE AS PESTICIDES
    44.
    发明公开
    ORGANIC NITRILE DERIVATIVES AND THEIR USE AS PESTICIDES 审中-公开
    ORGANISCHE NITRILDERIVATE UND IHRE ANWENDUNG ALS PESTIZIDE

    公开(公告)号：EP1049663A1

    公开(公告)日：2000-11-08

    申请号：EP99907393.5

    申请日：1999-01-20

    申请人： Novartis AG ,  Novartis-Erfindungen Verwaltungsgesellschaft m.b.H.

    发明人： HALL, Roger, Graham ,  STEIGER, Arthur ,  HÜTER, Ottmar, Franz ,  PASCUAL, Alfons ,  KRIZ, Miroslav ,  TRAH, Stephan

    IPC分类号： C07C255/66 ,  C07C317/32 ,  C07C323/48 ,  C07D307/32 ,  C07D333/12 ,  C07D213/53 ,  A01N37/34 ,  A01N41/10 ,  A01N43/08 ,  A01N43/10

    CPC分类号： C07C255/66 ,  A01N37/34 ,  A01N41/08 ,  A01N43/08 ,  A01N43/10 ,  A01N43/40 ,  A01N43/80 ,  A01N43/82 ,  A01N47/28 ,  A01N47/34 ,  C07C311/16 ,  C07C317/34 ,  C07C317/44 ,  C07C323/36 ,  C07C323/62 ,  C07C2601/02 ,  C07D213/53 ,  C07D271/08 ,  C07D275/03 ,  C07D307/74 ,  C07D333/44

    摘要： Compounds of formula (I), wherein: A1 and A2 each represent independently of one other an aryl or a heteroaryl radical; and A1 where appropriate is substituted with substituent (R3a)n1 and A2 where appropriate with substituent (R3b)n2; n1 and n2 are independently of one another 0, 1, 2, 3 or 4; and either R3a and R3b independently of one another are for example halogen, C1-C6alkyl, C2-C4alkinyl, halogen-C1-C6alkyl, halogen-C2-C4alkinyl, C1-C6alkoxy, halogen-C1-C6alkoxy, C2-C6alkenyloxy, C2-C6alkinyloxy or halogen-C2-C6alkenyloxy; and R2 is R2a; R2a is for example -C1-C6alkyl-NR11R12, -COC9-C20alkyl, -C1-C6alkyl-O-C1-C6alkyl-O-C1-C6alkyl or -CH2O(C=O)C1-C6alkyl; or, at least one of the radicals R3a or R3b is -CR5=CR5R14, -NR11R12, -C(=O)CN, -C(=O)C(=O)O-C1-C6alkyl, -CR7=NOR10, or a five or six-membered heteroaryl ring bonded by a carbon atom; R2 is R2a or R2b, wherein R2a is as defined hereinbefore; and R2b is for example hydrogen, -OH, C1-C6alkyl or C1-C6alkoxy; R14 is for example hydrogen, halogen, C1-C6alkyl or halogen-C1-C6alkyl; X is O or S; p is 0, 1 or 2; R5 is independently H or C1-C8alkyl; R6 is for example independently H, C1-C8alkyl or C3-C6cycloalkyl; R7 is for example H, C1-C8alkyl, C2-C8alkenyl or halogen-C1-C8alkyl; R8 is for example C1-C8alkyl, C1-C8alkenyl or halogen-C1-C8alkyl; R9 is C1-C6alkyl, halogen-C1-C4alkyl or aryl; R10 is H, C1-C6alkyl, C3-C6cycloalkyl, phenyl or benzyl; R11 and R12 for example are independently of one another H, C1-C6alkyl or phenyl; and where applicable the possible E/Z isomers, E/Z isomer mixtures and/or tautomers thereof, in free form or in agrochemically acceptable form, can be used as agrochemical active ingredients and may be prepared in a known manner.

    摘要翻译： 式（I）化合物，其中：A1和A2各自独立地表示芳基或杂芳基; 适当时，取代基（R3a）n1和A2与取代基（R3b）n2适当地取代; n1和n2彼此独立地为0,1,2,3或4; R 3a和R 3b彼此独立地是例如卤素，C 1 -C 6烷基，C 2 -C 4炔基，卤素-C 1 -C 6烷基，卤素-C 2 -C 4炔基，C 1 -C 6烷氧基，卤素-C 1 -C 6烷氧基 ，C 2 -C 6烯氧基，C 2 -C 6烷氧基或卤素-C 2 -C 6烯氧基; R2为R2a; R2a是例如-C1-C6烷基-NR11R12，-COC9-C20烷基，-C1-C6烷基-O-C1-C6烷基-O-C1-C6烷基或-CH2O（C = O）C1-C6烷基; 基团R 3a或R 3b中的至少一个为-CR 5 = CR 5 R 14，-NR 11 R 12，-C（= O）CN，-C（= O）C（= O）O-C 1〜 C6烷基，-CR7 = NOR10，或被碳原子键合的五元或六元杂芳环; R2是R2a或R2b，其中R2a如上所定义; 并且R 2b是例如氢，-OH，C 1 -C 6烷基或C 1 -C 6烷氧基; R 14是例如氢，卤素，C 1 -C 6烷基或卤素-C 1 -C 6烷基; X为O或S; p为0,1或2; R5独立地为H或C1-C8烷基; R6例如独立地为H，C1-C8烷基或C3-C6环烷基; R 7是例如H，C 1 -C 8烷基，C 2 -C 8烯基或卤素-C 1 -C 8烷基; R8是例如C1-C8烷基，C1-C8链烯基或卤素-C1-C8烷基; R 9为C 1 -C 6烷基，卤素-C 1 -C 4烷基或芳基; R 10是H，C 1 -C 6烷基，C 3 -C 6环烷基，苯基或苄基; R 11和R 12例如彼此独立地为H，C 1 -C 6烷基或苯基; 并且如果适用，游离形式或农业化学上可接受的形式的可能的E / Z异构体，E / Z异构体混合物和/或互变异构体可用作农业化学活性成分，并且可以以已知方式制备。