摘要:
Finely divided composite materials are provided comprising a first metal oxide (e.g., MgO) at least partially coated with an extremely thin layer of a second metal oxide such as Fe2O3. The composites have a high surface area and are very effective for the destructive adsorption of undesirable fluids in gaseous or liquid form, such as chlorocarbons and clorofluorocarbons. In use, a fluid stream including undesirable fluids are contacted with the composites of the invention, such as through the use of a filter containing the composite as a part of the filter media thereof.
摘要:
This invention relates to rigid porous carbon structures and to methods of making same. The rigid porous structures have a high surface area which are substantially free of micropores. Methods for improving the rigidity of the carbon structures include causing the nanofibers to form bonds or become glued with other nanofibers at the fiber intersections. The bonding can be induced by chemical modification of the surface of the nanofibers to promote bonding, by adding 'gluing' agents and/or by pyrolyzing the nanofibers to cause fusion or bonding at the interconnect points.
摘要:
Disclosed are a kit, composition and method for cell separation. The kit includes a centrifugable container and an organosilanized silica particle-based cell separation suspension suitable for density gradient separation, containing a polylactam and sterilized by treatment with ionizing radiation. The composition includes a silanized silica particle-based suspension for cell separation which contains at least 0.05 % of a polylactam, and preferably treated by ionizing radiation. Also disclosed is a method of isolating rare blood cells from a blood cell mixture.
摘要:
Methods for adsorbing toxic target chemical compounds are provided wherein such compounds (either as gases, liquids or solids) are contacted with nanoscale oxide adsorbents, such as MgO and CaO, preferably at ambient temperatures and at atmospheric pressure. The preferred adsorbents have an average particle size of from about 1-20 nm, and have a total pore volume of at least about 0.5 cc/g.
摘要:
The present invention is related to a method of producing a nanoporous body containing nanodiamonds and having a desired shape, comprising the steps of: forming an intermediate body having the desired shape of nanodiamond particles having a maximum size of 10 nm, exposing said body to a gaseous hydrocarbon or a mixture of hydrocarbons at a temperature exceeding the decomposition temperature for the hydrocarbon or the hydrocarbons. In accordance with the invention the intermediate body is formed with a porosity of 50-80 vol.%, and during the heat-treatment of the intermediate body with hydrocarbon or hydrocarbons the mass of said body is increased by 50 % at the most. The present invention also relates to a nonoporous body produced by said method and to uses of such a body.
摘要:
Nitric oxide-releasing mesoporous silica nanoparticles (MSNs) were prepared using an aminosilane-template surfactant ion exchange reaction. Initially, bare silica particles were synthesized under basic conditions in the presence of cetyltrimethylammonium bromide (CTAB). These particles were functionalized with nitric oxide (NO) donor precursors via the addition of aminosilane directly to the particle sol, and a commensurate ion exchange reaction between the cationic aminosilanes and CTAB. N-diazeniumdiolate NO donors were formed at the secondary amines to yield NO-releasing silica MSNs. Tuning of the ion exchange-based MSN modification approach allowed for the preparation of monodisperse particles ranging from 30 to 1100 nm. Regardless of size, the MSNs stored appreciable levels of NO (0.4-3.5 μmol/mg) with tunable NO-release durations (1-33 h) dependent on the aminosilane modification. The range of MSN sizes and NO release demonstrate the versatility of this strategy.
摘要:
The present invention relates to a method for preparing superabsorbent polymer with improved anti-caking, and according to the present invention, a method for preparing superabsorbent polymer that has properties equivalent to or more excellent than the existing superabsorbent polymer but has improved anti-caking, and thus, has excellent processability, and superabsorbent polymer prepared thereby, are provided.
摘要:
The present invention relates to a method for preparing a superabsorbent polymer including a) preparing a hydrogel phase polymer by thermopolymerizing or photopolymerizing a monomer composition including a water-soluble ethylenically unsaturated monomer and a polymerization initiator; b) adding particles having properties of the following i) and ii) to the hydrogel phase polymer; c) chopping the particle-added hydrogel phase polymer; d) drying the hydrogel phase polymer; e) milling the dried hydrogel phase polymer; f) adding a surface crosslinking agent to the milled hydrogel phase polymer; and g) carrying out a surface crosslinking reaction. i) BET specific surface area of 300 m 2 /g to 1500 m 2 /g, ii) Porosity of 50% or greater.
摘要:
Filter media that includes activated carbon particulates and zinc oxide particles disposed on surfaces of the activated carbon particulates. The zinc oxide particles have an average crystallite dimension that is not greater than about 50 nm.
摘要:
Superficially porous silica particles are provided as well as a one-pot process for making the superficially porous particles, the process comprising hydrolyzing and condensing a silica precursor comprising a functional group to form superficially porous particles, the superficially porous particles comprising silica microparticles having silica nanoparticles bound to the surface of the microparticles. The nanoparticles provide a porous outer layer on the microparticles. The superficially porous particles are useful as a stationary phase in liquid chromatography and allow for fast mass transfer and separation of samples