摘要:
An aromatic alkylation process includes contacting an aromatic compound with an alkylating agent in the presence of a zeolite beta in a reaction zone under alkylation reaction conditions, wherein said zeolite beta is a high performance zeolite beta possessing a ratio of strong acid sites/weak acid sites greater than 1. The high performance zeolite beta is superior to conventional zeolite beta in the aromatics alkylation reaction, such as benzene alkylation with ethylene for ethylbenzene production, and benzene alkylation with propylene for cumene production.
摘要:
There is provided macrostructures of porous inorganic material which can have controlled size, shape, and/or porosity and a process for preparing the macrostructures. The macrostructures comprise a three-dimension network of particles of porous inorganic materials. The process for preparing the macrostructures involves forming an admixture containing a porous organic ion exchanger and a synthesis mixture capable of forming a porous inorganic material and then converting the synthesis mixture to a solid porous inorganic material. After formation of the composite material, the porous organic ion exchanger can be removed from the composite material to obtain the macrostructures, either before of after the porous inorganic material is hydrothermally treated with a structure directing agent to convert at least a portion of such porous inorganic material to a crystalline molecular sieve composition. The resulting macrostructure is composed of particles of the crystalline molecular sieve composition.
摘要:
The present invention includes a microporous or mesoporous composition of matter in which the composition is formed continuously or semicontinuously in a heated reactor zone at a temperature between 200°C and 500°C with a residence time less than 24 hours. The reagents are solid and liquid reagents in which the solid reagents have a weight percent between 45% and 98% of the total reagents. The invention also includes a continuous or semi-continuous process for the hydrothermal manufacture of the microporous or mesoporous composition.
摘要:
The invention concerns a process for the production of a molecular sieve material by growing the molecular sieve material structure in the presence of a template for the pore structure, followed by removal of the template from the molecular sieve material, in which process the template is removed by oxidation of the template material using an oxidising agent.
摘要:
The invention concerns a heat-stable ordered mesoporous or mesostructured material, comprising a mineral phase wherein are dispersed particles of nanometric dimension at least partly crystalline, the global crystallinity index of said mesostructured or ordered mesoporous material being less than 10 % in volume. The invention also concerns a method for obtaining such a material.
摘要:
The invention provides transition metal oxide mesophase compositions that include a sulfur-containing anionic surfactant and processes for preparing them. The processes involve conversion of a transition metal oxide precursor to a transition metal oxide mesophase in the presence of a sulfur-containing anionic surfactant templating agent, under conditions effective for formation of a transition metal oxide mesophase composition that includes the surfactant. The invention further provides processes for replacing at least part of the surfactant in such a transition metal oxide mesophase composition with anions. The anions may be anions of one or more oxyacids, thereby producing a transition metal oxide mesophase composition that includes a first transition metal oxide and a lesser amount of a second transition metal oxide dispersed on the first metal oxide.
摘要:
An in-extrudate reaction mixture to be effectively crystallized is effectively crystallized to produce zeolitic or non-zeolitic molecular sieves. The reaction mixture is heated within a slowly rotating, double-walled reactor vessel wherein a heated medium is conducted within a space formed between the double walls of the vessel. Thus, the reaction mixture is contacted by a uniformly heated wall while being gently tumbled at low speed. The tumbling action serves to uniformly distribute the heat within the reaction mixture without subjecting the mixture to such shearing that could damage shaped particles. A relatively high quantity of reaction mixture can be handled in that way to maximize the production volumes and reduce production costs.
摘要:
A method for the preparation of new quasi-crystalline, porous inorganic oxide materials possessing uniform framework-confined mesopores in the range 2.0-10.0 nm and large elementary particle size of more than 500.0 nm. The method uses an interaction between various non-ionic polyethylene oxide based surfactants (N DEG ) and neutral inorganic oxide precursors (I DEG ) at ambient reaction temperatures. The materials formed exhibit semi-ordered arrays of well defined pores owing to the specific mechanism of self-assembly, large pore wall thicknesses of at least 2.0 nm producing highly stable materials and large particle sizes incorporating large numbers of pores. This (N DEG I DEG ) templating approach introduces several new concepts to mesostructure synthesis. The application of the low-cost, non-toxic and biodegradable surfactants and ambient reaction temperatures, introduces environmentally clean synthetic techniques to the formation of mesostructures. Recovery of the template can be achieved through solvent extraction where the solvent may be water or ethanol.