PROCESS FOR THE GENERATION OF THIN INORGANIC FILMS
    65.
    发明公开
    PROCESS FOR THE GENERATION OF THIN INORGANIC FILMS 审中-公开
    生成薄无机膜的过程

    公开(公告)号:EP3172356A1

    公开(公告)日:2017-05-31

    申请号:EP15749738.9

    申请日:2015-07-22

    Applicant: BASF SE

    CPC classification number: C23C16/45553 C07F15/04 C07F15/06 C23C16/18

    Abstract: The present invention is in the field of processes for the generation of thin inorganic films on substrates, in particular atomic layer deposition processes. In detail the present invention relates a process comprising bringing a compound of general formula (I) into the gaseous or aerosol state (Fig.) and depositing the compound of general formula (I) from the gaseous or aerosol state onto a solid substrate, wherein R1 and R4 are independent of each other an alkyl group, an aryl group or a trialkylsilyl group, R2, R3, R5 and R6 are independent of each other hydrogen, an alkyl group, an aryl group or a trialkylsilyl group, n is an integer from 1 to 3, M is Ni or Co, X is a ligand which coordinates M, and m is an integer from 0 to 4.

    Abstract translation: 本发明属于用于在衬底上生成薄无机膜的工艺领域,特别是原子层沉积工艺。 详细地说,本发明涉及一种方法,其包括使通式(I)的化合物进入气态或气溶胶状态(图),并将通式(I)的化合物从气态或气溶胶状态沉积到固体基质上,其中 R1和R4彼此独立地为烷基,芳基或三烷基甲硅烷基,R2,R3,R5和R6彼此独立地为氢,烷基,芳基或三烷基甲硅烷基,n为整数 1至3,M为Ni或Co,X为配位M的配体,m为0至4的整数。

    ÜBERGANGSMETALLCARBENKOMPLEX- KATALYSIERTES VERFAHREN ZUR HERSTELLUNG VON CARBONSÄUREESTERN AUS ALKOHOLEN UNTER DEHYDRIERUNG
    69.
    发明公开
    ÜBERGANGSMETALLCARBENKOMPLEX- KATALYSIERTES VERFAHREN ZUR HERSTELLUNG VON CARBONSÄUREESTERN AUS ALKOHOLEN UNTER DEHYDRIERUNG 审中-公开
    ÜBERGANGSMETALLCARBENKOMPLEX-催化的过程用于从醇下进行脱水环生产羧酸酯的

    公开(公告)号:EP2874991A1

    公开(公告)日:2015-05-27

    申请号:EP13739190.0

    申请日:2013-07-16

    Applicant: BASF SE

    Abstract: The present invention relates to a method for producing carboxylic acid esters, comprising the reaction of at least one primary mono alcohol or a mixture of a primary mono alcohol and at least one alcohol differing from this in the presence of a transition metal carbene complex catalyst (K), which has as the central atom (M) at least one transition metal atom of group 8, 9 or 10 of the periodic table (IUPAC) and at least one monodentate N-heterocyclic carbene ligand, in the presence of a base, characterized in that the catalyst (K) is produced by reaction of a transition metal compound (V), which has at least one transition metal atom of group 8, 9 or 10 of the periodic table (IUPAC), but no carbene ligand, with an imidazolium salt in the presence of the primary mono alcohol and the base, wherein the reaction is a bulk reaction.

    Abstract translation: 本发明涉及一种用于生产羧酸酯,其包含至少一个伯一元醇的在过渡金属卡宾络合物催化剂的存在下与此不同的反应或伯单醇的混合物和至少一种醇( K),其具有作为中心原子(M)基团8,9或周期表的第10中的至少一个过渡金属原子(IUPAC)和至少一种单齿N-杂环卡宾配体,在碱的存在下, dadurch gekennzeichnet,DASS模具催化剂(K)是由过渡金属化合物(V),其具有第8族,9或周期表(IUPAC)10中的至少一个过渡金属原子的反应所产生,但无碳烯配体,具有 在主元醇与碱的存在咪唑鎓盐,worin反应是本体反应。

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